Contribution of Zeolite to Deterioration of Pelitic Rocks from Asu-River Group and Variation of the Deterioration with Water Sorption

Author(s):  
Tochukwu A. S. Ugwoke
Keyword(s):  
GEOgraphia ◽  
2018 ◽  
Vol 19 (41) ◽  
pp. 123
Author(s):  
Gustavo Souza Valladares ◽  
Cláudia Maria Sabóia de Aquino ◽  
Renê Pedro de Aquino ◽  
Raphael Moreira Beirigo

Resumo: O Parque Nacional da Serra da Capivara (PNSC) tem alguns dos sítios arqueológicos mais importantes das Américas. A área onde os solos foram amostrados corresponde ao Parque Nacional da Serra da Capivara (PNSC) e uma área tampão de 10km no entorno de seus limites oficiais, no sudeste do Piauí. Para a elaboração do presente trabalho foram selecionados solos considerados frágeis, devido ao alto risco de degradação por erosão, formados de diferentes materiais geológicos representativos do PNSC. Todos os solos estudados são pouco evoluídos, com desenvolvimento pedogenético ainda incipiente, e enquadram-se nas ordens dos Neossolos ou Cambissolos. O bioma representativo da área de estudo é a caatinga, que pela vegetação com pouca biomassa e características decíduas confere pouca cobertura aos solos, aumentando a susceptibilidade dos mesmos à erosão. Foram coletados sete perfis de solos, em diferentes posições na paisagem e formados de materiais de origem. As amostras foram secas ao ar e analisados atributos químicos e granulométricos. Os solos estudados apresentam grandes variações em seus atributos morfológicos, químicos e granulométricos, reflexo dos diferentes materiais de origem. A fragilidade em quase todos os perfis é reflexo da incipiência dos solos, representada pelo baixo grau de agregação e coesão entre as partículas, pequena profundidade e o fator de formação relevo induz na maior erosão de cinco dos sete perfis estudados. Os solos frágeis do PNSC necessitam de cuidados especiais quanto ao manejo, pois alguns deles, principalmente os originários de rochas pelíticas da Formação Pimenteiras, encontram-se em forte processo de degradação, em muitas áreas com as rochas expostas. Palavras-chave: Conservação do solo. Classificação de solos. Degradação ambiental. Semiárido tropical. FRAGILE SOILS OF SERRA DA CAPIVARA NATIONAL PARK, PIAUÍ Abstract: The Serra da Capivara National Park (PNSC) are some of the most important archaeological sites in the Americas. The area where the soils were sampled corresponds to the PNSC and a buffer area of 10km around of its official limits in southeastern of Piauí. For this work were considered fragile soils, due to the high risk of degradation by erosion, formed in different geological materials representative of PNSC. All soils are poorly evolved, with pedogenic development incipient fall in orders of Entisols or Inceptisols. The representative of the study area biome is the caatinga, which vegetation with little biomass and deciduous characteristics, gives little coverage to the soil, increasing susceptibility to erosion. Seven soil profiles were collected at different positions and mother rocks. The soils were classified according to the Brazilian System of Soil Classification (SiBCS). The samples were air dried and analyzed the chemical attributes and texture. The soils vary widely in their morphological, chemical and grain size, reflecting the different source material attributes. The weakness in nearly all profiles reflects the incipient soil, represented by a low degree of aggregation and cohesion between the particles of soil and small depth of relief factor induces the formation of further erosion profiles 5 of the 7 studied. Fragile soils of PNSC require special care in the mangement, because some soils, especially those originating from pelitic rocks by Pimenteiras Formation, are in strong degradation process in many areas with exposed rocks. Keywords: Soil conservation. Soil classification. Environmental degradation. Tropical semiarid. SUELOS FRÁGILES DEL PARQUE NACIONAL DE LA SIERRA DE CAPYBARA, PIAUÍ Resumen: El Parque Nacional de la Sierra de Capybara (PNSC) tiene algunos de los sitios arqueológicos más importantes de las Américas. El área donde los suelos fueron muestreados corresponde al PNSC y un área tampón de 10km en el entorno de sus límites oficiales, en el sureste del Piauí. Para la elaboración del presente trabajo se seleccionaron suelos considerados frágiles, debido al alto riesgo de degradación por erosión, formados de diferentes materiales geológicos representativos del PNSC. Todos los suelos estudiados son poco evolucionados, con desarrollo pedogenético aún incipiente, y se encuadran en las órdenes de los Neossolos o Cambissolos (en portugués). El bioma representativo del área de estudio es la caatinga, que por la vegetación con poca biomasa y características deciduas, confiere poca cobertura a los suelos, aumentando la susceptibilidad de los mismos a la erosión. Se recogieron muestras de siete perfiles de suelos, en diferentes posiciones en el paisaje y formados de materiales geológicos distintos. Las muestras fueron secas al aire y analizados los atributos químicos y granulométricos. Los suelos estudiados presentan grandes variaciones en sus atributos morfológicos, químicos y granulométricos, reflejo de los diferentes materiales de origen. La fragilidad en casi todos los perfiles es reflejo de la incipiente de los suelos, representada por el bajo grado de agregación y cohesión entre las partículas, pequeña profundidad y el factor de formación relieve induce en la mayor erosión de cinco de los siete perfiles estudiados. Los suelos frágiles del PNSC necesitan cuidados especiales en cuanto al manejo, pues algunos de ellos, principalmente los originarios de rocas pelíticas de la Formación Pimenteiras, se encuentran en fuerte proceso de degradación, en muchas áreas con las rocas expuestas. Palabras clave: Conservación del suelo. Clasificación de suelos. Degradación ambiental. Semiárido tropical.


Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 2817
Author(s):  
Biao Yu ◽  
Jingwei He ◽  
Sufyan Garoushi ◽  
Pekka K. Vallittu ◽  
Lippo Lassila

In order to improve the toughness and reduce polymerization shrinkage of traditional bisphenol A-glycidyl methacrylate (Bis-GMA)/triethylene glycol dimethacrylate (TEGDMA) based dental resin system, a hyperbranched thiol oligomer (HMDI-6SH) was synthesized via thiol-isocyanate click reaction using pentaerythritol tetra(3-mercaptopropionate (PETA) and dicyclohexylmethane 4,4′-diisocyanate (HMDI) as raw materials. Then HMDI-6SH was mixed with 1,3,5-Triallyl-1,3,5-Triazine-2,4,6(1H,3H,5H)-Trione (TTT) to prepare thiol-ene monomer systems, which were added into Bis-GMA/TEGDMA resins with different mass ratio from 10 wt% to 40 wt% to serve as anti-shrinking and toughening agent. The physicochemical properties of these thiol-ene-methacrylate ternary resins including functional groups conversion, volumetric shrinkage, flexural properties, water sorption, and water solubility were evaluated. The results showed that the incorporation of HMDI/TTT monomer systems into Bis-GMA/TEGDMA based resin could improve C=C double bond conversion from 62.1% to 82.8% and reduced volumetric shrinkage from 8.53% to 4.92%. When the mass fraction of HMDI/TTT monomer systems in the resins was no more than 20 wt%, the flexural strength of the resin was higher or comparable to Bis-GMA/TEGDMA based resins (p > 0.05). The toughness (it was measured from the stress–strain curves of three-point bending test) of the resins was improved. Water sorption and water solubility tests showed that the hydrophobicity of resin was enhanced with increasing the content of thioester moiety in resin.


2021 ◽  
pp. 000370282110282
Author(s):  
Daitaro Ishikawa ◽  
Jiamin Yang ◽  
Tomoyuki Fujii

The purpose of this study was to understand the ordered structure of starch in rice flour based on a physical modification with non-heating, milling, and water sorption through the structural evaluation of rice flour using small-angle X-ray scattering (SAXS) and infrared spectroscopy within the 4000–100 cm−1 region. The SAXS pattern of the samples with low moisture contents subjected to milling yield a band within the 0.4–0.9 nm−1 of the q range owing to a lamellar repeat of starch with an ordered structure in rice flour. We proposed an order parameter using the intensity of the SAXS band to quantify the order structure of starch in rice flour, and the true density was negatively correlated with the order parameter. Infrared band at 990 cm−1 in COH bending mode applied to the hydroxyl group of C6 shifted to a low wavenumber corresponding to the order parameter. A linear correlation was found between the order parameter and the 990 cm−1 and band at 861 cm−1 owing to COC symmetrical stretching of glycoside bond and CH2 deformation of the glucose unit of starch, 572, 472, and 436 cm−1, owing to the pyranose ring in the glucose unit of starch. The identified infrared bands are effective for quantifying the ordered structure of starch at the lamellar level. When subjected to water sorption, the band position at 990 cm−1 shifted to a higher wavenumber above a water activity of 0.7. This result revealed that the water-induced transition of glass to rubber of starch in rice flour can be clearly evaluated through infrared spectroscopy using the band at 990 cm−1. In addition, the band at 861 cm−1 also shifted to a higher wavenumber, whereas those at 572 and 436 cm−1 did not show a significant shift. These results indicate that water sorption slightly affects the internal structure and may mainly affect the surface of starch.


Author(s):  
D. C. Gornig ◽  
R. Maletz ◽  
P. Ottl ◽  
M. Warkentin

Abstract Objective The aim of the study was to evaluate the influence of filler content, degradation media and time on the mechanical properties of different dental composites after in vitro aging. Materials and Methods Specimens (1 mm3) of three commercially available composites (GrandioSO®, Arabesk Top®, Arabesk Flow®) with respect to their filler content were stored in artificial aging media: artificial saliva, ethanol (60%), lactic acid (pH 5) and citric acid (pH 5). Parameters (Vickers microhardness, compressive strength, elastic modulus, water sorption and solubility) were determined in their initial state (control group, n = 3 for microhardness, n = 5 for the other parameters) and after 14, 30, 90 and 180 days (n = 3 for microhardness, n = 5 for the other parameters for each composite group, time point and media). Specimens were also characterized with dynamic-mechanical-thermal analysis (compression tests, F =  ± 7 N; f = 0.5 Hz, 1 Hz and 3.3 Hz; t = 0–170 °C). Results Incorporation of fillers with more than 80 w% leads to significantly better mechanical properties under static and dynamic compression tests and a better water sorption behavior, even after chemical degradation. The influence of degradation media and time is of subordinate importance for chemical degradation. Conclusion Although the investigated composites have a similar matrix, they showed different degradation behavior. Since dentine and enamel occur only in small layer thickness, a test specimen geometry with very small dimensions is recommended for direct comparison. Moreover, the use of compression tests to determine the mechanical parameters for the development of structure-compatible and functionally adapted composites makes sense as an additional standard. Clinical relevance Preferential use of highly filled composites for occlusal fillings is recommended.


Polymers ◽  
2021 ◽  
Vol 13 (15) ◽  
pp. 2517
Author(s):  
Anatoliy Olkhov ◽  
Olga Alexeeva ◽  
Marina Konstantinova ◽  
Vyacheslav Podmasterev ◽  
Polina Tyubaeva ◽  
...  

Biocompatible glycero (9,10-trioxolane) trioleate (ozonide of oleic acid triglyceride, OTOA) was incorporated into polylactic acid (PLA) fibers by electrospinning and nonwoven PLA mats with 1%, 3% and 5% OTOA content. The morphological, mechanical, thermal and water sorption properties of electrospun PLA mats after the addition of OTOA were studied. A morphological analysis showed that the addition of OTOA increased the average fiber diameter and induced the formation of pores on the fiber surface, leading to an increase in the specific surface area for OTOA-modified PLA fibrous mats. PLA fiber mats with 3% OTOA content were characterized by a highly porous surface morphology, an increased specific surface area and high-water sorption. Differential scanning calorimetry (DSC) was used to analyze the thermal properties of the fibrous PLA mats. The glass transition temperatures of the fibers from the PLA–OTOA composites decreased as the OTOA content increased, which was attributed to the plasticizing effect of OTOA. DSC results showed that OTOA aided the PLA amorphization process, thus reducing the crystallinity of the obtained nonwoven PLA–OTOA materials. An analysis of the mechanical properties showed that the tensile strength of electrospun PLA mats was improved by the addition of OTOA. Additionally, fibrous PLA mats with 3% OTOA content showed increased elasticity compared to the pristine PLA material. The obtained porous PLA electrospun fibers with the optimal 3% OTOA content have the potential for various biomedical applications such as drug delivery and in tissue engineering.


2021 ◽  
Author(s):  
Deepa Agarwal ◽  
William MacNaughtan ◽  
Julie King ◽  
Tim J. Foster

This research investigate the structural and functional differences between four main wheat cultivars in comparison to the wild relatives of wheat. “Wheat image from www.freepik.com.”


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