scholarly journals New liquid-free proton conductive nanocomposite based on imidazole-functionalized cellulose nanofibers

Cellulose ◽  
2020 ◽  
Author(s):  
Iga Aleksandra Jankowska ◽  
Katarzyna Pogorzelec-Glaser ◽  
Paweł Ławniczak ◽  
Michał Matczak ◽  
Radosław Pankiewicz
Keyword(s):  
Thermal Stability ◽  
Proton Transport ◽  
Cellulose Nanofibers ◽  
Solid Polymer ◽  
Water Evaporation ◽  
Scanning Calorimetry ◽  
Pure Cellulose ◽  
Maximum Conductivity ◽  
Cellulose Materials ◽  
Thermal Stability Of

AbstractThe first successful attempt to synthesize a new proton conducting polymeric nanocomposite film based on pure cellulose nanofibers (CNF) as a polymer matrix functionalized on their surface with imidazole molecules (Im) as a dopant, was made. The 2CNF-Im nanomaterial contains on average one molecule of imidazole per 2 glucose units from cellulose chains. Water evaporation and thermal stability of 2CNF-Im were studied by thermogravimetric analysis (TGA and DTG) and differential scanning calorimetry (DSC). The temperature dependence of electrical conductivity was studied by the impedance spectroscopy. At 140 °C, the 2CNF-Im nanocomposite has a maximum conductivity of 7.0 × 10−3 S/m, i.e. four orders of magnitude higher than that of non-functionalized CNF matrix. The newly synthesized cellulose nanocomposite exhibits high electrical and thermal stability. In 2CNF-Im, the activation energy of the proton transport process is the lowest compared to the previously synthesized imidazole-functionalized composites based on other pure cellulose materials and equals 0.62 eV. The synthesized nanomaterial is liquid-free solid polymer electrolyte showing proton conductivity above the boiling point of water.

Thermal Stability of N-Heterocycle-Stabilized Iodanes – A Systematic Investigation

2019 ◽  
Author(s):  
Andreas Boelke ◽  
Yulia A. Vlasenko ◽  
Mekhman S. Yusubov ◽  
Boris Nachtsheim ◽  
Pavel Postnikov
Keyword(s):  
Thermal Stability ◽  
Differential Scanning Calorimetry ◽  
Thermogravimetric Analysis ◽  
Systematic Investigation ◽  
Scanning Calorimetry ◽  
Thermal Stability Of

<p>The thermal stability of pseudocyclic and cyclic <i>N</i>-heterocycle-stabilized (hydroxy)aryl- and mesityl(aryl)-l<sup>3</sup>-iodanes (NHIs) through thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) is investigated. NHIs bearing <i>N</i>-heterocycles with a high N/C-ratio such as triazoles show among the lowest descomposition temperatures and the highest decomposition energies. A comparison of NHIs with known (pseudo)cyclic benziodoxolones is made and we further correlated their thermal stability with reactivity in a model oxygenation. </p>

scholarly journals Isothermal Vulcanization and Non-Isothermal Degradation Kinetics of XNBR/Epoxy/XNBR-g-Halloysite Nanotubes (HNT) Nanocomposites

Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 2872
Author(s):  
Seyed Mohamad Reza Paran ◽  
Ghasem Naderi ◽  
Elnaz Movahedifar ◽  
Maryam Jouyandeh ◽  
Krzysztof Formela ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Degradation Kinetics ◽  
Halloysite Nanotubes ◽  
Butadiene Rubber ◽  
Order Model ◽  
Scanning Calorimetry ◽  
Theoretical Methods ◽  
Vulcanization Kinetics ◽  
Kinetics Of ◽  
Thermal Stability Of

The effect of several concentrations of carboxylated nitrile butadiene rubber (XNBR) functionalized halloysite nanotubes (XHNTs) on the vulcanization and degradation kinetics of XNBR/epoxy compounds were evaluated using experimental and theoretical methods. The isothermal vulcanization kinetics were studied at various temperatures by rheometry and differential scanning calorimetry (DSC). The results obtained indicated that the nth order model could not accurately predict the curing performance. However, the autocatalytic approach can be used to estimate the vulcanization reaction mechanism of XNBR/epoxy/XHNTs nanocomposites. The kinetic parameters related to the degradation of XNBR/epoxy/XHNTs nanocomposites were also assessed using thermogravimetric analysis (TGA). TGA measurements suggested that the grafted nanotubes strongly enhanced the thermal stability of the nanocomposite.

Grain Growth in Nanocrystalline Nickel

1999 ◽  
Vol 580 ◽  
Author(s):  
G.D. Hibbard ◽  
U. Erb ◽  
K.T. Aust ◽  
G. Palumbo
Keyword(s):  
Thermal Stability ◽  
Grain Size ◽  
Grain Growth ◽  
Size Distributions ◽  
Nanocrystalline Nickel ◽  
Scanning Calorimetry ◽  
Solute Content ◽  
Grain Size Distributions ◽  
Thermal Stability Of ◽  
Total Solute Content

AbstractIn this study, the effect of grain size distribution on the thermal stability of electrodeposited nanocrystalline nickel was investigated by pre-annealing material such that a limited amount of abnormal grain growth was introduced. This work was done in an effort to understand the previously reported, unexpected effect, of increasing thermal stability with decreasing grain size seen in some nanocrystalline systems. Pre-annealing produced a range of grain size distributions in materials with relatively unchanged crystallographic texture and total solute content. Subsequent thermal analysis of the pre-annealed samples by differential scanning calorimetry showed that the activation energy of further grain growth was unchanged from the as-deposited nanocrystalline nickel.

scholarly journals Changes in thermal stability of lignocelluloses waste aggregates long-term incorporated in composite

2021 ◽  
Vol 900 (1) ◽  
pp. 012042
Author(s):  
N Stevulova ◽  
A Estokova
Keyword(s):  
Thermal Stability ◽  
Alkaline Treatment ◽  
Cement Matrix ◽  
Scanning Calorimetry ◽  
Alkali Ions ◽  
Thermal Gravimetry ◽  
Pre Treatment ◽  
Surface Modified ◽  
Thermal Stability Of

Abstract This paper is addressed to comparative study of changes in thermal stability of surface-modified hemp-hurds aggregates long-term incorporated in bio-aggregate-based composites with the original ones before their integration into alternative binder matrix. In this study, the effectiveness of alkaline treatment of hemp hurds compared to the raw bio-aggregates as well as in relation to their behaviour when they are long-term incorporated in the MgO-cement environment is investigated. The differences in the thermal behaviour of the samples are explained by the changed structure of hemp hurds constituents due to the pre-treatment and long-term action of the alternative binder components on the bio-aggregates. Alkaline treatment increases thermal stability of hemp hurds compared to raw sample. Also long-term incorporation of hemp hurds in MgO-cement matrix had a similar effect in case of alkaline modified bio-aggregates. The more alkali ions present in the structure of hemp hurdssamples, the more ash is formed during their thermal decomposition studied by thermal gravimetry (TG) and differential scanning calorimetry (DSC).

scholarly journals Thermal stability and thermal decomposition of sucralose

2018 ◽  
Vol 39 (4) ◽  
pp. 21
Author(s):  
Gilbert Bannach ◽  
Rafael R. Almeida ◽  
Luis G. Lacerda ◽  
Egon Schnitzler ◽  
Massao Ionashiro
Keyword(s):  
Thermal Stability ◽  
Thermal Analysis ◽  
Differential Scanning Calorimetry ◽  
Thermal Decomposition ◽  
Differential Thermal Analysis ◽  
Infrared Spectroscopy ◽  
Scanning Calorimetry ◽  
Thermoanalytical Techniques ◽  
Thermal Stability Of

Several papers have been described on the thermal stability of the sweetener, C12H19Cl3O8 (Sucralose). Nevertheless no study using thermoanalytical techniques was found in the literature. Simultaneous thermogravimetry and differential thermal analysis (TG-DTA), differential scanning calorimetry (DSC) and infrared spectroscopy, have been used to study the thermal stability and thermal decomposition of sweetener.

Systematic Characterization of Different Quaternary Ammonium Salts to be Used in Organoclays

2012 ◽  
Vol 727-728 ◽  
pp. 1552-1556
Author(s):  
Renata Barbosa ◽  
Dayanne Diniz Souza ◽  
Edcleide Maria Araújo ◽  
Tomás Jefférson Alves de Mélo
Keyword(s):  
Thermal Stability ◽  
Quaternary Ammonium ◽  
Chemical Structure ◽  
Quaternary Ammonium Salts ◽  
Ammonium Salts ◽  
Degradation Mechanisms ◽  
Scanning Calorimetry ◽  
Higher Temperature ◽  
Thermal Stability Of

Studies of degradation have verified that the decomposition of some quaternary ammonium salts can begin to be significant at the temperature of about 180 ° C and like most thermoplastics are processed at least around this temperature, the thermal stability of the salt in clay should always be considered. Some salts are more stable than others, being necessary to study the degradation mechanisms of each case. In this work, four quaternary ammonium salts were characterized by differential scanning calorimetry (DSC) and thermogravimetry (TG). The results of DSC and TG showed that the salts based chloride (Cl-) anion begin to degrade at similar temperatures, while the salt based bromide (Br-) anion degrades at higher temperature. Subsequently, a quaternary ammonium salt was chosen to be used in organoclays, depending on its chemical structure and its thermal behavior.

Solid state amorphization reactions in deformed Ni-Zr multilayered composites

1990 ◽  
Vol 5 (3) ◽  
pp. 488-497 ◽  
Author(s):  
G. C. Wong ◽  
W. L. Johnson ◽  
E. J. Cotts
Keyword(s):  
Thermal Stability ◽  
Solid State ◽  
Amorphous Phase ◽  
Equilibrium Phase ◽  
Solid State Reactions ◽  
Heat Of Mixing ◽  
Scanning Calorimetry ◽  
Multilayered Composites ◽  
State Amorphization ◽  
Thermal Stability Of

The mechanisms of metallic glass formation and competing crystallization processes in mechanically-deformed Ni-Zr multilayered composites have been investigated by means of differential scanning calorimetry and x-ray diffraction. Our investigation of the heat of formation of amorphous NixZr1−x alloys shows a large negative heat of mixing (on the order of 30 kJ/mole) for compositions near Zr55Ni45 with a compositional dependence qualitatively similar to that predicted by mean field theory. We find that the products of solid state reactions in composites of Ni and Zr can be better understood in terms of the equilibrium phase diagram and the thermal stability of liquid quenched metallic glasses. We have determined the composition of the growing amorphous phase at the Zr interface in these Ni-Zr diffusion couples to be 55 ± 4% Zr. We investigated the kinetics of solid state reactions competing with the solid state amorphization reaction and found the value of the activation energy of the initial crystallization and growth of the growing amorphous phase to be 2.0 ± 0.1 eV, establishing an upper limit on the thermal stability of the growing amorphous phase.

scholarly journals Thermal stability of Sn anode material with non-aqueous electrolytes in sodium-ion batteries

2018 ◽  
Vol 6 (41) ◽  
pp. 20383-20392 ◽  
Author(s):  
Yongho Lee ◽  
Hyojun Lim ◽  
Sang-Ok Kim ◽  
Hyung-Seok Kim ◽  
Ki Jae Kim ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Differential Scanning Calorimetry ◽  
Thermal Behavior ◽  
Anode Material ◽  
Sodium Ion ◽  
Aqueous Electrolytes ◽  
Sodium Ion Batteries ◽  
Scanning Calorimetry ◽  
Sn Anode ◽  
Thermal Stability Of

The thermal behavior of fully lithiated and sodiated Sn electrodes cycled in a MePF6 (Me = Li or Na)-based electrolyte was studied using differential scanning calorimetry (DSC).

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