In this work, the structural and magnetic properties of polycrystalline Zn1-xCoxO (x = 0,
0.02, 0.05, 0.0625, 0.10 and 0.15) oxides were studied in detail. Rietveld refinement of x-ray
diffraction spectra indicates that a single-phase wurtzite structure was formed in Zn1-xCoxO samples
for x up to 0.10. The magnetization for x = 0.02 can be fitted to a model with a paramagnetic Curie
term and a diamagnetic constant which could arise from spins of isolated free Co ions and a
diamagnetic background, respectively. For x > 0.02, however, an additional antiferromagnetic
Curie-Weiss term needs to employ for fitting. This is due to an additional contribution from
clustered Co ions that are in nearest neighbor positions through oxygen ions. Results show that the
substitution of Co at the Zn site does not occur in a completely random manner but Co ions appear
to have a tendency for clustering. In addition, the homogenous ZnO:Co thin film prepared by
Pulsed Laser Deposition on SiO2/Si substrate shows ferromagnetic behavior at room temperature.