THE EFFECT OF ORGANIC MATTER FROM BROWN COAL ON BIOAVAILABILITY OF HEAVY METALS IN CONTAMINATED SOILS

Heavy metals (HMs) toxicity represents a global problem depending on the soil environment’s geochemical forms. Biochar addition safely reduces HMs mobile forms, thus, reducing their toxicity to plants. While several studies have shown that biochar could significantly stabilize HMs in contaminated soils, the study of the relationship of soil properties to potential mechanisms still needs further clarification; hence the importance of assessing a naturally contaminated soil amended, in this case with Paulownia biochar (PB) and Bamboo biochar (BB) to fractionate Pb, Cd, Zn, and Cu using short sequential fractionation plans. The relationship of soil pH and organic matter and its effect on the redistribution of these metals were estimated. The results indicated that the acid-soluble metals decreased while the fraction bound to organic matter increased compared to untreated pots. The increase in the organic matter metal-bound was mostly at the expense of the decrease in the acid extractable and Fe/Mn bound ones. The highest application of PB increased the organically bound fraction of Pb, Cd, Zn, and Cu (62, 61, 34, and 61%, respectively), while the BB increased them (61, 49, 42, and 22%, respectively) over the control. Meanwhile, Fe/Mn oxides bound represents the large portion associated with zinc and copper. Concerning soil organic matter (SOM) and soil pH, as potential tools to reduce the risk of the target metals, a significant positive correlation was observed with acid-soluble extractable metal, while a negative correlation was obtained with organic matter-bound metal. The principal component analysis (PCA) shows that the total variance represents 89.7% for the TCPL-extractable and HMs forms and their relation to pH and SOM, which confirms the positive effect of the pH and SOM under PB and BB treatments on reducing the risk of the studied metals. The mobility and bioavailability of these metals and their geochemical forms widely varied according to pH, soil organic matter, biochar types, and application rates. As an environmentally friendly and economical material, biochar emphasizes its importance as a tool that makes the soil more suitable for safe cultivation in the short term and its long-term sustainability. This study proves that it reduces the mobility of HMs, their environmental risks and contributes to food safety. It also confirms that performing more controlled experiments, such as a pot, is a disciplined and effective way to assess the suitability of different types of biochar as soil modifications to restore HMs contaminated soil via controlling the mobilization of these minerals.

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The influence of organic matter content of contaminated soils on the leaching rate of heavy metals

Environmental Progress ◽

10.1002/ep.670190118 ◽

2000 ◽

Vol 19 (1) ◽

pp. 53-58 ◽

Cited By ~ 34

Author(s):

M. C. M. Alvim Ferraz ◽

J. C. N. Lourençlo

Keyword(s):

Heavy Metals ◽

Organic Matter ◽

Contaminated Soils ◽

Organic Matter Content ◽

Matter Content ◽

Leaching Rate

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Bioremediation of Spent Engine Oil on Selected Contaminated Soils within Ilorin Metropolis

Advanced Journal of Graduate Research ◽

10.21467/ajgr.8.1.91-104 ◽

2020 ◽

Vol 8 (1) ◽

pp. 91-104

Author(s):

Elizabeth Adeyinka AJIBOYE ◽

Hikmat Omolara SULAYMAN ◽

Abdullahi Taiwo AJAO

Keyword(s):

Heavy Metals ◽

Organic Matter ◽

Organic Carbon ◽

Contaminated Soils ◽

Physicochemical Parameters ◽

Soil Samples ◽

Engine Oil ◽

Biochemical Tests ◽

Spent Engine Oil ◽

Before And After

The research aimed to investigate the bioremediation of spent engine oil on selected contaminated soils within Ilorin metropolis. To achieve this, soil samples were collected from three (3) mechanic workshops along Taiwo axis within the metropolis. The soil samples were then subjected to bioremediation using the land-farming approach. The physicochemical parameters of the soil samples before and after bioremediation were analyzed using standard methods. Bacteria were isolated using standard procedures and identified using biochemical tests and molecular methods. Results for the physicochemical parameters of the soil samples before bioremediation include particle size (all sandy in nature); pH (6.00 ± 0.14 - 6.20 ± 0.14); Organic carbon (14.65 ± 3.20 - 17.54 ± 1.87), Organic matter (33.50 ± 0.85 - 43.45 ± 9.12) and heavy metals (ND - 11.74 ± 0.07). Values after bioremediation for pH, organic carbon, organic matter and heavy metals were 8.25 ± 0.07 - 8.90 ± 0.14, 13.07 ± 0.05 - 13.25 ± 0.84, 37.25 ± 1.06 - 44.80 ± 1.13, ND - 9.40 ± 0.04 respectively. Values for bacterial count before and after bioremediation of the soil samples were 8.00 1.41 - 67.50 ± 2.12 x 105 CFU/mL and 6.50 ± 2.12 - 164.00 ± 11.31 x 105 CFU/mL respectively. Bacterial isolates were identified as Pseudomonas sp., Enterobacter sp., Acinetobacter sp., and Bacillus sp. while the hydrocarbon-utilizing bacteria were identified as Thalassospira mesophila strain JCM 18969; Pseudomonas fluorescens F113; Siccibacter turicensis LMG 23730; Pseudomonas Zeshuii strain KACC 15471; Pseudomonas stutzeri strain CGMCC 1.1803 and Marinobacter hydrocarbonoclasticus strain ATCC 49840. In conclusion, the bacteria isolates effectively bioremediated the spent engine oil contaminated soils with a reduction of hydrocarbon pollutants.

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THE INFLUENCE OF ORGANIC MATTER ON YIELD AND QUALITY OF WINTER WHEAT Triticum aestivum ssp. vulgare (L.) CULTIVATED ON SOILS CONTAMINATED WITH HEAVY METALS

Ecological Chemistry and Engineering S ◽

10.2478/eces-2013-0048 ◽

2013 ◽

Vol 20 (4) ◽

pp. 701-708

Author(s):

Danuta Leszczyńska ◽

Jolanta Kwiatkowska-Malina

Keyword(s):

Heavy Metals ◽

Triticum Aestivum ◽

Organic Matter ◽

Winter Wheat ◽

Brown Coal ◽

Organic Substance ◽

Farmyard Manure ◽

Liquid Form ◽

Yield And Quality ◽

Different Sources

Abstract The aim of this study was to determine the influence of organic matter from different sources on the yield of winter wheat and macroelements content in it. The experiment was carried out in stoneware pots sank into the ground filled up with 56.4 kg of soil: Haplic Luvisols formed from loamy sand. The soil was slightly acidic. The soil was mixed up with liquid form of salts: Cd(NO3)2, Pb(CH3COO)2 and ZnSO4. To the soil a brown coal preparation, so called “Rekulter”, brown coal, peat and farmyard manure were applied in the amount of 180, 140, 390 and 630 g per pot, which is equivalent to 5 Mg of organic carbon per ha. Winter wheat Triticum aestivum ssp. vulgare (L.) for grain was cultivated. The manurial value of organic substance originated from different sources expressed as the plants' crop was the highest for Rekulter and the lowest for peat. The addition of organic substance to soil contaminated with heavy metals causes the higher content of potassium, magnesium and nitrogen in winter wheat's grain. The content of calcium and sodium in winter wheat grain's did not depend from addition of organic matter to soil. Organic matter added into contaminated soil increased the uptake of main macroelements by winter wheat straw. Organic matter fertilization broadened the K: (Ca + Mg) ratio in grain and straw.

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Synergistic Effect of Rhamnolipid and Saponin Biosurfactants on Removal of Heavy Metals from Oil Contaminated Soils

Tenside Surfactants Detergents ◽

10.3139/113.110672 ◽

2020 ◽

Vol 57 (2) ◽

pp. 109-114

Author(s):

Amirhossein Dolatzadeh khiyavi ◽

Reza Hajimohammadi ◽

Hossein Amani ◽

Hadi Soltani

Keyword(s):

Heavy Metals ◽

Synergistic Effect ◽

Contaminated Soils ◽

Removal Of Heavy Metals

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The impact of urban effluents on the coastal marine environment of Mediterranean islands

Water Science & Technology ◽

10.2166/wst.1995.0673 ◽

1995 ◽

Vol 32 (9-10) ◽

pp. 85-94 ◽

Cited By ~ 1

Author(s):

Michael O. Angelidis

Keyword(s):

Heavy Metals ◽

Organic Matter ◽

Marine Environment ◽

Suspended Particle ◽

Pollution Source ◽

Mediterranean Islands ◽

Coastal Marine Environment ◽

Coastal Marine ◽

The Impact ◽

The City

The impact of the urban effluents of Mytilene (Lesvos island, Greece) on the receiving coastal marine environment, was evaluated by studying the quality of the city effluents (BOD5, COD, SS, heavy metals) and the marine sediments (grain size, organic matter, heavy metals). It was found that the urban effluents of Mytilene contain high organic matter and suspended particle load because of septage discharge into the sewerage network. Furthermore, although the city does not host important industrial activity, its effluents contain appreciable metal load, which is mainly associated with the particulate phase. The city effluents are discharged into the coastal marine environment and their colloidal and particulate matter after flocculation settles to the bottom, where is incorporated into the sediments. Over the years, the accumulation of organic matter and metals into the harbour mud has created a non-point pollution source in the relatively non-polluted coastal marine environment of the island. Copper and Zn were the metals which presented the higher enrichment in the sediments of the inner harbour of Mytilene.

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Chemical Properties of Heavy Metal-Contaminated Soils from a Korean Military Shooting Range: Evaluation of Pb Sources Using Pb Isotope Ratios

Applied Sciences ◽

10.3390/app11157099 ◽

2021 ◽

Vol 11 (15) ◽

pp. 7099

Author(s):

Inkyeong Moon ◽

Honghyun Kim ◽

Sangjo Jeong ◽

Hyungjin Choi ◽

Jungtae Park ◽

...

Keyword(s):

Heavy Metals ◽

Heavy Metal ◽

Contaminated Soils ◽

Management Strategies ◽

Chemical Properties ◽

Heavy Metal Concentration ◽

Soil Samples ◽

Shooting Range ◽

Geochemical Properties ◽

Mineral Phases

In this study, the geochemical properties of heavy metal-contaminated soils from a Korean military shooting range were analyzed. The chemical behavior of heavy metals was determined by analyzing the soil pH, heavy metal concentration, mineral composition, and Pb isotopes. In total, 24 soil samples were collected from a Korean military shooting range. The soil samples consist of quartz, albite, microcline, muscovite/illite, kaolinite, chlorite, and calcite. Lead minerals, such as hydrocerussite and anglesite, which are indicative of a transformation into secondary mineral phases, were not observed. All soils were strongly contaminated with Pb with minor concentrations of Cu, Ni, Cd, and Zn. Arsenic was rarely detected. The obtained results are indicated that the soils from the shooting range are contaminated with heavy metals and have evidences of different degree of anthropogenic Pb sources. This study is crucial for the evaluation of heavy metal-contaminated soils in shooting ranges and their environmental effect as well as for the establishment of management strategies for the mitigation of environmental risks.

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Enhanced Electrokinetic Remediation for the Removal of Heavy Metals from Contaminated Soils

Applied Sciences ◽

10.3390/app11041799 ◽

2021 ◽

Vol 11 (4) ◽

pp. 1799

Author(s):

Claudio Cameselle ◽

Susana Gouveia ◽

Adrian Cabo

Keyword(s):

Heavy Metals ◽

Citric Acid ◽

Organic Acids ◽

Contaminated Soils ◽

Electrokinetic Remediation ◽

Deionized Water ◽

Soil Specimen ◽

Removal Of Heavy Metals ◽

Ph Conditions ◽

Neutral Metal

The electrokinetic remediation of an agricultural soil contaminated with heavy metals was studied using organic acids as facilitating agents. The unenhanced electrokinetic treatment using deionized water as processing fluid did not show any significant mobilization and removal of heavy metals due to the low solubilization of metals and precipitation at high pH conditions close to the cathode. EDTA and citric acid 0.1 M were used as facilitating agents to favor the dissolution and transportation of metals. The organic acids were added to the catholyte and penetrated into the soil specimen by electromigration. EDTA formed negatively charged complexes. Citric acid formed neutral metal complexes in the soil pH conditions (pH = 2–4). Citric acid was much more effective in the dissolution and transportation out of the soil specimen of complexed metals. In order to enhance the removal of metals, the concentration of citric acid was increased up to 0.5 M, resulting in the removal of 78.7% of Cd, 78.6% of Co, 72.5% of Cu, 73.3% of Zn, 11.8% of Cr and 9.8% of Pb.

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