Adsorption of Monoazo Dyes (Crocein Orange G and Procion Red MX5B) from Water Using Raw and Acid-Treated Montmorillonite K10: Insight into Kinetics, Isotherm, and Thermodynamic Parameters

2018 ◽  
Vol 229 (10) ◽  
Author(s):  
Gautam Kumar Sarma ◽  
Susmita SenGupta ◽  
Krishna G. Bhattacharyya
Keyword(s):  
Thermodynamic Parameters ◽  
Montmorillonite K10 ◽  
Orange G ◽  
Monoazo Dyes ◽  
Insight Into

The main reasons for substance formation and natural process manifestation

2021 ◽  
pp. 76-96
Author(s):  
Alexander Likhachev
Keyword(s):  
Thermodynamic Parameters ◽  
World History ◽  
Natural Process ◽  
Natural Materials ◽  
Main Factors ◽  
Composition Structure ◽  
The Impact ◽  
Insight Into ◽  
Structure Properties

Natural materials and processes represent the global substance reflecting and determining its formation and existence as a whole and in all its components. Revealing the reasons for their formation and manifestation is crucial. The paper highlights the two main factors: «influences» and «gradients». Influences are interpreted as the impact of some substances and events on other similar parameters, and gradients are vector changes and differences in systems composition, structure, properties, states, energy and thermodynamic parameters. To provide an insight into the role and significance of the above factors and reasons, an attempt was made to consider their potential manifestation throughout the general world history within the existing knowledge about it.

scholarly journals Calorimetric techniques applied to the thermodynamic study of interactions between proteins and polysaccharides

2016 ◽  
Vol 46 (8) ◽  
pp. 1491-1497
Author(s):  
Monique Barreto Santos ◽  
Bernardo de Sá Costa ◽  
Edwin Elard Garcia Rojas
Keyword(s):  
Differential Scanning Calorimetry ◽  
Thermodynamic Parameters ◽  
Isothermal Titration Calorimetry ◽  
Thermal Energy ◽  
Titration Calorimetry ◽  
Biological Macromolecules ◽  
Valuable Insight ◽  
Scanning Calorimetry ◽  
Temperature Scanning ◽  
Insight Into

ABSTRACT: The interactions between biological macromolecules have been important for biotechnology, but further understanding is needed to maximize the utility of these interactions. Calorimetric techniques provide information regarding these interactions through the thermal energy that is produced or consumed during interactions. Notable techniques include differential scanning calorimetry, which generates a thermodynamic profile from temperature scanning, and isothermal titration calorimetry that provide the thermodynamic parameters directly related to the interaction. This review described how calorimetric techniques can be used to study interactions between proteins and polysaccharides, and provided valuable insight into the thermodynamics of their interaction.

scholarly journals Density, viscosity, ultrasonic velocity and excess thermodynamic parameters of ternary liquid mixtures of morpholine + 1,4-dioxane + toluene or nitrobenzene at 308.15 K

2018 ◽  
Vol 83 (10) ◽  
pp. 1131-1142 ◽  
Author(s):  
Krishnamoorthy Umasivakami ◽  
Sundararajan Vaideeswaran ◽  
Venis Rose
Keyword(s):  
Thermodynamic Parameters ◽  
Entire Range ◽  
Isothermal Compressibility ◽  
Excess Volume ◽  
Adiabatic Compressibility ◽  
Polynomial Equation ◽  
Liquid Mixtures ◽  
Ultrasonic Velocities ◽  
Excess Thermodynamic Parameters ◽  
Insight Into

Densities, viscosities and ultrasonic velocities were measured for the two ternary liquid mixtures containing morpholine (1) + 1,4-dioxane (2) + nitrobenzene (3) or + toluene (3) at 308.15 K over the entire range of mole fractions. Thermodynamic parameters, such as excess volume (VE), deviations in adiabatic compressibility (?KS), free length (?LF), isothermal compressibility (??T), free volume (?VF) and viscosity (??) were calculated and applied to the Redlich? Kister polynomial equation to determine the appropriate coefficients. The deviations of the ternary liquid mixtures from their ideal behaviour were determined from the measured and calculated thermodynamic properties. In addition, an insight into the molecular structure and possible interactions for the investigated mixtures was attempted.

scholarly journals Osmium assay in fixatives and stained rat tissues by means of acid and o,o′-dihydroxo substituted monoazo dyes and some flavonoids

2011 ◽  
Vol 9 (5) ◽  
pp. 886-895 ◽  
Author(s):  
Mariana Rydchuk ◽  
Galyna Mykhalyna ◽  
Olga Dobryanska ◽  
Olha Korkuna ◽  
Teodoziya Vrublevska
Keyword(s):  
Azo Dyes ◽  
Rat Tissues ◽  
Clinical Testing ◽  
Eriochrome Black T ◽  
Orange G ◽  
Matrix Components ◽  
Monoazo Dyes ◽  
Dark Blue ◽  
Osmium Determination ◽  
Coloured Compounds

AbstractNew simple, rapid and accurate spectrophotometric techniques for osmium assays in fixatives and stained tissues have been elaborated using acid (Tropaeolin O, Tropaeolin OOO-I, Tropaeolin OOO-II, Orange G), o,o′-dihydroxo substituted azo dyes (Eriochrome Blue Black R, Acid Chrome Dark-Blue, Eriochrome Black T) and flavonoids (morin, quercetin, luteolin). Methods are based on sensitive osmium(IV) reactions with reagents and the formation of stable coloured compounds. Tolerance ratios of main matrix components of histological specimens during Os(IV) spectrophotometric determination with reagents has been established. Results of osmium determination in fixatives and fixed tissues, obtained by means of different reagents, appeared to be sufficiently similar, although effects of matrix components differ. The accuracy of spectrophotometric osmium assay in fixatives with azo dyes has been confirmed with voltammetric investigations. Results obtained from osmium uptake by rat gum tissues are valuable for clinical testing of dental drugs, indicating the influence of drug treatment on the gums.

Supramolecuar Motifs in s-Block Metal-Bound Sulfonated Monoazo Dyes:  The Case of Orange G

2006 ◽  
Vol 45 (7) ◽  
pp. 2965-2971 ◽  
Author(s):  
Alan R. Kennedy ◽  
Jennifer B. A. Kirkhouse ◽  
Lynda Whyte
Keyword(s):  
Orange G ◽  
Monoazo Dyes

Calibration problems in hydrogen luminosities

1966 ◽  
Vol 24 ◽  
pp. 322-330
Author(s):  
A. Beer
Keyword(s):  
Galactic Structure ◽  
B Stars ◽  
Insight Into

The investigations which I should like to summarize in this paper concern recent photo-electric luminosity determinations of O and B stars. Their final aim has been the derivation of new stellar distances, and some insight into certain patterns of galactic structure.

Models of Thermodynamic Properties of Prominences

1979 ◽  
Vol 44 ◽  
pp. 349-355
Author(s):  
R.W. Milkey
Keyword(s):  
Thermodynamic Properties ◽  
Mass Transport ◽  
Emission Spectrum ◽  
Thermodynamic Parameters ◽  
Working Group ◽  
Physical Processes ◽  
Theoretical Concepts ◽  
Group 3 ◽  
Observational Techniques

The focus of discussion in Working Group 3 was on the Thermodynamic Properties as determined spectroscopically, including the observational techniques and the theoretical modeling of physical processes responsible for the emission spectrum. Recent advances in observational techniques and theoretical concepts make this discussion particularly timely. It is wise to remember that the determination of thermodynamic parameters is not an end in itself and that these are interesting chiefly for what they can tell us about the energetics and mass transport in prominences.

Stochasting modeling of planetary ring systems

1984 ◽  
Vol 75 ◽  
pp. 461-469 ◽  
Author(s):  
Robert W. Hart
Keyword(s):  
Maximum Entropy ◽  
Ring System ◽  
The Sun ◽  
Ultimate State ◽  
Interparticle Interactions ◽  
Ring Systems ◽  
First Order ◽  
Planetary Ring ◽  
Insight Into

ABSTRACTThis paper models maximum entropy configurations of idealized gravitational ring systems. Such configurations are of interest because systems generally evolve toward an ultimate state of maximum randomness. For simplicity, attention is confined to ultimate states for which interparticle interactions are no longer of first order importance. The planets, in their orbits about the sun, are one example of such a ring system. The extent to which the present approximation yields insight into ring systems such as Saturn's is explored briefly.

Skeletal elements of crinoid echinoderms: High-resolution structural and microanalytical results

1983 ◽  
Vol 41 ◽  
pp. 194-195
Author(s):  
D. F. Blake ◽  
L. F. Allard ◽  
D. R. Peacor
Keyword(s):  
High Resolution ◽  
Marine Invertebrates ◽  
Sea Urchins ◽  
Structural Features ◽  
Sea Stars ◽  
High Resolution Tem ◽  
Relationship Of ◽  
The Relationship ◽  
Insight Into

Echinodermata is a phylum of marine invertebrates which has been extant since Cambrian time (c.a. 500 m.y. before the present). Modern examples of echinoderms include sea urchins, sea stars, and sea lilies (crinoids). The endoskeletons of echinoderms are composed of plates or ossicles (Fig. 1) which are with few exceptions, porous, single crystals of high-magnesian calcite. Despite their single crystal nature, fracture surfaces do not exhibit the near-perfect {10.4} cleavage characteristic of inorganic calcite. This paradoxical mix of biogenic and inorganic features has prompted much recent work on echinoderm skeletal crystallography. Furthermore, fossil echinoderm hard parts comprise a volumetrically significant portion of some marine limestones sequences. The ultrastructural and microchemical characterization of modern skeletal material should lend insight into: 1). The nature of the biogenic processes involved, for example, the relationship of Mg heterogeneity to morphological and structural features in modern echinoderm material, and 2). The nature of the diagenetic changes undergone by their ancient, fossilized counterparts. In this study, high resolution TEM (HRTEM), high voltage TEM (HVTEM), and STEM microanalysis are used to characterize tha ultrastructural and microchemical composition of skeletal elements of the modern crinoid Neocrinus blakei.

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