In this work, atomically clean and structurally ordered surface of CdTe epitaxial layer after storage in air by treatment in isopropyl alcohol saturated with vapors of hydrochloric acid, and further temperature heating in an ultrahigh vacuum, was obtained. CdTe surface chemical treatment results in the removal of native oxides and surface enrichment with elemental tellurium. Heating in vacuum leads to the tellurium desorption and the appearance of a Te-stabilized CdTe surface. During heating in vacuum, two stages of surface state change are observed (~125°С and ≤250°С). At Т>250°С, elemental tellurium is desorbed and a Te-stabilized structure (1x1) CdTe(013) is formed.