Structural and thermodynamic characteristics of ionic associates in vapors over sodium bromide and iodide

2010 ◽  
Vol 51 (2) ◽  
pp. 231-237 ◽  
Author(s):  
T. P. Pogrebnaya ◽  
A. M. Pogrebnoi ◽  
L. S. Kudin
Keyword(s):  
Thermodynamic Characteristics ◽  
Sodium Bromide ◽  
Ionic Associates

ABOUT HEAT CAPACITY OF TITANIUM CARBIDE TiCx

2019 ◽  
pp. 56-66
Author(s):  
I. Khidirov ◽  
V. V. Getmanskiy ◽  
A. S. Parpiev ◽  
Sh. A. Makhmudov
Keyword(s):  
Heat Capacity ◽  
High Temperature ◽  
Titanium Carbide ◽  
Temperature Dependence ◽  
Carbon Concentration ◽  
Room Temperature ◽  
Thermodynamic Characteristics ◽  
Liquid Nitrogen Temperature ◽  
Analysis Data ◽  
Thermal Excitation

This work relates to the field of thermophysical parameters of refractory interstitial alloys. The isochoric heat capacity of cubic titanium carbide TiCx has been calculated within the Debye approximation in the carbon concentration  range x = 0.70–0.97 at room temperature (300 K) and at liquid nitrogen temperature (80 K) through the Debye temperature established on the basis of neutron diffraction analysis data. It has been found out that at room temperature with decrease of carbon concentration the heat capacity significantly increases from 29.40 J/mol·K to 34.20 J/mol·K, and at T = 80 K – from 3.08 J/mol·K to 8.20 J/mol·K. The work analyzes the literature data and gives the results of the evaluation of the high-temperature dependence of the heat capacity СV of the cubic titanium carbide TiC0.97 based on the data of neutron structural analysis. It has been proposed to amend in the Neumann–Kopp formula to describe the high-temperature dependence of the titanium carbide heat capacity. After the amendment, the Neumann–Kopp formula describes the results of well-known experiments on the high-temperature dependence of the heat capacity of the titanium carbide TiCx. The proposed formula takes into account the degree of thermal excitation (a quantized number) that increases in steps with increasing temperature.The results allow us to predict the thermodynamic characteristics of titanium carbide in the temperature range of 300–3000 K and can be useful for materials scientists.

Determination of Some Nitrophenols by Atomic Absorption Spectrometry (AAS) After Extraction of Ionic Associates Involving the Bipyridylocopper(II) or Phenanthrolinocopper(II) Complex

1994 ◽  
Vol 59 (10) ◽  
pp. 2227-2234 ◽  
Author(s):  
Václav Stužka ◽  
Jaromír Souček
Keyword(s):  
Molecular Weight ◽  
Atomic Absorption Spectrometry ◽  
Atomic Absorption ◽  
Methyl Isobutyl Ketone ◽  
Absorption Spectrometry ◽  
Methyl Isobutyl ◽  
Isobutyl Ketone ◽  
Indirect Determination ◽  
Ionic Associates

A new method has been developed for the indirect determination of nitroso- and nitrophenols by atomic absorption spectrometry (AAS) after extraction of ionic associates involving bipyridylocopper(II) (CuDP) or phenanthrolinocopper(II) (CuPH) complexes. Nitrobenzene and methyl isobutyl ketone appeared to be suitable for the extraction. It was possible to determine several tenths to hundredths of a milligram of nitrophenol in a litre. Extractable associates with CuDP and CuPH are formed by phenols possessing two substituents or by higher molecular weight phenols such as naphthol or hydroxyquinoline. Monosubstituted phenols fail to form associates of this kind.

Surface chemistry of structural materials subjected to corrosion

2020 ◽  
Vol 92 (8) ◽  
pp. 1227-1237
Author(s):  
Ivan. S. Pytskii ◽  
Irina V. Minenkova ◽  
Elena S. Kuznetsova ◽  
Rinad Kh. Zalavutdinov ◽  
Aleksei V. Uleanov ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Surface Condition ◽  
Thermodynamic Characteristics ◽  
Complete Information ◽  
Structural Materials ◽  
Ionization Mass ◽  
Surface Layers ◽  
Surface Contaminants ◽  
Gas And Liquid Chromatography ◽  
Mass Spectrometric Approach

AbstractThe article describes a comprehensive mass spectrometric approach to the study of surfaces of structural materials. The combined use of thermal desorption mass spectrometry, gas and liquid chromatography, and laser desorption/ionization mass spectrometry (LDI) to provide information about the surface and surface layers of materials is proposed. The suggested method allows one to determine the thermodynamic characteristics of compounds and surface contaminants adsorbed on surfaces, as well as surface layers, to determine the composition of volatile and non-volatile contaminants on the surface, and to determine the nature of the distribution over the surface of these compounds. The method allows to obtain the most complete information about the surface condition and can be used to predict the life of structural materials.

Effect of pre-swirl nozzle closure modes on unsteady flow and heat transfer characteristics in a pre-swirl system of aero-engine

2021 ◽  
pp. 095441002110191
Author(s):  
Gaowen Liu ◽  
Zhao Lei ◽  
Aqiang Lin ◽  
Qing Feng ◽  
Yan Chen
Keyword(s):  
Heat Transfer ◽  
Mass Flow Rate ◽  
Mass Flow ◽  
Flow Rate ◽  
Temperature Drop ◽  
Thermodynamic Characteristics ◽  
Circumferential Direction ◽  
Temperature Changes ◽  
Air Supply ◽  
Cooling Air

The pre-swirl system is of great importance for temperature drop and cooling air supply. This study aims to investigate the influencing mechanism of heat transfer, nonuniform thermodynamic characteristics, and cooling air supply sensitivity in a pre-swirl system by the application of the flow control method of the pre-swirl nozzle. A novel test rig was proposed to actively control the supplied cooling air mass flow rate by three adjustable pre-swirl nozzles. Then, the transient problem of the pre-swirl system was numerically conducted by comparison with 60°, 120°, and 180° rotating disk cavity cases, which were verified with the experiment results. Results show that the partial nozzle closure will aggravate the fluctuation of air supply mass flow rate and temperature. When three parts of nozzles are closed evenly at 120° in the circumferential direction, the maximum value of the nonuniformity coefficient of air supply mass flow rate changes to 3.1% and that of temperature changes to 0.25%. When six parts of nozzles are closed evenly at 60° in the circumferential direction, the maximum nonuniformity coefficient of air supply mass flow rate changes to 1.4% and that of temperature changes to 0.20%. However, different partial nozzle closure modes have little effect on the average air supply parameters. Closing 14.3% of the nozzle area will reduce the air supply mass flow rate by 9.9% and the average air supply temperature by about 1 K.

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