MICROSTRUCTURE AND MARTENSITIC TRANSFORMATION OF Ni_{50}Ti_{50-x}Er_{x} SHAPE MEMORY ALLOYS

The effect of rare earth element Er addition on the microstructure and phase transformation behavior of Ni_{50}Ti_{50-x}Er_{x} (x =0, 1, 5) shape memory alloy was investigated experimentally. The results showed that the microstructure of Ni-Ti-Er ternary alloys consists of the NiEr precipitate and the NiTi matrix. A one-step martensitic transformation was observed in all alloys. The martensitic transformation temperature M_s increased gradually with increasing Er content.

Phase Transformations, Microstructure and Shape Memory Effect of NiTiAg Alloy with Different Atomic Percentages (at. % Ag) Manufactured by Casting Method

In this paper, shape memory alloys (SMAs) (NiTi-based) have been manufactured by casting with a different atomic percentage of a silver element (0, 1, 2 and 3 at. % Ag) using a Vacuum Arc Remelting (VAR) furnace. The silver element is added to the binary alloys due to its excellent properties such as (anti-corrosion, anti-bacterial and high electrical conductivity), which make these alloys using in wider applications. These alloys with different atomic percentages (Ni55Ti45Ag0, Ni55Ti44Ag1, Ni55Ti43Ag2 and Ni55Ti42Ag3) have been manufactured. The successful manufacturing process has been achieved and proved via examinations and tests. The FESEM microscopic examinations show that the silver element has been distributed uniformly and homogeneously in the NiTi matrix. Moreover, the emergence of austenite phase, martensite phase and little amount impurities. Regarding the XRD examination, showed that there is an increase in the number of peaks of Ag phase with an increase in the atomic percentage of the silver element, as well to emergence of phase (Ti2Ni) upon heating, phase (Ti 002) upon cooling, and phase (Ni4Ti3) is not desired. The starting and finishing of the phase transformations have been determined for all samples by the DSC test. The Shape Memory Effect (SME) for the alloy (Ni50Ti42Ag3) is measured to be about 89.99%.

Effects of Nb on the Microstructure and Compressive Properties of an As-Cast Ni44Ti44Nb12 Eutectic Alloy

The addition of Nb can form a eutectic phase with a NiTi matrix in a NiTi-based shape memory alloy, improving the transition hysteresis of the NiTi alloy. A Ni44Ti44Nb12 ingot was prepared using the vacuum induction melting technique. Under compression deformation, the yield strength of the NiTi–Nb alloy is about 1000 MPa, the maximum compressive strength and strain can reach 3155 MPa and 43%, respectively. Ni44Ti44Nb12 exhibited a superelastic recovery similar to that of the as-cast NiTi50. Meanwhile, the loading–unloading cycle compression shows that the superelastic recovery strain reached a maximum value (2.32%) when the total strain was about 15%, and the superelasticity tends to rise first and then decrease as the strain increases.

Nanocrystal, phase transformation and microstructure of Ni50Ti50 shape memory alloy

The nanocrystal, phase transformation and microstructure behavior of Ni50Ti50 shape memory alloy was investigated by scanning electronic microscope, X-ray diffraction and differential scanning calorimetry. The results showed that the microstructure of Ni-Ti binary alloy consists of the NiTi2 phase and the NiTi matrix phase. One-step phase transformation was observed alloy.

Structure of multi-functional calcium phosphates/TiO2 layers deposited on NiTi shape-memory alloy

The structure of the NiTi matrix covered by multi-layer was studied applying X-ray diffraction techniques supported by electron microscopy. Multi-layer was composed from titanium oxide (passivation) followed by mixture of the hydroxyapatite (HAp) and β-tricalcium phosphate (β-TCP) (electrophoresis). Conditions of deposition as well as sintering did not change the nominal ratio of HAp/TCP and saved their original structure. Also, the passivated NiTi matrix and with HAp/TCP-deposited layer did not change structure. However, sintering, done for HAp/TCP consolidation, introduced local differences in the lattice parameter as well as phase composition of the NiTi matrix. In consequence of that, two-steps martensitic transformation occurred in sintered NiTi/TiO2/Hap–TCP composite.

Investigation on microstructure and martensitic transformation of neodymium-added NiTi shape memory alloys

The effect of rare earth element neodymium (Nd) addition on the microstructure and martensitic transformation behavior of Ni[Formula: see text]Ti[Formula: see text]Nd[Formula: see text] ([Formula: see text] = 0, 0.1, 0.3, 0.5 and 0.7 at.%) shape memory alloy was investigated by scanning electronic microscope, X-ray diffraction and differential scanning calorimetry. The results show that the microstructure of Ni–Ti–Nd ternary alloy consists of NiNd phase, NiTi2 and the NiTi matrix. A one-step martensitic transformation is observed in the alloys. The martensitic transformation temperature Ms increases sharply increasing 0.1–0.7 at.% Nd content is added.