Chemical compositions of tourmaline in the vein-type tungsten deposits of the kaneuchi mine, Japan

1984 ◽  
Vol 19 (4) ◽  
Author(s):  
Y. Shibue
1993 ◽  
Vol 8 (3-4) ◽  
pp. 233-246 ◽  
Author(s):  
Liu Yingjun ◽  
Ma Dongsheng
Keyword(s):  

Geofluids ◽  
2017 ◽  
Vol 2017 ◽  
pp. 1-11 ◽  
Author(s):  
Xiangchong Liu ◽  
Huilin Xing ◽  
Dehui Zhang

Wolframite is the main ore mineral at the vein-type tungsten deposits in the Nanling Range, which is a world-class tungsten province. It is disputed how wolframite is precipitated at these deposits and no one has yet studied the links of the mechanical processes to fluid flow and mineralization. Finite element-based numerical experiments are used to investigate the influences of a hydraulic fracturing process on fluid flow and solubility of CO2and quartz. The fluids are aqueous NaCl solutions and fluid pressure is the only variable controlling solubility of CO2and quartz in the numerical experiments. Significant fluctuations of fluid pressure and high-velocity hydrothermal pulse are found once rock is fractured by high-pressure fluids. The fluid pressure drop induced by hydraulic fracturing could cause a 9% decrease of quartz solubility. This amount of quartz deposition may not cause a significant decrease in rock permeability. The fluid pressure decrease after hydraulic fracturing also reduces solubility of CO2by 36% and increases pH. Because an increase in pH would cause a major decrease in solubility of tungsten, the fluid pressure drop accompanying a hydraulic fracturing process facilitates wolframite precipitation. Our numerical experiments provide insight into the mechanisms precipitating wolframite at the tungsten deposits in the Nanling Range as well as other metals whose solubility is strongly dependent on pH.


Author(s):  
D.I. Potter ◽  
M. Ahmed ◽  
K. Ruffing

Ion implantation, used extensively for the past decade in fabricating semiconductor devices, now provides a unique means for altering the near-surface chemical compositions and microstructures of metals. These alterations often significantly improve physical properties that depend on the surface of the material; for example, catalysis, corrosion, oxidation, hardness, friction and wear. Frequently the mechanisms causing these beneficial alterations and property changes remain obscure and much of the current research in the area of ion implantation metallurgy is aimed at identifying such mechanisms. Investigators thus confront two immediate questions: To what extent is the chemical composition changed by implantation? What is the resulting microstructure? These two questions can be investigated very fruitfully with analytical electron microscopy (AEM), as described below.


Author(s):  
Gejing Li ◽  
D. R. Peacor ◽  
D. S. Coombs ◽  
Y. Kawachi

Recent advances in transmission electron microscopy (TEM) and analytical electron microscopy (AEM) have led to many new insights into the structural and chemical characteristics of very finegrained, optically homogeneous mineral aggregates in sedimentary and very low-grade metamorphic rocks. Chemical compositions obtained by electron microprobe analysis (EMPA) on such materials have been shown by TEM/AEM to result from beam overlap on contaminant phases on a scale below resolution of EMPA, which in turn can lead to errors in interpretation and determination of formation conditions. Here we present an in-depth analysis of the relation between AEM and EMPA data, which leads also to the definition of new mineral phases, and demonstrate the resolution power of AEM relative to EMPA in investigations of very fine-grained mineral aggregates in sedimentary and very low-grade metamorphic rocks.Celadonite, having end-member composition KMgFe3+Si4O10(OH)2, and with minor substitution of Fe2+ for Mg and Al for Fe3+ on octahedral sites, is a fine-grained mica widespread in volcanic rocks and volcaniclastic sediments which have undergone low-temperature alteration in the oceanic crust and in burial metamorphic sequences.


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