Treatment of Gas Emissions of Sodium Bisulfite Production to Remove Sulfur Dioxide by Pelletized Sorption Material

2021 ◽  
Vol 56 (11-12) ◽  
pp. 935-942
Author(s):  
L. A. Nikolaeva ◽  
E. M. Khusnutdinova
Author(s):  
L. A. Nikolaeva ◽  
◽  
E. M. Khusnutdinova ◽  

It is proposed to purify industrial gas emissions from sulfur dioxide by the adsorption method. Waste from the power industry - sludge from the chemical water treatment of Kazan CHPP-1 - was used as an adsorption material. Its chemical composition is presented. Experimental studies of a new sorption material based on energy waste for gas purification from sulfur dioxide have been carried out. The kinetic dependence and isotherm of the adsorption process are obtained. The mechanism of the process of adsorption of sulfur dioxide by sorption material at different temperatures has been studied. The Gibbs free energy, differential heat, and activation energy of adsorption are determined. The economic and environmental impact of modernization of procedure for cleaning gas emissions from sulfur dioxide in sodium bisulfite production at JSC “Chemical factory named after L.Ya. Karpov” was measured.


2020 ◽  
Vol 28 (4) ◽  
pp. 397-407
Author(s):  
Larisa A. Nikolaeva ◽  
Elvira M. Khusnutdinova

Chemical industry enterprises are the main environmental pollutants that cause environmental problems. This is due to the production technology and the toxicity of some substances. In this paper, it is proposed to purify the gas emissions at the JSC Karpov Chemical Plant formed during the production of sodium bisulfite from sulfur dioxide by the adsorption method. As a sorption material, a modified energy waste - carbonate sludge from the chemical water treatment plant of the Naberezhnye Chelny CHPP - was used. The technological characteristics of the granular sorption material are presented. A batch adsorber with a fixed layer of granular sorption material is calculated. The modernization of the technological scheme for cleaning gas emissions from sulfur dioxide of the production line of sodium bisulfite at JSC Chemical Plant named after L.Ya. Karpov is proposed. The calculation of the prevented environmental damage and the economic effect of the modernization of the technological scheme is made.


2019 ◽  
Vol 7 ◽  
Author(s):  
Brendan T. McCormick Kilbride ◽  
Kila Mulina ◽  
Geoffrey Wadge ◽  
R. Wally Johnson ◽  
Ima Itikarai ◽  
...  

Author(s):  
Junyou Zhao ◽  
Chongning Liu ◽  
Yafei Dong ◽  
Qingqiang He ◽  
Fawei Wan ◽  
...  

PM2.5 refers to fine particles with a diameter of 2.5 µm or less in the air. With PM2.5 continuously impacting people's lives, researchers are starting to pay more attention on the treatment of flue gas emitted from coal-fired boilers. This paper introduces a treatment device for ejected fine flue gas. The device uses ejectors to effectively remove acid substances and large dust particles contained in flue gas, and uses air dynamic ultrasonic atomizer to eliminate micro dust particles effectively. The overall scheme of the flue gas processing device is designed, the principle and simulation results of the main components of the ejector are studied, and the optimal value of the ejector ratio is determined by experiments. Finally, the efficiency of processing dust and sulfur dioxide in the flue gas is tested during experiments on the industrial worksite. For the gas emissions from domestic small- and medium-sized coal-fired boilers, this device is more efficient and costs less energy.


2021 ◽  
Author(s):  
Christoph Kern ◽  
Patricia Nadeau ◽  
Tamar Elias ◽  
Peter Kelly ◽  
Allan Lerner ◽  
...  

<p>Kīlauea Volcano (Hawaii, USA) had been in a state of quiescence since the end of the historic 2018 eruption on its lower East Rift Zone. Tapping the volcanic plumbing system at elevations around 300 m well below the volcano’s 1200 m summit, the 2018 eruption drained magma from the volcano’s summit reservoir and East Rift Zone, causing the drainage of a decade-old subaerial lava lake followed by widespread caldera collapse. Two years later, on the evening of 20 December 2020, the Hawaiian Volcano Observatory (HVO) once again detected a glow within the now vastly deepened Halemaʻumaʻu Crater at Kīlauea’s summit. A new eruption had begun. Observations over the next few days revealed lava flowing from three vents in the wall of the crater and into its base. A water lake, which had formed in 2019 – 2020 from groundwater infiltration, boiled off within hours and the crater began rapidly filling with lava. Over the first 3 days of the eruption, the new lava lake filled the lowermost ~150 m of the summit crater, and sulfur dioxide (SO<sub>2</sub>) emission rates sometimes exceeded 30,000 metric tons per day (t/d) as measured by Differential Optical Absorption Spectroscopy (DOAS) traverses recorded both from the ground and by helicopter. These vigorous SO<sub>2</sub> emissions were also clearly detected by the Tropospheric Monitoring Instrument (TROPOMI) aboard the Sentinal-5 Precursor satellite, and comparisons of the ground-based data with those collected by TROPOMI are the topic of ongoing research. Lava effusion and gas emission rates then tailed off and, from 26 December to 2 January, DOAS measurements indicated SO<sub>2</sub> emissions of ~5,000 t/d, similar to the average emission rate from Kīlauea’s summit lava lake throughout most of the volcano’s 2008-2018 eruption. Data from a continuous Multiple Gas Analyzer System (MultiGAS) installed approximately 1.3 km downwind of the active vents indicate that the carbon dioxide (CO<sub>2</sub>) to SO<sub>2</sub> molar ratio of the emitted gas is low (0.3 ± 0.1), consistent with a model in which the erupted lava has been previously degassed in carbon dioxide but is only now degassing the more soluble sulfur as it reaches the surface. Further MultiGAS measurements performed with an unoccupied aircraft system (UAS) show that the gas composition varies throughout the emitted plume, but that the primary constituents are water vapor (~80-90% molar), carbon dioxide (~3%), and sulfur dioxide (~7-16%), while hydrogen sulfide is below the detection limit of the instrumentation. As of 11 January 2021, lava effusion and gas emissions appear to be slowly decreasing in vigor, but it is as yet unclear whether the eruption will continue to weaken and end within the coming weeks, or whether Kīlauea Volcano will once again harbor a sustained subaerial lava lake for months or years to come.</p>


Author(s):  
В.О. ГОРОДЕЦКИЙ ◽  
С.О. СЕМЕНИХИН ◽  
Н.М. ДАИШЕВА ◽  
Н.И. КОТЛЯРЕВСКАЯ

Для увеличения производительности сахарного завода без существенных финансовых затрат можно использовать технологическую схему вывода сиропа на длительное хранение с последующей его переработкой в межсезонье. Одним из недостатков такой технологической схемы является риск микробиологической обсемененности сиропа, для снижения которой отечественные исследователи предлагают обработку электромагнитными полями. Однако, на наш взгляд, обработка сиропа сульфитсодержащими реагентами более безопасна и менее энергоемка. Проведены лабораторные исследования, направленные на снижение микробиологической обсемененности сиропа при выводе его на хранение. Объектом исследований был полученный в лабораторных условиях концентрированный сироп с содержанием сухих веществ 67%, который делили на три образца по 300 мл каждый. Контрольный образец сиропа оставляли без обработки, образец 1 обрабатывали сернистым ангидридом до рН 7,3–7,5, образец 2 – раствором бисульфита натрия в количестве 0,01% к массе образца. После этого все три образца подвергали подщелачиванию 1 н раствором NaOH до pH 9,15 и хранили в течение 100 сут при комнатной температуре. По окончанию срока хранения в образцах сиропа определяли микробиологические показатели и содержание редуцирующих веществ. Установлено, что предварительная обработка сиропа, направляемого на длительное хранение, сульфитсодержащими реагентами способствует достаточно эффективному снижению количества мезофильных аэробных и факультативно-анаэробных микроорганизмов и плесеней. Наибольший эффект снижения наблюдается при обработке сиропа сернистым ангидридом: на 69% снижается показатель микробиальной обсемененности и на 58% количество плесеней по сравнению с необработанным сиропом. При обработке сиропа бисульфитом натрия снижение составило 31 и 33% соответственно. Степень предотвращения накопления редуцирующих веществ при обработке сиропа сернистым ангидридом составила 18,8%, а при обработке бисульфитом натрия – 11,5%. Снижение микробиальной обсемененности сиропа при выводе его на длительное хранение будет способствовать снижению потерь сахарозы. To increase the productivity of the sugar factory without significant financial costs, you can use a technological scheme for the withdrawal of thick juice for long-term storage with its subsequent processing in the off-season. One of the disadvantages of such a technological scheme is the risk of microbiological contamination of the thick juice, to reduce which domestic researchers offer treatment with electromagnetic fields. However, in our opinion, the treatment of thick juice with sulfite-containing reagents is safer and less energy intensive. Laboratory studies aimed at reducing the microbiological contamination of the thick juiceduring its storage were carried out. The object of research was a concentrated thick juice obtained under laboratory conditions with a dry matter content of 67%, which was divided into three samples of 300 ml each. The control sample of the thick juice was left untreated, sample 1 was treated with sulfur dioxide to a pH of 7,3–7,5, sample 2 – with a solution of sodium bisulfite in an amount of 0.01% by weight of the sample. After that, all three samples were alkalized with 1 n NaOH solution to pH 9,15 and stored for 100 days at room temperature. At the end of the shelf life, microbiological parameters and the content of reducing substances were determined in the thick juice samples. It was found that the pretreatment of thick juice sent for long-term storage with sulfite-containing reagents contributes to a sufficiently effective reduction in the number of mesophilic aerobic and facultative anaerobic microorganisms and molds. The greatest reduction effect is observed when the thick juice is treated with sulfurous anhydride: the indicator of microbial contamination is reduced by 69% and the number of molds is reduced by 58% compared to untreated thick juice. When treating the syrup with sodium bisulfite, the reduction was 31 and 33% respectively. The degree of prevention of the accumulation of reducing substances when treating the thick juice with sulfur dioxide was 18,8%, and when treating with sodium bisulfite – 11,5%. Reducing the microbial contamination of the thick juicewhen it is taken out for long-term storage will help to reduce the loss of sucrose.


Chemosphere ◽  
2012 ◽  
Vol 89 (5) ◽  
pp. 579-584 ◽  
Author(s):  
Ziqiang Meng ◽  
Zhenhua Yang ◽  
Junling Li ◽  
Quanxi Zhang

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