HPLC–MS/MS Analysis and Study on the Adsorption/Desorption Characteristics of Ginsenosides on Anion-Exchange Macroporous Resins

AbstractThe adsorption/desorption characteristics, modeling and properties of anthocyanins from extruded red cabbage juice by macroporous resins were investigated. The static adsorption and desorption capacities of red cabbage anthocyanins on five macroporous resins were measured and compared. The X-5 resin showed the best capacities and was selected for the adsorption kinetics, isotherms and elution studies. The pseudo-second-order kinetic model and Langmuir isotherm model were used to describe the adsorption process and mechanism. Dynamic adsorption and desorption tests were performed on a fixed-bed column, and the loading and eluent conditions were optimized. The purity of anthocyanins in freeze-dried purified powder by the resin adsorption process is 21.3 ± 0.9 wt % and shows better stability in the air than the unpurified one. Finally, the antioxidant activity and color properties including color density, color intensity, color tonality and degradation index of the purified powders were measured.

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Insight into mass transfer during ultrasound-enhanced adsorption/desorption of blueberry anthocyanins on macroporous resins by numerical simulation considering ultrasonic influence on resin properties

Chemical Engineering Journal ◽

10.1016/j.cej.2019.122530 ◽

2020 ◽

Vol 380 ◽

pp. 122530 ◽

Cited By ~ 7

Author(s):

Yang Tao ◽

Yue Wu ◽

Yongbin Han ◽

Farid Chemat ◽

Dandan Li ◽

...

Keyword(s):

Numerical Simulation ◽

Mass Transfer ◽

Macroporous Resins ◽

Enhanced Adsorption ◽

Ultrasonic Influence ◽

Adsorption Desorption ◽

Insight Into

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An efficient method for decoloration of polysaccharides from the sprouts of Toona sinensis (A. Juss.) Roem by anion exchange macroporous resins

Food Chemistry ◽

10.1016/j.foodchem.2016.08.079 ◽

2017 ◽

Vol 217 ◽

pp. 461-468 ◽

Cited By ~ 21

Author(s):

Yingying Shi ◽

Tingting Liu ◽

Yun Han ◽

Xiufang Zhu ◽

Xiaojuan Zhao ◽

...

Keyword(s):

Anion Exchange ◽

Efficient Method ◽

Toona Sinensis ◽

Macroporous Resins

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Physicochemical Study of 3,4-Dichlorophenoxyacetic Acid Intercalated into Hydrotalcite-Like Compound by Ion Exchanged Method

Materials Science Forum ◽

10.4028/www.scientific.net/msf.846.440 ◽

2016 ◽

Vol 846 ◽

pp. 440-447

Author(s):

Sheikh Ahmad Izaddin Sheikh Mohd Ghazali ◽

Siti Halimah Sarijo ◽

Mohd Zobir Hussein

Keyword(s):

Surface Area ◽

Anion Exchange ◽

Layered Double Hydroxide ◽

Nitrogen Adsorption ◽

Basal Spacing ◽

Dichlorophenoxyacetic Acid ◽

Exchange Method ◽

Type Iv ◽

Double Hydroxide ◽

Adsorption Desorption

The intercalation of herbicide, 3,4-dicholorophenoxyacetic acid (3,4D), into zinc-aluminium-layered double hydroxide (LDH) for the formation of a new nanocomposite ZADX, was accomplished via anion exchange method. Due to the intercalation of 3,4D with LDH interlayer domain, basal spacing expanded from 8.9Å in the ZAL to 17.7-19.0 Å in the ZADX. The percentage loading of 3,4D in the ZADX is 51.4 % (w/w). The FTIR spectra of the nanocomposite shows resemblance peaks of the 3,4D and Zn-Al-layered double hydroxide indicating the inclusion of 3,4D into the layered double hydroxide. Surface area of the resulting nanocomposite increased from 1.3 to 7.14 m2g-1 with the nitrogen adsorption-desorption of type IV.

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Simultaneous Purification and Separation of Syringoside and Oleuropein from Syringa oblata Lindl. Extract Using Macroporous Resin

Journal of Chemistry ◽

10.1155/2019/2924548 ◽

2019 ◽

Vol 2019 ◽

pp. 1-10

Author(s):

Guoliang Li ◽

Hongxiu Yan ◽

Xiangping Liu

Keyword(s):

Optimal Parameters ◽

Macroporous Resin ◽

Adsorption Experiment ◽

Adsorption Performance ◽

Macroporous Resins ◽

Initial Extract ◽

Langmuir Isotherm Model ◽

Potential Basis ◽

Adsorption Desorption ◽

Separation Parameters

This study developed an efficient method to simultaneously separate and purify syringoside and oleuropein from Syringa oblata Lindl. extract using macroporous resins. The adsorption and desorption property of 11 resins were systematically evaluated. Based on the adsorption performance, HPD-100B resin was selected for the separation of syringoside and oleuropein. The HPD-100B resin fitted well to the Langmuir isotherm model (R2 > 0.97), as ascertained by the results of the static adsorption experiment. Kinetic and dynamic adsorption/desorption experiments were conducted using the HPD-100B resin to optimize the separation parameters of syringoside and oleuropein. On the optimal parameters, syringoside and oleuropein were obtained from the 20% and 40% ethanol eluates, respectively. In addition, the adsorption effluent (15–60 BV) contained a large amount of syringoside with less impurities; therefore, this part was also collected for further syringoside separation and enrichment of syringoside. By only one cycle treatment, the syringoside and oleuropein contents in the final products increased by 7.1-fold and 8.2-fold, respectively, compared to the initial extract. The method developed in this study provides a potential basis for the industrial-scale enrichment and separation of syringoside and oleuropein from S. oblata extract.

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Adsorption/Desorption of Tungsten from Ammonium Tungstate Pentahydrate using Anion Exchange Resins

Journal of the Korean Society of Mineral and Energy Resources Engineers ◽

10.12972/ksmer.2014.51.3.448 ◽

2014 ◽

Vol 51 (3) ◽

pp. 448-467 ◽

Cited By ~ 3

Author(s):

Jonghyuk Jeon ◽

Younghun Kim ◽

Jinyoung Lee ◽

Choon Han

Keyword(s):

Anion Exchange ◽

Anion Exchange Resins ◽

Ammonium Tungstate ◽

Exchange Resins ◽

Adsorption Desorption

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Determination of Suitable Macroporous Resins and Desorbents for Carnosol and Carnosic Acid from Deep Eutectic Solvent Sage (Salvia officinalis) Extract with Assessment of Antiradical and Antibacterial Activity

Antioxidants ◽

10.3390/antiox10040556 ◽

2021 ◽

Vol 10 (4) ◽

pp. 556

Author(s):

Martina Jakovljević Kovač ◽

Valentina Pavić ◽

Anastazija Huđ ◽

Ines Cindrić ◽

Maja Molnar

Keyword(s):

Antibacterial Activity ◽

Large Scale ◽

Deep Eutectic Solvent ◽

Deep Eutectic Solvents ◽

Salvia Officinalis ◽

Carnosic Acid ◽

Whole Process ◽

Optimal Separation ◽

Macroporous Resins ◽

Adsorption Desorption

In this study, for the first time, the adsorption/desorption characteristics of carnosic acid and carnosol from deep eutectic solvent extract of Salvia officinalis on five macroporous resins (HP20, XAD7HP, XAD16N, HP21, HP2MG) were evaluated. The high adsorption and medium desorption capacities of carnosic acid and carnosol as well as antibacterial and antiradical activity from the extract obtained with choline chloride:lactic acid (1:2) on XAD7HP resin indicated that resin was appropriate. To get the optimal separation process, the influence of factors such as adsorption/desorption time and volume of desorbent was further investigated. The results showed that the extract with high antiradical and antibacterial activity was obtained via adsorption and desorption on XAD7HP resin. The extraction efficiencies of the deep eutectic solvents (DESs) recycled once, twice, and thrice were 97.64% (±0.03%), 93.10% (±0.66%), and 88.94% (±1.15%), respectively, for carnosic acid, and 96.63% (±0.04%), 94.38% (±0.27%), and 91.19% (±0.36%), respectively, for carnosol, relative to the initial solvent efficiency. Based on that, this method is a promising basis for the large-scale preparation of extracts from Salvia officinalis with further application in the pharmaceutical or food industry, especially for maintaining the “green” character of the whole process to obtain the appropriate extract.

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