scholarly journals Nd-Sr Isotopic Study of Magmatic Rocks and 40Ar/39Ar Dating of the Mafic Dike of the Proterozoic Ulan-Sar’dag Ophiolite Mélange (Southern Siberia, East Sayan, Middle Belt, Russia)

Minerals ◽  
2022 ◽  
Vol 12 (1) ◽  
pp. 92
Author(s):  
Olga Kiseleva ◽  
Pavel Serov ◽  
Evgenia Airiyants ◽  
Aleksey Travin ◽  
Dmitriy Belyanin ◽  
...  

We report the first radiogenic Nd-Sr isotope data in the magmatic rocks island-arc ophiolite assemblage from the middle branch of the East Sayan ophiolite complexes to better constrain geodynamic processes in this segment of the CAOB in southern central Siberia. The magmatic rocks belong to the following geochemical types: (1) Ensimatic island-arc boninites; (2) island-arc assemblage; (3) enriched basalts of mid-ocean ridges; and (4) oceanic island-like basalts. The boninites have a positive value εNd (T), which is generated from a depleted mantle source (N-MORB). The island-arc assemblage has negative or slightly positive εNd (T) and was formed from an enriched mantle source due to the subduction of terrigenous rocks. The source of the terrigenous material was most likely the rocks of the Archean TTG (Trondhjemite Tonalite Granodiorite) complex of the Gargan block. Isotopic ratios for E-MOR and OIB-like basalts are characterized by positive or slightly negative values of εNd (T). The mafic dike, which crosscut ophiolite rocks, corresponds to OIB-like basalts. The values of εNd (T), measured 87Sr/86Sr and I (Sr), in the mafic dike correspond to the EM I mantle source. The E-MOR and OIB-like basalts appear to be formed in late-stage asthenospheric mantle melting via the decompression melting processes. The obtained isotope geochemical data for the E-MOR and OIB-like basalts probably indicate the mixing of island-arc melts with asthenospheric melts. We undertook 40Ar/39Ar dating of the mafic dike, which crosscut the ophiolite unit. The mafic dike has a whole-rock 40Ar/39Ar weighted mean plateau age of 799 ± 11 Ma. The dating constrains the minimum age of the ophiolite and island-arc magmatism in the region.

2020 ◽  
Vol 105 (12) ◽  
pp. 1778-1801
Author(s):  
Takafumi Kimura ◽  
Kazuhito Ozawa ◽  
Takeshi Kuritani ◽  
Tsuyoshi Iizuka ◽  
Mitsuhiro Nakagawa

Abstract Ophiolite pulses, which are periods of enhanced ophiolite generation and emplacement, are thought to have a relevance to highly active superplumes (superplume model). However, the Cambrian-Ordovician pulse has two critical geological features that cannot be explained by such a superplume model: predominance of subduction-related ophiolites and scarcity of plume-related magma activities. We addressed this issue by estimating the mechanism and condition of magma generation, including mantle potential temperature (MPT), from a ~500 Ma subduction-related ophiolite, the Hayachine-Miyamori ophiolite. We developed a novel method to overcome difficulties in global MPT estimation from an arc environment by using porphyritic ultramafic dikes showing flow differentiation, which have records of the chemical composition of the primitive magma, including its water content, because of their high pressure (~0.6 GPa) intrusion and rapid solidification. The solidus conditions for the primary magmas are estimated to be ~1450 °C, ~5.3 GPa. Geochemical data of the dikes show passive upwelling of a depleted mantle source in the garnet stability field without a strong influence of slab-derived fluids. These results, combined with the extensive fluxed melting of the mantle wedge prior to the dike formation, indicate sudden changes of the melting environment, its mechanism, and the mantle source from extensive fluxed melting of the mantle wedge to decompressional melting of the sub-slab mantle, which has been most plausibly triggered by a slab breakoff. The estimated MPT of the sub-slab mantle is ~1350 °C, which is very close to that of the current upper mantle and may reflect the global value of the upper mantle at ~500 Ma if small-scale convection maintained the shallow sub-slab mantle at a steady thermal state. We, therefore, conclude that the Cambrian-Ordovician ophiolite pulse is not attributable to the high temperature of the upper mantle. Frequent occurrence of slab breakoff, which is suggested by our geochemical compilation of Cambrian-Ordovician ophiolites, and subduction termination, which is probably related to the assembly of the Gondwana supercontinent, may be responsible for the ophiolite pulse.


2020 ◽  
Author(s):  
Vartan Simmonds ◽  
Mohssen Moazzen ◽  
Gültekin Topuz ◽  
Ali Mohammadi

<p>The Qaradagh batholith in northwest Iran mainly comprises granodioritic rocks, which makes more than 50% of the batholith. This lithology is the first intrusive pulse within this batholith and the oldest Tertiary magmatism in the region, though other younger pulses of granite, diorite, quartz-diorite, syenite, quartz-syenite, monzonite, quartz-monzonite, quartz monzodiorite, monzogranite and gabbro intruded the main body. These magmatic rocks have intruded the Upper Cretaceous and Paleogene sedimentary, volcano-sedimentary and igneous rocks.</p><p>The Qaradagh batholith hosts vein-type and some local stock-work type Cu–Au–Mo mineralization, especially in its central parts, while skarn-type deposits have been formed at its contacts with peripheral carbonate rocks. Its extension towards the north into the neighboring south Armenia (which is part of the South Armenian Block) is known as the Meghri–Ordubad pluton (MOP), which hosts several large porphyry Cu–Mo deposits and other precious and base metal mineralizations. U–Pb geochronology on the zircons separated from the granodioritic unit yielded a weighted <sup>206</sup>Pb/<sup>238</sup>U mean age of 43.81 ± 0.18 (MSWD=1.38) and a Pb*/U concordia age of 44.04 ± 1.00 Ma (MSWD= 24), which correspond to Middle Eocene.</p><p>Since the Qaradagh batholith and especially its earliest magmatic phase are considered as the oldest plutonic event of the Cenozoic age in northwest Iran, thus this investigation testifies to the fact that intrusive activities of Tertiary in this region has commenced in Middle Eocene, contrary to the opinion of the majority of authors who believe that plutonism in this region occurred during Oligocene.</p><p>However, this age is much older than the molybdenite Re–Os ages of quartz-sulfide veins hosted by granodioritic rocks (25.19 ± 0.19 to 31.22 ± 0.28 Ma), indicating that mineralization in this batholith is related to another much younger intrusive phase, and even to several phases, as the published ages of molybdenites from various veins and mineralized zones show a large interval. Comparing the obtained age with those from the MOP in southern Armenia indicate that southern part of the MOP is almost coeval with the emplacement of the granodioritic rocks in Qaradagh batholith.</p><p>The U and Th contents of the zircons range from 17.1 to 1534.0 and from 4.9 to 641.0 ppm, respectively, with Th/U ratios between 0.66 and 5.82 (mean of 1.26), indicating a magmatic source. Meanwhile, the εHf<sub>(t) </sub>values of the zircons range from 8.7 to 11.1 with the mean of 9.5, which are plotted between the CHUR and the Depleted Mantle evolution lines, indicating a juvenile and homogeneous magmatic source and the predominance of mantle-derived magmas with limited crustal assimilation.</p>


2020 ◽  
Vol 61 (7) ◽  
Author(s):  
Lukáš Krmíček ◽  
Rolf L Romer ◽  
Martin J Timmerman ◽  
Jaromír Ulrych ◽  
Johannes Glodny ◽  
...  

Abstract The orogenic development after the continental collision between Laurussia and Gondwana, led to two contrasting associations of mantle-derived magmatic rocks on the territory of the Bohemian Massif: (i) a 340–310 Ma lamprophyre-lamproite orogenic association; and (ii) a 300–275 Ma lamprophyre association of anorogenic affinity. Major types of potassic mantle-derived magmatic rocks recognized in the orogenic and anorogenic associations include: (i) calc-alkaline to alkaline lamprophyres; (ii) alkaline ‘orthopyroxene minettes’ and geochemically related rocks grouped here under the new term lampyrite; and (iii) peralkaline lamproites. These three types significantly differ with respect to mineral, whole-rock and Sr–Nd–Pb–Li isotope composition and spatial distribution. The calc-alkaline lamprophyres occur throughout the entire Saxo-Thuringian and Moldanubian zones, whereas the different types of malte-derived potassic rocks are spatially restricted to particular zones. Rocks of the Carboniferous lamprophyre-lamproite orogenic association are characterized by variable negative εNd(i) and variably radiogenic Sr(i), whereas the rocks of the Permian lamprophyre association of anorogenic affinity are characterized by positive εNd(i) and relatively young depleted-mantle Nd-model ages reflecting increasing input from upwelling asthenospheric mantle. The small variation in the Pb isotopic composition of post-collisional potassic mantle-derived magmatic rocks (of both the orogenic and anorogenic series) implies that the Pb budget of the mantle beneath the Bohemian Massif is dominated by the same crust-derived material, which itself may include material derived from several sources. The source rocks of ‘orthopyroxene minettes’ are characterized by isotopically light (‘eclogitic’) Li and strongly radiogenic (crustal) Sr and may have been metasomatized by high-pressure fluids along the edge of a subduction zone. In contrast, the strongly Al2O3 and CaO depleted mantle source of the lamproites is characterized by isotopically heavy Li and high SiO2 and extreme K2O contents. This mantle source may have been metasomatized predominantly by melts. The mantle source of the lamprophyres may have undergone metasomatism by both fluids and melts.


2015 ◽  
Vol 52 (9) ◽  
pp. 701-721 ◽  
Author(s):  
Lars Eivind Augland ◽  
Abdelali Moukhsil ◽  
Fabien Solgadi ◽  
Aphrodite Indares

Understanding the magmatic evolution of the rocks once comprising the hinterland of the Grenville Orogen through their Mesoproterozoic formation is a key to understanding the Grenvillian Orogeny as a whole. In this contribution, we present high-precision isotope dilution thermal ionization mass spectrometry (ID–TIMS) U–Pb and coupled solution multicollector inductively coupled plasma mass spectrometry (S–MC–ICP–MS) Lu–Hf zircon data from magmatic rocks occurring in the allochthonous belt of the Grenville Orogen in the central part of the Grenville Province. We document the presence of a large tract of Pinwarian crust represented by a 1497 ± 5 Ma granitic gneiss, as well as large late Geon 14 to early Geon 13 (1434 +7/−11, 1413 ± 12, 1393 ± 8, 1383 ± 1 Ma) magmatic complexes. One Grenvillian plutonic suite of 1015 ± 2 Ma that cross-cuts the host-rock metamorphic fabric has also been dated. This age provides a minimum age of Ottawan metamorphism in the region. The Hf-isotopic data show that the magmatic rocks of Geons 14 and 13 had mixed mantle and crustal sources compatible with intrusion in a supra-subduction setting as is also supported by the whole-rock geochemical data presented. Emplacement of the magmatic rocks occurred in settings varying from a distal margin arc to a contractional and extensional continental arc. Grenvillian-aged magmatism is more ambiguous, but our data indicate that rocks as young as ca. 1015 Ma may have formed in an ensialic setting.


1991 ◽  
Vol 28 (11) ◽  
pp. 1744-1752 ◽  
Author(s):  
A. Andrew ◽  
R. L. Armstrong ◽  
D. Runkle

Combined neodymium, strontium, and lead isotope measurements show that Vancouver Island is made up of Phanerozoic crustal material accreted to North America in the Mesozoic and early Cenozoic, but that there are differences in the relative proportions of depleted mantle and aged, enriched crustal components in the Phanerozoic magmatic episodes that contribute to this new crust.The Devonian Sicker Group volcanic arc has an isotopic signature that can be explained by mixing mantle material with subducted continentally derived sediments. The Early to Middle Jurassic Bonanza Volcanics and Island Intrusions magmatic arc isotopic signature indicates mixing of magma from a depleted mantle source with crustal material of Sicker arc-type, rather than of continental origin. This is consistent with large-scale assimilation of Sicker Group and Karmutsen rocks by Jurassic mantle-derived magmas, or introduction of arc-derived sediments into the Jurassic mantle by subduction. Eocene calc-alkaline Flores Volcanics – Catface Intrusions may be derived from reworked Vancouver Island crust with little addition of mantle material.Late Triassic Karmutsen Formation flood basalts are similar to the lower parts of the Columbia River Basalt in all three isotope systems and in petrochemistry. Radiogenic isotopic data are consistent with the interpretation that the Karmutsen basalts were extruded in a post-arc or back-arc setting, with mantle lithosphere and depleted mantle components, and perhaps some plume source input and crustal contamination, but the latter are not provable from the radiogenic isotopic data alone.Early Eocene Metchosin basalts show a depleted mantle source, consistent with their origin as ocean islands, before Middle to Late Eocene accretion to the rest of Vancouver Island.


1997 ◽  
Vol 34 (9) ◽  
pp. 1185-1201 ◽  
Author(s):  
David P. Moecher ◽  
Eric D. Anderson ◽  
Claudia A. Cook ◽  
Klaus Mezger

Veins and dikes of calcite-rich rocks within the Central Metasedimentary Belt boundary zone (CMBbz) in the Grenville Province of Ontario have been interpreted to be true carbonatites or to be pseudocarbonatites derived from interaction of pegmatite melts and regional Grenville marble. The putative carbonatites have been metamorphosed and consist mainly of calcite, biotite, and apatite with lesser amounts of clinopyroxene, magnetite, allanite, zircon, titanite, cerite, celestite, and barite. The rocks have high P and rare earth element (REE) contents, and calcite in carbonatite has elevated Sr, Fe, and Mn contents relative to Grenville Supergroup marble and marble mélange. Values of δ18OSMOW (9.9–13.3‰) and δ13CPDB (−4.8 to −1.9‰) for calcite are also distinct from those for marble and most marble mélange. Titanites extracted from clinopyroxene–calcite–scapolite skarns formed by metasomatic interaction of carbonatites and silicate lithologies yield U–Pb ages of 1085 to 1035 Ma. Zircon from one carbonatite body yields a U–Pb age of 1089 ± 5 Ma; zircon ages from two other bodies are 1170 ± 3 and 1143 ± 8 Ma, suggesting several carbonatite formation events or remobilization of carbonatite during deformation and metamorphism around 1080 Ma. Values of εNd(T) are 1.7–3.2 for carbonatites, −1.5–1.0 for REE-rich granite dikes intruding the CMBbz, and 1.6–1.7 for marble. The mineralogy and geochemical data are consistent with derivation of the carbonatites from a depleted mantle source. Mixing calculations indicate that interaction of REE-rich pegmatites with regional marbles cannot reproduce selected major and minor element abundances, REE contents, and O and Nd isotope compositions of the carbonatites.


2016 ◽  
Author(s):  
Cody L. MacCabe ◽  
◽  
Greg L. Melton ◽  
Richard Wendlandt

2020 ◽  
Author(s):  
Hai Zhou ◽  
Guochun Zhao ◽  
et al.

Table S1: Summary of the samples and sampling positions in this study (sampling sites are marked in Fig. 3); Table S2: U-Pb age data for zircons of (meta-)sedimentary and volcanic rocks in this study; Table S3: Lu-Hf isotopic data for zircons of (meta-)sedimentary and volcanic rocks in this study.


Minerals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 711
Author(s):  
Irina Nedosekova ◽  
Nikolay Vladykin ◽  
Oksana Udoratina ◽  
Boris Belyatsky

The Ilmeno–Vishnevogorsk (IVC), Buldym, and Chetlassky carbonatite complexes are localized in the folded regions of the Urals and Timan. These complexes differ in geochemical signatures and ore specialization: Nb-deposits of pyrochlore carbonatites are associated with the IVC, while Nb–REE-deposits with the Buldym complex and REE-deposits of bastnäsite carbonatites with the Chetlassky complex. A comparative study of these carbonatite complexes has been conducted in order to establish the reasons for their ore specialization and their sources. The IVC is characterized by low 87Sr/86Sri (0.70336–0.70399) and εNd (+2 to +6), suggesting a single moderately depleted mantle source for rocks and pyrochlore mineralization. The Buldym complex has a higher 87Sr/86Sri (0.70440–0.70513) with negative εNd (−0.2 to −3), which corresponds to enriched mantle source EMI-type. The REE carbonatites of the Chetlassky сomplex show low 87Sr/86Sri (0.70336–0.70369) and a high εNd (+5–+6), which is close to the DM mantle source with ~5% marine sedimentary component. Based on Sr–Nd isotope signatures, major, and trace element data, we assume that the different ore specialization of Urals and Timan carbonatites may be caused not only by crustal evolution of alkaline-carbonatite magmas, but also by the heterogeneity of their mantle sources associated with different degrees of enrichment in recycled components.


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