Carbon isotopic signatures of carbonyls from roadside air observation

Author(s):  
S.J. Guo
2021 ◽  
Vol 2 (1) ◽  
Author(s):  
Henrik Drake ◽  
Nick M. W. Roberts ◽  
Manuel Reinhardt ◽  
Martin Whitehouse ◽  
Magnus Ivarsson ◽  
...  

AbstractEarth’s crust contains a substantial proportion of global biomass, hosting microbial life up to several kilometers depth. Yet, knowledge of the evolution and extent of life in this environment remains elusive and patchy. Here we present isotopic, molecular and morphological signatures for deep ancient life in vein mineral specimens from mines distributed across the Precambrian Fennoscandian shield. Stable carbon isotopic signatures of calcite indicate microbial methanogenesis. In addition, sulfur isotope variability in pyrite, supported by stable carbon isotopic signatures of methyl-branched fatty acids, suggest subsequent bacterial sulfate reduction. Carbonate geochronology constrains the timing of these processes to the Cenozoic. We suggest that signatures of an ancient deep biosphere and long-term microbial activity are present throughout this shield. We suggest that microbes may have been active in the continental igneous crust over geological timescales, and that subsurface investigations may be valuable in the search for extra-terrestrial life.


Molecules ◽  
2021 ◽  
Vol 26 (13) ◽  
pp. 3895
Author(s):  
Marica Baldoni ◽  
Alessandra Nardi ◽  
Flavio De Angelis ◽  
Olga Rickards ◽  
Cristina Martínez-Labarga

The present research investigates the relationship between dietary habits and mortality patterns in the Roman Imperial and Medieval periods. The reconstructions of population dynamics and subsistence strategies provide a fascinating source of information for understanding our history. This is particularly true given that the changes in social, economic, political, and religious aspects related to the transition from the Roman period to the Middle Ages have been widely discussed. We analyzed the isotopic and mortality patterns of 616 individuals from 18 archeological sites (the Medieval Latium sites of Colonna, Santa Severa, Allumiere, Cencelle, and 14 Medieval and Imperial funerary contexts from Rome) to compile a survivorship analysis. A semi-parametric approach was applied, suggesting variations in mortality patterns between sexes in the Roman period. Nitrogen isotopic signatures influenced mortality in both periods, showing a quadratic and a linear effect for Roman Imperial and Medieval populations, respectively. No influence of carbon isotopic signatures has been detected for Roman Imperial populations. Conversely, increased mortality risk for rising carbon isotopic values was observed in Medieval samples.


2021 ◽  
Author(s):  
Janica C. Bühler ◽  
Josefine M. Axelsson ◽  
Franziska A. Lechleitner ◽  
Jens Fohlmeister ◽  
Allegra N. LeGrande ◽  
...  

Abstract. The incorporation of water isotopologues into the hydrology of general circulation models (GCMs) facilitates the comparison between modelled and measured proxy data in paleoclimate archives. However, the variability and drivers of measured and modelled water isotopologues, and indeed the diversity of their representation in different models are not well constrained. Improving our understanding of this variability in past and present climates will help to better constrain future climate change projections and decrease their range of uncertainty. Speleothems are a precisely datable paleoclimate archive and provide well preserved (semi-)continuous multivariate isotope time series in the lower and mid-latitudes, and are, therefore, well suited to assess climate and isotope variability on decadal and longer timescales. However, the relationship between speleothem oxygen and carbon isotopes to climate variables also depends on site-specific parameters, and their comparison to GCMs is not always straightforward. Here we compare speleothem oxygen and carbon isotopic signatures from the Speleothem Isotopes Synthesis and AnaLysis database version 2 (SISALv2) to the output of five different water-isotope-enabled GCMs (ECHAM5-wiso, GISS-E2-R, iCESM, iHadCM3, and isoGSM) over the last millennium (850–1850 common era, CE). We systematically evaluate differences and commonalities between the standardized model simulation outputs. The goal is to distinguish climatic drivers of variability for both modelled and measured isotopes. We find strong regional differences in the oxygen isotope signatures between models that can partly be attributed to differences in modelled temperatures. At low latitudes, precipitation amount is the dominant driver for water isotope variability, however, at cave locations the agreement between modelled temperature variability is higher than for precipitation variability. While modelled isotopic signatures at cave locations exhibited extreme events coinciding with changes in volcanic and solar forcing, such fingerprints are not apparent in the speleothem isotopes, and may be attributed to the lower temporal resolution of speleothem records compared to the events that are to be detected. Using spectral analysis, we can show that all models underestimate decadal and longer variability compared to speleothems, although to varying extent. We found that no model excels in all analyzed comparisons, although some perform better than the others in either mean or variability. Therefore, we advise a multi-model approach, whenever comparing proxy data to modelled data. Considering karst and cave internal processes through e.g. isotope-enabled karst models may alter the variability in speleothem isotopes and play an important role in determining the most appropriate model. By exploring new ways of analyzing the relationship between the oxygen and carbon isotopes, their variability, and co-variability across timescales, we provide methods that may serve as a baseline for future studies with different models using e.g. different isotopes, different climate archives, or time periods.


Author(s):  
Futa Nakasugi ◽  
Motohiro Shimanaga ◽  
Hidetaka Nomaki ◽  
Hiromi Kayama Watanabe ◽  
Tomo Kitahashi ◽  
...  

Abstract Dirivultid copepods (Siphonostomatoida), one of the most successful meiobenthic organisms found at deep-sea hydrothermal vents, have been the focus of most previous ecological studies among meiofauna in these habitats. The ecology of Harpacticoida, a major benthic copepod group in typical deep-sea floor, however, is not well understood in terms of variations in community structure and controlling factors at venting sites. The spatial heterogeneities in benthic harpacticoid composition and their association with environmental parameters were investigated at hydrothermal vent chimney structures in the calderas of three neighbouring sea knolls (Bayonnaise Knoll, Myojin Knoll and Myojin-sho Caldera) in the western North Pacific. While a previous study had reported the distribution of dirivultids was strongly associated with spatial differences in stable carbon isotopic signatures (δ13C) of organic matter in the detritus on active chimneys in the field, multivariate analyses detected no significant corelation between the parameter and harpacticoid composition in this study. Instead, high associations of the harpacticoid composition with differences in water depth and total organic carbon (TOC) concentration were detected. Ectinosomatidae dominated at vent sites with lower TOC values in the shallowest Bayonnaise Knoll, while they were less prevalent at deeper vent fields in the other knolls, where Miraciidae was the most abundant family. This study indicated the availability of vent chemoautotrophic carbon is not a primary factor controlling the composition of harpacticoids even in the habitats on the hydrothermal vents, but instead by the food amount, regardless of its resources (including marine snow from the sea surface), in the study area.


2014 ◽  
Vol 102 (6) ◽  
pp. 1606-1611 ◽  
Author(s):  
Brenton Ladd ◽  
Pablo L. Peri ◽  
David A. Pepper ◽  
Lucas C. R. Silva ◽  
Douglas Sheil ◽  
...  

1997 ◽  
Vol 37 (1) ◽  
pp. 472 ◽  
Author(s):  
C.B. Foster ◽  
G.A. Logan ◽  
R.E. Summons ◽  
J.D. Gorter ◽  
D.S. Edwards

A global stratotype section for the boundary between the Permian and Triassic Systems is yet to be agreed internationally. However, in many parts of the world, there is evidence of massive extinction of marine fauna at or near the P-T boundary. In the absence of marine fauna, as is the case in most of Australia, changes in plant microfossils, in carbon isotopic signatures, and radiometric dates using SHRIMP, have been used to mark the boundary. The leading questions which arise from this are whether these events are synchronous and how they affect exploration.In eastern Australia, the top of the coal measures has been used as the top of the Permian, although presently only plant microfossils can be used to determine if the youngest seam is present. This has important economic consequences for determination of volumes of effective source rock and for estimates of coal-bed methane. It has been suggested that changes in the carbon isotopic signatures (δ13C) of either organic matter (δ13Corg) or carbonates (δ13Ccarb) can be used to delimit the P-T boundary. From studies of (δ13Ccarb data, Scholle (1995) concluded that 'the establishment of a secular variation curve which has enough detail and reliability to be used as a chemostratigraphic tool still lies in the future'. We concur, and demonstrate for organic carbon that, while there is evidence for secular change, the 13C signature is complicated and overprinted by contributions from different parent plant types; wood-dominated organics are typically −24 %o, while non-woody matter is significantly lighter (−30 %o). There is no simple relationship of δ13Corg to geological age. The consistency of our data, from both the east and west of Australia, allows us to construct a model to predict probable depositional and organic facies using either carbon isotopes (from kerogen or oil) or quantitative estimates of organic matter from standard palynlogical slides. This offers a novel and usefl predictive tool for hydrocarbon exploration.


Geobiology ◽  
2004 ◽  
Vol 2 (1) ◽  
pp. 31-47 ◽  
Author(s):  
Linda L. Jahnke ◽  
Tsegereda Embaye ◽  
Janet Hope ◽  
Kendra A. Turk ◽  
Mark Van Zuilen ◽  
...  

Sociobiology ◽  
2018 ◽  
Vol 65 (1) ◽  
pp. 38 ◽  
Author(s):  
Cassiano Sousa Rosa ◽  
Paulo Fellipe Cristaldo ◽  
Daniela Faria Florencio ◽  
Alessandra Marins ◽  
Eraldo R Lima ◽  
...  

Inter-specific symbiotic links are often reinforced by morphological, physiological, or behavioural trait modification undergone by the associated species. In some cases, such as in physogastric termitophile staphylinids, such modifications do facilitate the social interaction. Here we inspect chemical traits of the physogastric staphylinid Corotoca melantho (Insecta: Coleoptera) and its termite host Constrictotermes cyphergaster (Insecta: Blattodea: Isoptera), aiming to verify whether staphylinids resemble their host. First, we compared CHC profiles of hosts and guests within and among termitaria, to gather evidence on the origin of such profiles in guests. Then, we examined nitrogen and carbon isotopic signatures of these cohabitants to inspect whether chemical disguise is achieved by predation of host workers by staphylinids. Beetles presented CHC more similar to the CHC of their cohabiting termites than to (i) their conspecifics and (ii) termites from another nest, thereby favouring the hypothesis on CHC acquisition by guests. Isotopic signatures revealed that such similarities could not be majorly determined by share nutrition between these cohabitants. In general, our results evidenced that chemical disguise in termitophiles may function as a strategy for social integration in morphological mimics.


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