Effect of Hydrotreating Reaction Conditions on Viscosity, API Gravity and Specific Gravity of Maya Crude Oil

Author(s):  
Yanet Villasana ◽  
Sergio Ramírez ◽  
Jorge Ancheyta ◽  
Joaquín L. Brito
2019 ◽  
Vol 10 (01) ◽  
pp. 20-27
Author(s):  
Dian Kurnia Sari ◽  
Rian Ternando

Minyak bumi dievaluasi guna menentukan potensi minyak bumi sebagai bahan baku kilang minyak untuk menghasilkan fraksi yang dikehendaki. Evaluasi yang dilakukan meliputi pengujian sifat umum minyak bumi, klasifikasi minyak bumi dengan distilasi True Boiling Point (TBP) wide cut (pemotongan jarak lebar) serta analisis fraksi kerosin. Fraksi kerosin yang dihasilkan dari primary process dapat diolah menjadi bahan bakar rumah tangga (minyak  tanah) dan bahan bakar lampu penerangan. Selain itu fraksi kerosin juga dapat dioalah menjadi bahan bakar untuk pesawat terbang jenis jet (avtur). Avtur adalah kerosin yang dengan  spesifikasi yang diperketat, terutama mengenai titik uap dan titik beku. Untuk melakukan pengolahan pada minyak bumi perlu diketahui karakteristik dan spesifikasi minyak  bumi (bahan baku) yang akan diolah untuk mengetahui mutu dan manfaat minyak bumi tersebut. Salah satu parameter uji analisis minyak bumi yaitu parameter sifat fisika. Dari data distilasi TBP diperoleh persentase fraksi kerosin Crude Oil 99 PT HS sebesar 29 % vol sedangkan Crude Oil 165 PT RT sebesar 23 % vol. Berdasarkan analisis sifat fisika yang meliputi Specific Gravity, Refractive Index nD20, Freezing Point, Smoke Point, Flash Point “Abel”, Aniline Point, Copper Strip Corrosion, Kinematic Viscosity dan Characterization KUOP. Crude Oil 99 dan Crude Oil 165 memiliki mutu yang baik serta memenuhi spesifikasi produk kerosin maupun produk avtur.


2020 ◽  
Vol 53 (2D) ◽  
pp. 42-52
Author(s):  
Ahmed Khudhair

Drilling waste is a vital and persistent problem found in the petroleum industry which is mainly related to drilling and oil production. When drilling fluids ruminants are discharged on the ground, human health is affected by the toxic of oil contamination and the chemicals of liquid fraction ruin organisms functional and contaminate the groundwater as a result of seeping. A microwave technique was used to treat the remain drill cuttings resulting from drilling fluid. Whereas amounts of drill cuttings were taken from the southern Rumaila oilfields, prepared for testing and fixed with 100 gm per sample and contaminated with two types of crude oil, one from the southern Rumaila oilfields with Specific gravity of 0.882 and the other crude oil from the eastern Baghdad oilfield of Specific gravity 0.924. The concentrations of 7.5%, 10%, 12.5% ​​and 15% w/w in mass was chosen to be the pollution percentage. Samples were treated in the microwave with different power applied of 180, 540, and 900 watt and a time period of 50 minutes is divided into 5 parts for analysis 0, 10, 20, 30 and 50 min. the purpose of this study was trying to reach the zero-discharge concept treatment or near. It was found that the results of 22 sample reached below 1% w/w in mass, except for two samples of 180-watt power applied and oil contamination of 15% w/w in mass they reached about 1.5-1% w/w in mass. The results show a great declination in oil contamination even with highest pollution with lower power applied.


Catalysts ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 1118
Author(s):  
Martin Hájek ◽  
Aleš Vávra ◽  
Héctor de Paz Carmona ◽  
Jaroslav Kocík

This review paper summarizes the current state-of-the-art of the chemical transformation of oils/fats (i.e., triacylglycerols) to the use of biofuels or bio-lubricants in the means of transport, which is a novelty. The chemical transformation is necessary to obtain products that are more usable with properties corresponding to fuels synthesized from crude oil. Two types of fuels are described—biodiesel (the mixture of methyl esters produced by transesterification) and green diesel (paraffins produced by hydrogenation of oils). Moreover, three bio-lubricant synthesis methods are described. The transformation, which is usually catalysed, depends on: (i) the type and composition of the raw material, including alcohols for biodiesel production and hydrogen for green diesel; (ii) the type of the catalyst in the case of catalysed reactions; (iii) the reaction conditions; and (iv) types of final products. The most important catalysts, especially heterogeneous and including reaction conditions, for each product are described. The properties of biodiesel and green diesel and a comparison with diesel from crude oil are also discussed.


1999 ◽  
Vol 2 (03) ◽  
pp. 255-265 ◽  
Author(s):  
Ridha B.C. Gharbi ◽  
Adel M. Elsharkawy

Summary The importance of pressure/volume/temperature (PVT) properties, such as the bubblepoint pressure, solution gas-oil ratio, and oil formation volume factor, makes their accurate determination necessary for reservoir performance calculations. An enormous amount of PVT data has been collected and correlated over many years for different types of hydrocarbon systems. Almost all of these correlations were developed with linear or nonlinear multiple regression or graphical techniques. Artificial neural networks, once successfully trained, offer an alternative way to obtain reliable results for the determination of crude oil PVT properties. In this study, we present neural-network-based models for the prediction of PVT properties of crude oils from the Middle East. The data on which the network was trained represent the largest data set ever collected to be used in developing PVT models for Middle East crude oils. The neural-network model is able to predict the bubblepoint pressure and the oil formation volume factor as a function of the solution gas-oil ratio, the gas specific gravity, the oil specific gravity, and the temperature. A detailed comparison between the results predicted by the neural-network models and those predicted by other correlations are presented for these Middle East crude-oil samples. Introduction In absence of experimentally measured pressure/volume/temperature (PVT) properties, two methods are widely used. These methods are equation of state (EOS) and PVT correlations. The equation of state is based on knowing the detailed compositions of the reservoir fluids. The determination of such quantities is expensive and time consuming. The equation of state involves numerous numerical computations. On the other hand, PVT correlations are based on easily measured field data: reservoir pressure, reservoir temperature, oil, and gas specific gravity. In the petroleum process industries, reliable experimental data are always to be preferred over data obtained from correlations. However, very often reliable experimental data are not available, and the advantage of a correlation is that it may be used to predict properties for which very little experimental information is available. The importance of accurate PVT data for material-balance calculations is well understood. It is crucial that all calculations in reservoir performance, in production operations and design, and in formation evaluation be as good as the PVT properties used in these calculations. The economics of the process also depends on the accuracy of such properties. The development of correlations for PVT calculations has been the subject of extensive research, resulting in a large volume of publications.1–10 Several graphical and mathematical correlations for determining the bubblepoint pressure (Pb) and the oil formation volume factor (Bob) have been proposed during the last five decades. These correlations are essentially based on the assumption that P b and Bob are strong functions of the solution gas-oil ratio (Rs) the reservoir temperature (T), the gas specific gravity (?g) and the oil specific gravity (?o) or P b = f 1 ( R s , T , γ g , γ o ) , ( 1 ) B o b = f 2 ( R s , T , γ g , γ o ) . ( 2 ) In 1947, Standing1 presented graphical correlations for the determination of bubblepoint pressure (Pb) and the oil formation volume factor (Bob) In developing these correlations, Standing used 105 experimentally measured data points from 22 different crude-oil and gas mixtures from California oil fields. Average relative errors of 4.8% and of 1.17% were reported for Pb and Bob respectively. Later, in 1958, Lasater9 developed an empirical equation based on Henry's law for estimating the bubblepoint pressure. He correlated the mole fraction of gas in solution to a bubblepoint pressure factor. A total of 137 crude-oil and gas mixtures from North and South America was used for developing this correlation. An average error of 3.8% was reported. Lasater did not present a correlation for Bob In 1980, two sets of correlations were reported, one by Vasquez and Beggs10 and the other by Glasø.7 Vasquez and Beggs used 600 data points from various locations all over the world to develop correlations for Pb and Bob. Two different types of correlations were presented, one for crudes with °API>30 and the other for crudes with °API 30. An average error of 4.7% was reported for their correlation of Bob Glasø used a total of 45 oil samples from the North Sea to develop his correlations for calculating Pb and Bob. He reported an average error of 1.28% for the bubblepoint pressure and ?0.43% for the formation volume factor. Recently, Al-Marhoun4 used 160 experimentally determined data points from the PVT analysis of 69 Middle Eastern hydrocarbon mixtures to develop his correlations. Average errors of 0.03% and ?0.01% were reported for Pb and Bob respectively. Dokla and Osman6 used a total of 50 data points from reservoirs in the United Arab Emirates to develop correlations for Pb and Bob. They reported an average error of 0.45% for the bubblepoint pressure and 0.023% for the formation volume factor. The conventional approach to develop PVT correlations is based on multiple-regression techniques. An alternative approach will be to use an artificial neural network (ANN). PVT models based on a successfully trained ANN can be excellent, reliable tools for the prediction of crude-oil PVT properties. The massive interconnections in the ANN produces a large number of degrees of freedom, or fitting parameters, and thus may allow it to capture the system's nonlinearity better than conventional regression techniques. Recently, artificial neural networks have found use in a number of areas in petroleum engineering.11–20 The objective of this study is to use ANNs to develop accurate PVT correlations for Middle East crude oil to estimate Pb and Bob as functions of Rs, T, ?g, ?o. With additional experimental data, the neural-network model can be further refined to incorporate these new data. In addition, in this article we evaluate the accuracy of the ANN models developed in this study compared to other PVT correlations.


2020 ◽  
Vol 10 (02) ◽  
pp. 23-30
Author(s):  
Dian Kurnia Sari ◽  
Nidia Sauqi

Pada penelitian ini dilakukan pengujian demulsifier untuk proses demulsifikasi crude oil Bentayan, agar diperoleh nilai pemisahan air yang baik. Karakteristik fisika dan kimia seperti specific gravity, pour point, viscosity kinematic, asphaltene content dan basic sediment and water (BS&W) menunjukkan bahwa crude oil Bentayan adalah heavy medium crude oil dan mempunyai emulsi yang sangat stabil dengan jenis emulsi air dalam minyak W/O. Demulsifier yang digunakan ialah demulsifier A dan demulsifier B dimana untuk mengetahui pengaruh dari demulsifier tersebut terhadap crude oil Bentayan maka dilakukan pengujian bottle test demulsifier dengan pengaruh konsentrasi demulsifier, temperatur pengujian, waktu interaksi dan nilai basic sediment and water (BS&W). Dari pengujian tersebut didapatkan pemisahan air yang baik terjadi pada konsentrasi 30 ppm, temperatur pengujian 60 oC dan waktu interaksi (settling time) 60 menit. Pada crude oil Bentayan proses demulsifikasi yang baik menggunakan demulsifier B dibandingkan dengan demulsifier A dimana demulsifier B menunjukkan % waterdrop mencapai 100 %, % interface adalah 0 % dan % BS&W sebesar 0,1 %vol. Hal ini juga memungkinkan demulsifier B lebih baik dilihat dari pengujian fourier transform infra red (FTIR) dimana demulsifier B mempunyai gugus -OH yang memungkinkan dapat mengikat air dari crude oil Bentayan. Dengan hasil tersebut maka dapat diketahui bahwasanya demulsifier B lebih baik pada proses demulsifikasi crude oil Bentayan.


2019 ◽  
Vol 5 (3) ◽  
pp. 662 ◽  
Author(s):  
Arwa Ossama Shakir ◽  
Haifaa Abd Al-Rasool Ali

The main objectives of current work are to reduce the permeability of clayey soil for different fluid (water and crude oil) and to predict its efficiency for petroleum storage. Current research uses a sodium bentonite (B) with percentage (1.5, 3 and 6%) by the dry weight of soil and coal tar extended epoxy resin coating as the lining material. The soil sample was brought from AL -Nahrawan region. Soil's permeability for petrol was studied through using compacted soil model and making a central hole (core) in it with changing its dimensions (diameter, thickness of wall and base), type of fluid and number of filling cycles. After filling the core with these fluids, the volume losses of fluids were measured per day. When two cycles were finished, a sample was taken from the base of the core to be examined in a consolidation test. Number of laboratory tests have been conducted such as (Atterberg limits, compaction test, consolidation, sieve analysis and specific gravity).The results showed that the increase in bentonite percentage causes an increase in (optimum moisture content, Atterberg limit and specific gravity) and also decreasing in (max dry unit weight and permeability) as the fluid was water. However, an increase in permeability was obtained using the crude oil. A reduction in volume losses was observed when using the lining material, coal tar extended epoxy resin coating.


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