Microstructure and Mechanical Properties of Multicomponent Metal Ti(C,N)-Based Cermets

Ti(C,N)-based cermets with multicomponent ingredients were prepared using vacuum sintering technology. The effect of molding agents, binder phase and sintering temperature on Ti(C,N)-based cermets were studied. The optimum molding performance was obtained by adding 2% polyvinyl alcohol (PVA-1788). The microstructure and mechanical properties of Ti(C,N)-based cermets were investigated. The Ti(C,N)-based cermet with a weight percentage of TiC:TiN:Ni:Co:Mo:WC:Cr3C2:C = 40:10:20:10:7:8:4:1 and sintered at 1450 °C had the optimal mechanical properties. The relative bending strength, Vickers hardness, elastic modulus and wear resistance were 2010 MPa, 15.01 GPa, 483.57 GPa and 27 mg, respectively. Additionally, X-ray diffraction (XRD), backscatter scanning electron microscopy pictures (SEM–BSE), energy dispersive spectrometry (EDS) and optical micrographs of Ti(C,N)-based cermets were characterized.

Characterization and Tribological Performance of Cu-Based Intermetallic Layers

Fluidized bed reactor chemical vapor deposition (FBR-CVD) has been used to enrich the surface of oxygen free high conductivity (OFHC) copper with titanium, silicon and aluminum. This technique enables the production of coherent and adherent intermetallic surface layers of uniform thickness and high hardness. The characterization of the coatings was performed using backscatter scanning electron microscopy (BS-SEM), X-ray diffraction (XRD), glow discharge optical emission spectroscopy (GDOES) and micro-hardness. The tribological properties of the coatings in dry sliding contact with steel were evaluated by pin-on-disc wear testing.

Saddle dolomite: a new view of its nature and origin

Saddle dolomite is a common product of late-stage diagenesis and hydrothermal activity. It has been suggested that during growth Ca enrichment occurs towards crystal edges leading to a lattice expansion relative to face centres. However, backscatter scanning electron microscopy of eight samples has revealed that, instead of edge associated Ca enrichment, saddle dolomites have a series of edge associated Mg enriched wedges, between 5 and 20 µm thick and 300 µm long. Wedge geometry implies development of extra lattice layers at edges relative to face centres. It is suggested that the wedges develop during rapid, transport-controlled, crystal growth. The wedges possibly reflect a switching from continuous growth across the face to edge-nucleated growth as the boundary layer solution becomes progressively depleted. Continuous growth might be reinstigated through convective turnover of the boundary layer presenting fresh solution to the growing crystal.