The Study of Graphene Oxide on the Regulations and Controls of the Sol-Gel Film Structure and Its Performance

A facile strategy to boost anticorrosion potency of graphene oxide/silica hybrid sol-gel coating is developed through fully exploiting the capabilities of graphene oxide (GO). Together with a barrier to corrosives and crack inhibitor, GO was further explored herein as a regulator to regulate the gelation process and provide robust coating films with stratified microstructures and ultimately extended diffusion paths. The sol-gel coating with stratified microstructure achieved on AA5052 aluminum alloy surface afforded greatly enhanced corrosion protection capability as assessed by electrochemical measurements and immersion tests. The corrosion current density of the sample of a hybrid GO sol-gel film was about 30 times less than that of sample of pure sol-gel film sample. The regulation mechanism of GO during the film formation process and the anticorrosive protection properties of the film were discussed.

Environmental eustress modulates β-ARs/CCL2 axis to induce anti-tumor immunity and sensitize immunotherapy against liver cancer in mice

Although psycho-social stress is a well-known factor that contributes to the development of cancer, it remains largely unclear whether and how environmental eustress influences malignant diseases and regulates cancer-related therapeutic responses. Using an established eustress model, we demonstrate that mice living in an enriched environment (EE) are protected from carcinogen-induced liver neoplasia and transplantable syngeneic liver tumors, owning to a CD8+ T cell-dependent tumor control. We identify a peripheral Neuro-Endocrine-Immune pathway in eustress, including Sympathetic nervous system (SNS)/β-adrenergic receptors (β-ARs)/CCL2 that relieves tumor immunosuppression and overcomes PD-L1 resistance to immunotherapy. Notably, EE activates peripheral SNS and β-ARs signaling in tumor cells and tumor infiltrated myeloid cells, leading to suppression of CCL2 expression and activation of anti-tumor immunity. Either blockade of CCL2/CCR2 or β-AR signaling in EE mice lose the tumor protection capability. Our study reveales that environmental eustress via EE stimulates anti-tumor immunity, resulting in more efficient tumor control and a better outcome of immunotherapy.

Green natural dye from Buddleja officinalis and its ultrasonic dyeing on cotton fabric

Purpose The purpose of this paper is to explore a new eco-friendly green textile dyeing. Natural plant Buddleja officinalis is traditionally used as yellow pigment addition in rice. It is worth developing its application and dyeing performance in cotton fabric. Design/methodology/approach Buddleja officinalis dried flower was extracted with ethanol aqueous. The extraction conditions including ethanol concentration, material to liquor ratio, extract time and temperature were optimized. Then cotton fabrics were dyed with Buddleja officinalis extraction under conventional and ultrasonic conditions. The effects of dyeing time, bath ratio, pH value of dyeing bath, dyeing temperature and mordants on K/S values were studied and the resulting color strength obtained by conventional and ultrasonic dyeing were compared. The ultraviolet (UV) transmittance of Buddleja officinalis dyed cotton fabric was also evaluated. Findings The color strength of the fabric dyed with Buddleja officinalis under ultrasonic conditions was higher than that under conventional conditions. Alum, Fe and Cu as simultaneous mordants improved the K/S value of the dyed cotton fabrics. Both washing fastness and rubbing fastness were fairly good in all Buddleja officinalis dyed cotton fabrics, washing fastness = 3–4 and rubbing fastness = 4. What’s more, the dyed cotton fabrics showed lower transmittance values as compared to undyed cotton fabrics and indicated potential UV protection capability. Practical implications Buddleja officinalis can be a new natural dye source for the ultrasonic dyeing of cotton fabric. Originality/value It is for the first time that Buddleja officinalis is used as a natural dye in cotton fabric dyeing with less water and the dyeing using ultrasound has been found to have an obvious improvement in the color strength and color-fastness.

The Crowd Wisdom for Location Privacy of Crowdsensing Photos

The incorporation of the mobile crowd in visual sensing provides a significant opportunity to explore and understand uncharted physical places. We investigate the gains and losses of the involvement of the crowd wisdom on users' location privacy in photo crowdsensing. For the negative effects, we design a novel crowdsensing photo location inference model, regardless of the robust location protection techniques, by jointly exploiting the visual representation, correlation, and geo-annotation capabilities extracted from the crowd. Compared with existing retrieval-based and model-based location inference techniques, our proposal poses more pernicious threats to location privacy by considering the no-reference-photos situations of crowdsensing. We conduct extensive analyses on the model with four photo datasets and crowdsourcing surveys for geo-annotation. The results indicate that being in a crowd of photos will, unfortunately, increase one's risk to be geo-identified, and highlights that the model can yield a considerable high inference accuracy (48%~70%) and serious privacy exposure (over 80% of users get privacy disclosed) with a small portion of geo-annotated samples. In view of the threats, we further propose an adaptive grouping-based signing model that hides a user's track with the camouflage of a crowd of users. Wherein, ring signature is tailored for crowdsensing to provide indistinguishable while valid identities for every user's submission. We theoretically analyze its adjustable privacy protection capability and develop a prototype to evaluate the effectiveness and performance.

Near-Instantaneously Self-Healing Coating toward Stable and Durable Electromagnetic Interference Shielding

Durable electromagnetic interference (EMI) shielding is highly desired, as electromagnetic pollution is a great concern for electronics’ stable performance and human health. Although a superhydrophobic surface can extend the service lifespan of EMI shielding materials, degradation of its protection capability and insufficient self-healing are troublesome issues due to unavoidable physical/chemical damages under long-term application conditions. Here, we report, for the first time, an instantaneously self-healing approach via microwave heating to achieve durable shielding performance. First, a hydrophobic 1H,1H,2H,2H-perfluorooctyltriethoxysilane (POTS) layer was coated on a polypyrrole (PPy)-modified fabric (PPy@POTS), enabling protection against the invasion of water, salt solution, and corrosive acidic and basic solutions. Moreover, after being damaged, the POTS layer can, for the first time, be instantaneously self-healed via microwave heating for a very short time, i.e., 4 s, benefiting from the intense thermal energy generated by PPy under electromagnetic wave radiation. This self-healing ability is also repeatable even after intentionally severe plasma etching, which highlights the great potential to achieve robust and durable EMI shielding applications. Significantly, this approach can be extended to other EMI shielding materials where heat is a triggering stimulus for healing thin protection layers. We envision that this work could provide insights into fabricating EMI shielding materials with durable performance for portable and wearable devices, as well as for human health care."Image missing"

Effect of Hull Obliquity on Crew Protection, Mass and Space Occupancy of Light Armoured Vehicle

Apart from strengthening crew protective capability from gunfire, the hull obliquity in a light armoured vehicle (LAV) affects its weight and comfortable occupancy. Thus, it requires a critical design analysis for the obliqued hull. The study aims to present the optimal design analysis of an obliqued hull structure to ensure comfortable occupancy of the crew along with its minimum attainable weight and higher protection capability from the gunfire. Three geometric models (G1, G2, and G3) were investigated for the LAV hull’s optimal design. The analytical approach was used to investigate the hull obliquity’s effect, and the results were validated using experimental data reported by other researchers. Digital human modelling was adopted for validating the space adequacy of the hull. It was observed that the hull’s crew protection capabilities from the horizontal strike of armour piercing rounds/bullets were improved almost by half and double for G2 and G3, respectively, when compared with G1. The analytical results are also in good agreement with globally accepted experimental data at reasonable variations. The highest protection capability and comfortable occupancy for the targeted users can be achieved by G3 without affecting the mobility of LAV.