Quaternary Fe‐Cu‐Cr‐Al HT‐WGS Catalysts – Effect of Al Substitution on the Efficiency at Steam‐Lean Process Gas

2020 ◽  
Vol 2020 (36) ◽  
pp. 3474-3480
Author(s):  
Paweł Kowalik ◽  
Robert Bicki ◽  
Katarzyna Antoniak‐Jurak ◽  
Kamila Michalska ◽  
Wiesław Próchniak ◽  
...  
Keyword(s):  
2008 ◽  
Author(s):  
K. Walther ◽  
C. Holtkoetter ◽  
I. Kelbassa ◽  
R. Poprawe

Author(s):  
Max Bialaschik ◽  
Volker Schöppner ◽  
Mirko Albrecht ◽  
Michael Gehde

AbstractThe joining of plastics is required because component geometries are severely restricted in conventional manufacturing processes such as injection molding or extrusion. In addition to established processes such as hot plate welding, infrared welding, or vibration welding, hot gas butt welding is becoming more and more important industrially due to its advantages. The main benefits are the contactless heating process, the suitability for glass fiber reinforced, and high-temperature plastics as well as complex component geometries. However, various degradation phenomena can occur during the heating process used for economic reasons, due to the presence of oxygen in the air and to the high gas temperatures. In addition, the current patent situation suggests that welding with an oxidizing gas is not permissible depending on the material. On the other hand, however, there is experience from extrusion welding, with which long-term resistant weld seams can be produced using air. Investigations have shown that the same weld seam properties can be achieved with polypropylene using either air or nitrogen as the process gas. Experimental investigations have now been carried out on the suitability of different gases with regard to the weld seam quality when welding polyamides, which are generally regarded as more prone to oxidation. The results show that weld strengths are higher when nitrogen is used as process gas. However, equal weld strengths can be achieved with air and nitrogen when the material contains heat stabilizers.


Author(s):  
Marian Wiatowski ◽  
Roksana Muzyka ◽  
Krzysztof Kapusta ◽  
Maciej Chrubasik

AbstractIn this study, the composition of tars collected during a six-day underground coal gasification (UCG) test at the experimental mine ‘Barbara’ in Poland in 2013 was examined. During the test, tar samples were taken every day from the liquid product separator and analysed by the methods used for testing properties of typical coke oven (coal) tar. The obtained results were compared with each other and with the data for coal tar. As gasification progressed, a decreasing trend in the water content and an increasing trend in the ash content were observed. The tars tested were characterized by large changes in the residue after coking and content of parts insoluble in toluene and by smaller fluctuations in the content of parts insoluble in quinoline. All tested samples were characterized by very high distillation losses, while for samples starting from the third day of gasification, a clear decrease in losses was visible. A chromatographic analysis showed that there were no major differences in composition between the tested tars and that none of the tar had a dominant component such as naphthalene in coal tar. The content of polycyclic aromatic hydrocarbons (PAHs) in UCG tars is several times lower than that in coal tar. No light monoaromatic hydrocarbons (benzene, toluene, ethylbenzene and xylenes—BTEX) were found in the analysed tars, which results from the fact that these compounds, due to their high volatility, did not separate from the process gas in the liquid product separator.


2019 ◽  
Vol 55 (78) ◽  
pp. 11719-11722 ◽  
Author(s):  
Jacob Olchowka ◽  
Long H. B. Nguyen ◽  
Thibault Broux ◽  
Paula Sanz Camacho ◽  
Emmanuel Petit ◽  
...  

Investigation of the effects of Al substitution for V on the structural properties and electrochemical performances for two of the most promising positive electrode materials for Na-ion batteries, Na3V2(PO4)2F3 and Na3V2(PO4)2FO2.


Author(s):  
I. A. Sofia Larsson ◽  
Anna-Lena Ljung ◽  
B. Daniel Marjavaara

AbstractThe flow field and coal combustion process in a pilot-scale iron ore pelletizing kiln is simulated using a computational fluid dynamics (CFD) model. The objective of the work is to investigate how the thermal effects from the flame affect the flow field. As expected, the combustion process with the resulting temperature rise and volume expansion leads to an increase of the velocity in the kiln. Apart from that, the overall flow field looks similar regardless of whether combustion is present or not. The flow field though affects the combustion process by controlling the mixing rates of fuel and air, governing the flame propagation. This shows the importance of correctly predicting the flow field in this type of kiln, with a large amount of process gas circulating, in order to optimize the combustion process. The results also justify the use of down-scaled, geometrically similar, water models to investigate kiln aerodynamics in general and mixing properties in particular. Even if the heat release from the flame is neglected, valuable conclusions regarding the flow field can still be drawn.


Author(s):  
M. Carlomagno ◽  
S. Rossin ◽  
M. Delvecchio ◽  
A. Anichini

Temporary conical strainers are widely employed in the Oil & Gas industry as filtering devices in the Centrifugal Compressors suction line. They protect compressor stages from the ingestion of foreign objects whether coming from dirty process gas or left in the pipeline after its construction. Very few literature and research papers are available on the fluid dynamic and structural performance of conical strainers. The purpose of this work is to plug this gap by the definition of a theoretical-experimental model for the characterization of the pressure drop and mechanical resistance of these devices. Starting from the definition of the main fluid dynamics and geometric variables which influence the performances, an experimental campaign has been performed in order to derive the relationship governing the pressure drop behavior. The model efficacy has been confirmed by a CFD analysis, which also allowed a qualitative insight review into the dynamics of velocity and turbulence intensity fields. Further tests have been performed in order to validate the model at off-design points. As far as the structural analysis is concerned, several FEM models and DOE techniques have been implemented in order to define relationships for bust pressure computation and feasible design improvements with respect to the current state of the art. Besides fluid dynamic and structural correlations, the notable achievements of this work are the definition of best pressure static probes positioning and the maximum clogging level that a strainer can withstand before collapse. Furthermore, some guidelines are given in order to prevent pipeline resonance and acoustic fatigue caused by the interaction between strainer turbulence and compressor inlet flow.


2012 ◽  
Vol 46 (19) ◽  
pp. 10614-10623 ◽  
Author(s):  
Drew E. Latta ◽  
Jonathan E. Bachman ◽  
Michelle M. Scherer

Author(s):  
M. A. Porter ◽  
D. H. Martens

The design requirements for a large shell and tube vertical heat exchanger (to be used in a sulfur recovery tail gas treatment unit) included startup, shutdown and upset conditions that would subject the exchanger to significant temperature changes. The exchanger was designed to the requirement of the ASME Boiler and Pressure Vessel Section VIII Division 1 [1]. A detailed analysis of the thermal profiles and related stresses was performed to confirm the use of a flexible tube sheet design. The heat exchanger uses high pressure superheated steam on the shell side to heat a low pressure process gas on the tube side. The heat exchanger was sized and thermally rated, using commercially available analysis software. The proposed design was analyzed by Finite Element methods that included both thermal and stress analysis. These evaluations confirmed that a flexible tube sheet design was satisfactory when using specific dimensions.


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