An effective synthesis method for secondary fluorinated alcohols via the reaction of esters of polyfluorinated acids with trialkylalanes

1992 ◽  
Vol 41 (10) ◽  
pp. 1834-1835
Author(s):  
O. G. Khomutov ◽  
V. I. Filyakova ◽  
A. V. Kuchin ◽  
K. I. Pashkevich ◽  
GA. Tolstikov
Molecules ◽  
2015 ◽  
Vol 20 (12) ◽  
pp. 21458-21463 ◽  
Author(s):  
Junren Zhang ◽  
Qizheng Yao ◽  
Zuliang Liu

Nanoscale ◽  
2020 ◽  
Vol 12 (29) ◽  
pp. 15896-15904 ◽  
Author(s):  
Xue Bai ◽  
Tao Li ◽  
Umair Gulzar ◽  
Eleonora Venezia ◽  
Lin Chen ◽  
...  

In order to push forward the concept of sodium-ion batteries, a facile and cost effective synthesis method for achieving high performance anodes has been developed based on a dual modification of pristine anatase TiO2.


Author(s):  
Fatih Izzul Haq ◽  
◽  
Muhammad Aldin Nur Zein ◽  
Rachel Gabriella ◽  
Silmi Ridwan Putri ◽  
...  

Today, the application of NiFe2O4 nanoparticles is increasing in the field of technology that is in great demand, thereby increasing the demand for industrial production. The use of NiFe2O4 nanoparticles can be applied in various technologies, including aqueous batteries. Therefore, an effective method for industrial production is needed. This paper aims to discuss and compare a more efficient method in the synthesis of NiFe2O4. The research method used is a literature review of 62 papers. There are several NiFe2O4 synthesis methods, namely Coprecipitation, Citrate Precursor Technique, Mechanical Alloying, Hydrothermal, Sonochemistry, Reverse Micelle, Sol-Gel, and Pulsed Wire Discharge. The results show that the effective synthesis method of NiFe2O4 is Hydrothermal. This is because the hydrothermal method is economically feasible, environmentally friendly, and has no requirement of high temperatures in the calcination process to produce the final product. The nanoparticle size is around 29.39 nm. This paper is expected to assist in selecting the synthesis method of NiFe2O4.


2020 ◽  
Vol 56 (74) ◽  
pp. 10875-10878
Author(s):  
Yasun Jing ◽  
Zhenru Deng ◽  
Xiuyun Yang ◽  
Leijiao Li ◽  
Ying Gao ◽  
...  

Novel 2D polydopamine nanosheets were successfully prepared by using a simple but effective synthesis method. The polydopamine nanosheets exhibit excellent multiple free radical scavenging activities and skin wound healing promoting action.


2016 ◽  
Vol 6 (6) ◽  
pp. 1701-1709 ◽  
Author(s):  
Pillaiyar Puthiaraj ◽  
Wha-Seung Ahn

Cu NPs immobilized on a microporous covalent triazine polymer obtained by a cost-effective synthesis method were evaluated as a catalyst for Ullmann coupling of O-arylation.


2015 ◽  
Vol 1120-1121 ◽  
pp. 1350-1355
Author(s):  
Hui Li ◽  
Shao Jun Shi ◽  
Xuan Wang ◽  
Yong Zhu ◽  
Ning Yu ◽  
...  

Nondestructive determination of Au in gold ornaments mainly takes density method and X ray fluorescence spectrometer with energy dispersion (EDXRF), which exists disadvantages. This paper based on the principle of crystallography, deduced the mathematical relationship between the crystallographic parameters, the density and the impurities content in gold jewelry alloys, then introduced the results by density testing and determination of Ag and Cu by EDXRF into the mathematical relationship, and obtained the gold weight percent in gold jewelry alloys. The results show that obtained the gold weight percent and determination of Au by fire assay are almost consistent, which the error is less than 0.12 %, so establishes a synthesis method of determination of Au by EDXRF and density testing, solves the disadvantages which EDXRF only detects on gold jewelry surface and small area, and density testing cannot detect gold jewelry alloy and demands that jewelry shape is simple, and provides an effective synthesis way for determination of Au in gold jewelry alloys.


2021 ◽  
Author(s):  
Ansgar Bokel ◽  
Michael C. Hutter ◽  
Vlada B. Urlacher

Engineered cytochrome P450 monooxygenase CYP154E1 enables the effective synthesis of the potential antidepressant (2R,6R)-hydroxynorketamine via N-demethylation and regio- and stereoselective hydroxylation of (R)-ketamine.


MRS Advances ◽  
2020 ◽  
Vol 5 (57-58) ◽  
pp. 2961-2972
Author(s):  
P.C. Meléndez-González ◽  
E. Garza-Duran ◽  
J.C. Martínez-Loyola ◽  
P. Quintana-Owen ◽  
I.L. Alonso-Lemus ◽  
...  

In this work, low-Pt content nanocatalysts (≈ 5 wt. %) supported on Hollow Carbon Spheres (HCS) were synthesized by two routes: i) colloidal conventional polyol, and ii) surfactant-free Bromide Anion Exchange (BAE). The nanocatalysts were labelled as Pt/HCS-P and Pt/HCS-B for polyol and BAE, respectively. The physicochemical characterization of the nanocatalysts showed that by following both methods, a good control of chemical composition was achieved, obtaining in addition well dispersed nanoparticles of less than 3 nm TEM average particle size (d) on the HCS. Pt/HCS-B contained more Pt0 species than Pt/HCS-P, an effect of the synthesis method. In addition, the structure of the HCS remains more ordered after BAE synthesis, compared to polyol. Regarding the catalytic activity for the Oxygen Reduction Reaction (ORR) in 0.5 M KOH, Pt/HCS-P and Pt/HCS-B showed a similar performance in terms of current density (j) at 0.9 V vs. RHE than the benchmark commercial 20 wt. % Pt/C. However, Pt/HCS-P and Pt/HCS-B demonstrated a 6 and 5-fold increase in mass catalytic activity compared to Pt/C, respectively. A positive effect of the high specific surface area of the HCS and its interactions with metal nanoparticles and electrolyte, which promoted the mass transfer, increased the performance of Pt/HCS-P and Pt/HCS-B. The high catalytic activity showed by Pt/HCS-B and Pt/HCS-P for the ORR, even with a low-Pt content, make them promising cathode nanocatalysts for Anion Exchange Membrane Fuel Cells (AEMFC).


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