Sonoelectrochemical Synthesis of Nano Zinc(II) Complex with 2-Methyl-8-Hydroxyquinoline Ligand: a Precursor to Produce Pure Phase Nano-Sized Zinc(II) Oxide

2017 ◽  
Vol 27 (2) ◽  
pp. 715-722 ◽  
Author(s):  
Vida Jodaian ◽  
Akram Shahrjerdi ◽  
Pari Mirahmadpour
Keyword(s):  
Pure Phase ◽  
Sonoelectrochemical Synthesis ◽  
Nano Zinc

The role of differential phase contrast in electron microscopy

1978 ◽  
Vol 36 (1) ◽  
pp. 176-177
Author(s):  
E.M. Waddell ◽  
J.N. Chapman ◽  
R.P. Ferrier
Keyword(s):  
Phase Contrast ◽  
Practical Method ◽  
Position Vector ◽  
Differential Phase ◽  
Pure Phase ◽  
Differential Phase Contrast ◽  
The Difference ◽  
Image Position ◽  
First Moment

Dekkers and de Lang (1977) have discussed a practical method of realising differential phase contrast in a STEM. The method involves taking the difference signal from two semi-circular detectors placed symmetrically about the optic axis and subtending the same angle (2α) at the specimen as that of the cone of illumination. Such a system, or an obvious generalisation of it, namely a quadrant detector, has the characteristic of responding to the gradient of the phase of the specimen transmittance. In this paper we shall compare the performance of this type of system with that of a first moment detector (Waddell et al.1977).For a first moment detector the response function R(k) is of the form R(k) = ck where c is a constant, k is a position vector in the detector plane and the vector nature of R(k)indicates that two signals are produced. This type of system would produce an image signal given bywhere the specimen transmittance is given by a (r) exp (iϕ (r), r is a position vector in object space, ro the position of the probe, ⊛ represents a convolution integral and it has been assumed that we have a coherent probe, with a complex disturbance of the form b(r-ro) exp (iζ (r-ro)). Thus the image signal for a pure phase object imaged in a STEM using a first moment detector is b2 ⊛ ▽ø. Note that this puts no restrictions on the magnitude of the variation of the phase function, but does assume an infinite detector.

Magnetic and dielectric properties of BiFeO3 nanoparticles

2015 ◽  
Vol 7 (2) ◽  
pp. 1393-1403
Author(s):  
Dr R.P VIJAYALAKSHMI ◽  
N. Manjula ◽  
S. Ramu ◽  
Amaranatha Reddy
Keyword(s):  
Diffuse Reflectance Spectrum ◽  
Precipitation Method ◽  
Secondary Phases ◽  
X Ray Diffraction ◽  
Bifeo3 Nanoparticles ◽  
Transmission Electron ◽  
Multiferroic Bifeo3 ◽  
Pure Phase ◽  
Simple Chemical ◽  
Co Precipitation

Single crystalline nano-sized multiferroic BiFeO3 (BFO) powders were synthesized through simple chemical co-precipitation method using polyethylene glycol (PEG) as capping agent. We obtained pure phase BiFeO3 powder by controlling pHand calcination temperature. From X-ray diffraction studies the nanoparticles were unambiguously identified to have a rhombohedrally distorted perovskite structure belonging to the space group of R3c. No secondary phases were detected. It indicates single phase structure. EDX spectra indicated the appearance of three elements Bi, Fe, O in 1:1:3. From the UV-Vis diffuse reflectance spectrum, the absorption cut-off wavelength of the BFO sample is around 558nm corresponding to the energy band gap of 2.2 eV. The size (60-70 nm) and morphology of the nanoparticles have been analyzed using transmission electron microscopy (TEM).   Linear M−H behaviour and slight hysteresis at lower magnetic field is observed for BiFeO3 nanoparticles from Vibrating sample magnetometer studies. It indicates weak ferromagnetic behaviour at room temperature. From dielectric studies, the conductivity value is calculated from the relation s = L/RbA Sm-1 and it is around 7.2 x 10-9 S/m.

scholarly journals Post-illumination activity of Bi2WO6 in the dark from the photocatalytic “memory” effect

2021 ◽  
Vol 10 (2) ◽  
pp. 355-367
Author(s):  
Weiyi Yang ◽  
Yan Chen ◽  
Shuang Gao ◽  
Licheng Sang ◽  
Ruoge Tao ◽  
...  
Keyword(s):  
Memory Effect ◽  
Reduction Process ◽  
Production Performance ◽  
Intrinsic Activity ◽  
Light Illumination ◽  
Two Phase ◽  
Photogenerated Electrons ◽  
Composite Photocatalysts ◽  
Pure Phase ◽  
Activity Loss

AbstractPhotocatalysts with the photocatalytic “memory” effect could resolve the intrinsic activity loss of traditional photocatalysts when the light illumination is turned off. Due to the dual requirements of light absorption and energy storage/release functions, most previously reported photocatalysts with the photocatalytic “memory” effect were composite photocatalysts of two phase components, which may lose their performance due to gradually deteriorated interface conditions during their applications. In this work, a simple solvothermal process was developed to synthesize Bi2WO6 microspheres constructed by aggregated nanoflakes. The pure phase Bi2WO6 was found to possess the photocatalytic “memory” effect through the trapping and release of photogenerated electrons by the reversible chemical state change of W component in the (WO4)2− layers. When the illumination was switched off, Bi2WO6 microspheres continuously produced H2O2 in the dark as those trapped photogenerated electrons were gradually released to react with O2 through the two-electron O2 reduction process, resulting in the continuous disinfection of Escherichia coli bacteria in the dark through the photocatalytic “memory” effect. No deterioration of their cycling H2O2 production performance in the dark was observed, which verified their stable photocatalytic “memory” effect.

Controlled synthesis of pure-phase metastable tetragonal Nb2O5 anode material for high-performance lithium batteries

2021 ◽  
Vol 299 ◽  
pp. 122136
Author(s):  
Huibin Ding ◽  
Zihan Song ◽  
Kai Feng ◽  
Hongzhang Zhang ◽  
Huamin Zhang ◽  
...  
Keyword(s):  
Anode Material ◽  
Lithium Batteries ◽  
High Performance ◽  
Controlled Synthesis ◽  
Pure Phase

scholarly journals Controlled Synthesis of CuS and Cu9S5 and Their Application in the Photocatalytic Mineralization of Tetracycline

Catalysts ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 899
Author(s):  
Murendeni P. Ravele ◽  
Opeyemi A. Oyewo ◽  
Damian C. Onwudiwe
Keyword(s):  
Electron Microscopy ◽  
Visible Light ◽  
Blue Shift ◽  
X Ray Diffraction ◽  
X Ray ◽  
Copper Sulfides ◽  
Transmission Electron ◽  
Single Source Precursor ◽  
Pure Phase ◽  
Pure Phases

Pure-phase Cu2−xS (x = 1, 0.2) nanoparticles have been synthesized by the thermal decomposition of copper(II) dithiocarbamate as a single-source precursor in oleylamine as a capping agent. The compositions of the Cu2−xS nanocrystals varied from CuS (covellite) through the mixture of phases (CuS and Cu7.2S4) to Cu9S5 (digenite) by simply varying the temperature of synthesis. The crystallinity and morphology of the copper sulfides were studied using X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM), which showed pure phases at low (120 °C) and high (220 °C) temperatures and a mixture of phases at intermediate temperatures (150 and 180 °C). Covellite was of a spherical morphology, while digenite was rod shaped. The optical properties of these nanocrystals were characterized by UV−vis–NIR and photoluminescence spectroscopies. Both samples had very similar absorption spectra but distinguishable fluorescence properties and exhibited a blue shift in their band gap energies compared to bulk Cu2−xS. The pure phases were used as catalysts for the photocatalytic degradation of tetracycline (TC) under visible-light irradiation. The results demonstrated that the photocatalytic activity of the digenite phase exhibited higher catalytic degradation of 98.5% compared to the covellite phase, which showed 88% degradation within the 120 min reaction time using 80 mg of the catalysts. The higher degradation efficiency achieved with the digenite phase was attributed to its higher absorption of the visible light compared to covellite.

scholarly journals Nanominerals: Fabrication Methods, Benefits and Hazards, and Their Applications in Ruminants with Special Reference to Selenium and Zinc Nanoparticles

Animals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 1916
Author(s):  
Sameh A. Abdelnour ◽  
Mahmoud Alagawany ◽  
Nesrein M. Hashem ◽  
Mayada R. Farag ◽  
Etab S. Alghamdi ◽  
...  
Keyword(s):  
Assisted Reproductive Technologies ◽  
Reproductive Technologies ◽  
Nutrient Metabolism ◽  
Animal Products ◽  
Positive Effects ◽  
Ethical Implications ◽  
Livestock Sector ◽  
Efficient Delivery ◽  
Nano Zinc ◽  
Organic Minerals

Nanotechnology is one of the major advanced technologies applied in different fields, including agriculture, livestock, medicine, and food sectors. Nanomaterials can help maintain the sustainability of the livestock sector through improving quantitative and qualitative production of safe, healthy, and functional animal products. Given the diverse nanotechnology applications in the animal nutrition field, the use of nanomaterials opens the horizon of opportunities for enhancing feed utilization and efficiency in animal production. Nanotechnology facilitates the development of nano vehicles for nutrients (including trace minerals), allowing efficient delivery to improve digestion and absorption for better nutrient metabolism and physiology. Nanominerals are interesting alternatives for inorganic and organic minerals for animals that can substantially enhance the bioavailability and reduce pollution. Nanominerals promote antioxidant activity, and improve growth performance, reproductive performance, immune response, intestinal health, and the nutritional value of animal products. Nanominerals are also helpful for improving assisted reproductive technologies (ART) outcomes by enriching media for cryopreservation of spermatozoa, oocytes, and embryos with antioxidant nanominerals. Despite the promising positive effects of nanominerals on animal performance and health, there are various challenges related to nanominerals, including their metabolism and fate in the animal’s body. Thus, the economic, legal, and ethical implications of nanomaterials must also be considered by the authority. This review highlights the benefits of including nanominerals (particularly nano-selenium and nano-zinc) in animal diets and/or cryopreservation media, focusing on modes of action, physiological effects, and the potential toxicity of their impact on human health.

Effect of Calcination on the Basic Strength of Surface Modified Nano-Zinc Oxide Characterised by FTIR and Back Titration Methods

2015 ◽  
Vol 1107 ◽  
pp. 326-332
Author(s):  
Abdul Rahim Yacob ◽  
Kamaluddeen Suleiman Kabo
Keyword(s):  
Zinc Oxide ◽  
Metal Oxides ◽  
Base Catalysis ◽  
Nano Zinc Oxide ◽  
Back Titration ◽  
And Performance ◽  
Nano Zinc ◽  
Surface Modified ◽  
Heterogeneous Base ◽  
Basic Strength

The use of metal oxides in heterogeneous base catalysis has gained a large interest due to their application in many chemical and industrial processes and is environmental friendly. Basic metal oxides are commonly used and their structures, morphology and performance can be modified by method of preparation and thermal activation. In this study, surface modified amphoteric zinc oxide was prepared via hydration-dehydration method and characterised by TGA and FTIR. The basic strength at various temperatures is characterised by FTIR and back titration analyses. The results shows that surface modified zinc oxide has the highest basic strength of 1.453mmolg-1at 400°C making it a relatively good and suitable compound for use in heterogeneous basic catalysis. This result is also supported by FTIR spectra which show possible relationship between the Lewis O2-and increasing basic strength.

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