Thermal modification of consolidated oriented strandboards: effects on dimensional stability, mechanical properties, chemical composition and surface color

2009 ◽  
Vol 67 (4) ◽  
Author(s):  
C.H.S. Del Menezzi ◽  
I. Tomaselli ◽  
E.Y.A. Okino ◽  
D.E. Teixeira ◽  
M.A.E. Santana
Keyword(s):  
Mechanical Properties ◽  
Chemical Composition ◽  
Dimensional Stability ◽  
Thermal Modification ◽  
Surface Color

scholarly journals New Perspective on Wood Thermal Modification: Relevance between the Evolution of Chemical Structure and Physical-Mechanical Properties, and Online Analysis of Release of VOCs

Polymers ◽  
2019 ◽  
Vol 11 (7) ◽  
pp. 1145 ◽  
Author(s):  
Jiajia Xu ◽  
Yu Zhang ◽  
Yunfang Shen ◽  
Cong Li ◽  
Yanwei Wang ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Dimensional Stability ◽  
Chemical Structure ◽  
Low Cost ◽  
Physical And Mechanical Properties ◽  
Decay Resistance ◽  
Thermal Modification ◽  
Infrared Spectrometry ◽  
Dominant Component ◽  
New Perspective

Thermal modification (TM) is an ecological and low-cost pretreated method to improve the dimensional stability and decay resistance of wood. This study systematically investigates the relevance between the evolution of chemical structure and the physical and mechanical properties during wood thermal modification processes. Moreover, the volatility of compounds (VOCs) was analyzed using a thermogravimetric analyzer coupled with Fourier transform infrared spectrometry (TGA-FTIR) and a pyrolizer coupled with gas chromatography/mass spectrometer (Py-GC/MS). With an increase of TM temperature, the anti-shrink efficiency and contact angle increased, while the equilibrium moisture content decreased. This result indicates that the dimensional stability improved markedly due to the reduction of hydrophilic hydroxyl (–OH). However, a slight decrease of the moduli of elasticity and of rupture was observed after TM due to the thermal degradation of hemicellulose and cellulose. Based on a TGA-FTIR analysis, the small molecular gaseous components were composed of H2O, CH4, CO2, and CO, where H2O was the dominant component with the highest absorbance intensity, i.e., 0.008 at 200 °C. Based on the Py-GC/MS analysis, the VOCs were shown to be mainly composed of acids, aldehydes, ketones, phenols, furans, alcohols, sugars, and esters, where acids were the dominant compounds, with a relative content of 37.05−42.77%.

scholarly journals THERMAL MODIFICATION OF SUGARCANE WASTE AND BAMBOO PARTICLES FOR THE MANUFACTURE OF PARTICLEBOARDS

2019 ◽  
Vol 43 (1) ◽  
Author(s):  
Flávia Maria Silva Brito ◽  
Geraldo Bortoletto Júnior
Keyword(s):  
Mechanical Properties ◽  
Thermal Treatment ◽  
Sugarcane Bagasse ◽  
Dimensional Stability ◽  
Industrial Waste ◽  
Urea Formaldehyde ◽  
Dry Mass ◽  
Thermal Modification ◽  
Thickness Variation ◽  
Dendrocalamus Asper

ABSTRACT The thermal modification of particles of the paticleboards constituted of agroforest and industrial waste can improves the dimensional stability (thickness variation) and reduces the use of chemicals that can raise the costs of the process or be hazardous to humans and the environment. This study evaluated the effect of the thermal modification on the physical-mechanical properties and density profile of particleboards manufactured from sugarcane bagasse and bamboo (Dendrocalamus asper) (Schult f.) Backer ex Heyne). A mixture of 75% bamboo particles and 25% sugarcane bagasse was subjected to 220 °C temperature for 201 min. Urea-formaldehyde (UF)-based adhesive with three solids contents (10, 12 and 14%) based on the dry mass of the particles was used for the aggregation of the materials. Both temperature and increases in the adhesive content improved their dimensional stability, however, the thermal treatment reduced the mechanical properties. The particleboards composed of treated particles did not meet the minimum specifications established by the Brazilian norm utilized. The densitometric profiles were negatively influenced by the thermal modification and improved by the increase in adhesive content.

scholarly journals Physical and Mechanical Properties of Heat Treated Daniella oliveri (Africa Balsam Tree) Wood

2019 ◽  
pp. 1-9 ◽  
Author(s):  
Ebenezer Adeyemi Iyiola ◽  
Babatola Olufemi ◽  
Victoria Olubukola Oyerinde ◽  
J. M. Owoyemi ◽  
Ayanleye Samuel
Keyword(s):  
Mechanical Properties ◽  
Heat Treatment ◽  
Compressive Strength ◽  
Study Design ◽  
Dimensional Stability ◽  
Treated Wood ◽  
Physical And Mechanical Properties ◽  
Thermal Modification ◽  
Average Weight ◽  
Direction Parallel

Aims: This work investigated the effect of thermal modification on some of the physical properties and mechanical properties of Daniella oliveri wood. Study Design: The study design used for this experiment was 3 x4 Factorial experiment in Completely Randomized Design. Place and Duration of Study: The study was conducted at the Federal University of Technology, Akure wood laboratory and the study lasted for 6 months. Methodology: Wood samples were thermally treated at the temperature of 120, 140, 160 and 180°C, for different durations of 1, 1.5 and 2 hours in a muffle furnace. The planks were air-dried to reduce the moisture content and then machined into the required dimensions in the direction parallel to grain with a circular saw. Thirty-nine defect-free samples of dimensions 20 mm × 20 mm × 60 mm were prepared for dimensional stability and compression test, static bending tests and the hardness tests to make a total of 117 samples. Results: The result showed that the average weight loss of the treated wood samples varied from 3.79% at 120°C for 1 hour to 7.51% at 180°C for 2 hours. The treatment led to reduction in density from 528 to 459 kg/m3 at 180°C for 2 hours. The heat treatment also led to reduction in water absorption and volumetric swelling of the treated samples. The mean value for Modulus of elasticity (MOE) ranges from 2.17x103 N/mm2 to 2.96 x 103 N/mm2 for the treated samples while the untreated was 2.22x103 N/mm2. Heat treatment brought about improvement in the maximum compressive strength and the Janka hardness parallel to the grain of wood samples. The value of compressive strength increased from 26.58 N/mm2 to 41.71 N/mm2 and hardness from 69.24 N to 75.5 N. It can therefore be concluded that thermal modification greatly enhanced the dimensional stability and mechanical properties of wood samples.

Study of the character and causes of destruction of the cardan shaft of the propeller engine

2019 ◽  
Vol 85 (12) ◽  
pp. 43-50
Author(s):  
D. A. Movenko ◽  
L. V. Morozova ◽  
S. V. Shurtakov
Keyword(s):  
Mechanical Properties ◽  
Chemical Composition ◽  
Yield Point ◽  
Protective Coating ◽  
Fracture Pattern ◽  
Corrosion Cracking ◽  
Tempered Martensite ◽  
Neck Formation ◽  
Static Mechanism ◽  
Shaft Surface

The results of studying operational destruction of a high-loaded cardan shaft of the propeller engine made of steel 38KhN3MFA are presented to elucidate the cause of damage and develop a set of recommendations and measures aimed at elimination of adverse factors. Methods of scanning electron and optical microscopy, as well as X-ray spectral microanalysis are used to determine the mechanical properties, chemical composition, microstructure, and fracture pattern of cardan shaft fragments. It is shown that the mechanical properties and chemical composition of the material correspond to the requirements of the regulatory documentation, defects of metallurgical origin both in the shaft metal and in the fractures are absent. The microstructure of the studied shaft fragments is tempered martensite. Fractographic analysis revealed that the destruction of cardan shaft occurred by a static mechanism. The fracture surface is coated with corrosion products. The revealed cracks developed by the mechanism of corrosion cracking due to violation of the protective coating on the shaft. The results of the study showed that the destruction of the cardan shaft of a propeller engine made of steel 38Kh3MFA occurred due to formation and development of spiral cracks by the mechanism of stress corrosion cracking under loads below the yield point of steel. The reason for «neck» formation upon destruction of the shaft fragment is attributed to the yield point of steel attained during operation. Regular preventive inspections are recommended to assess the safety of the protective coating on the shaft surface to exclude formation and development of corrosion cracks.

Structural features and strength behavior of TRIP/TWIP steels

2020 ◽  
pp. 5-18
Author(s):  
D. V. Prosvirnin ◽  
◽  
M. S. Larionov ◽  
S. V. Pivovarchik ◽  
A. G. Kolmakov ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Chemical Composition ◽  
Thermomechanical Processing ◽  
Maximum Load ◽  
Structural Features ◽  
Stacking Fault ◽  
Stacking Fault Energy ◽  
Structural And Functional Properties ◽  
Twip Steels ◽  
The Creation

A review of the literature data on the structural features of TRIP / TWIP steels, their relationship with mechanical properties and the relationship of strength parameters under static and cyclic loading was carried out. It is shown that the level of mechanical properties of such steels is determined by the chemical composition and processing technology (thermal and thermomechanical processing, hot and cold pressure treatment), aimed at achieving a favorable phase composition. At the atomic level, the most important factor is stacking fault energy, the level of which will be decisive in the formation of austenite twins and / or the formation of strain martensite. By selecting the chemical composition, it is possible to set the stacking fault energy corresponding to the necessary mechanical characteristics. In the case of cyclic loads, an important role is played by the strain rate and the maximum load during testing. So at high loading rates and a load approaching the yield strength under tension, the intensity of the twinning processes and the formation of martensite increases. It is shown that one of the relevant ways to further increase of the structural and functional properties of TRIP and TWIP steels is the creation of composite materials on their basis. At present, surface modification and coating, especially by ion-vacuum methods, can be considered the most promising direction for the creation of such composites.

Weldability - Behavior of Welded Reinforcement

2019 ◽  
Vol 70 (10) ◽  
pp. 3469-3472
Keyword(s):  
Mechanical Properties ◽  
Chemical Composition ◽  
Mechanical Characteristics ◽  
Mechanical Performance ◽  
Current Work ◽  
Carbon Equivalent ◽  
Work Process ◽  
Ultimate Limit

Weldability involves two aspects: welding behavior of components and safety in operation. The two aspects will be reduced to the mechanical characteristics of the elements and to the chemical composition. In the case of steel reinforcing rebar’s, it is reduces to the percentage of Cech(carbon equivalent) and to the mechanical characteristics: the yielding limit, the ultimate limit, and the elongations which after that represent the ductility class in which the re-bars is framed. The paper will present some types of steel reinforcing rebar’s with its mechanical characteristics and the welding behavior of those elements. In the current work, process-related behavior of welded reinforcement, joint local and global mechanical properties, and their correlation with behavior of normal reinforcement and also the mechanical performance resulted in this type of joints. Keywords: welding behavior, ultimate limit, reinforcing rebar’s

scholarly journals Cellular Orientation on Repeatedly Stretching Gelatin Hydrogels with Supramolecular Cross-Linkers

Polymers ◽  
2019 ◽  
Vol 11 (12) ◽  
pp. 2095
Author(s):  
Dae Hoon Lee ◽  
Yoshinori Arisaka ◽  
Asato Tonegawa ◽  
Tae Woong Kang ◽  
Atsushi Tamura ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Chemical Composition ◽  
Cellular Response ◽  
Linear Polymer ◽  
Cross Linking ◽  
Adherent Cells ◽  
Cell Cultivation ◽  
Supramolecular Compound ◽  
Synthetic Materials ◽  
Cyclic Molecules

The cytocompatibility of biological and synthetic materials is an important issue for biomaterials. Gelatin hydrogels are used as biomaterials because of their biodegradability. We have previously reported that the mechanical properties of gelatin hydrogels are improved by cross-linking with polyrotaxanes, a supramolecular compound composed of many cyclic molecules threaded with a linear polymer. In this study, the ability of gelatin hydrogels cross-linked by polyrotaxanes (polyrotaxane–gelatin hydrogels) for cell cultivation was investigated. Because the amount of polyrotaxanes used for gelatin fabrication is very small, the chemical composition was barely altered. The structure and wettability of these hydrogels are also the same as those of conventional hydrogels. Fibroblasts adhered on polyrotaxane–gelatin hydrogels and conventional hydrogels without any reduction or apoptosis of adherent cells. From these results, the polyrotaxane–gelatin hydrogels have the potential to improve the mechanical properties of gelatin without affecting cytocompatibility. Interestingly, when cells were cultured on polyrotaxane–gelatin hydrogels after repeated stress deformation, the cells were spontaneously oriented to the stretching direction. This cellular response was not observed on conventional hydrogels. These results suggest that the use of a polyrotaxane cross-linking agent can not only improve the strength of hydrogels but can also contribute to controlling reorientation of the gelatin.

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