scholarly journals Nitrated monoaromatic hydrocarbons (nitrophenols, nitrocatechols, nitrosalicylic acids) in ambient air: levels, mass size distributions and inhalation bioaccessibility

2020 ◽  
Author(s):  
Zoran Kitanovski ◽  
Jan Hovorka ◽  
Jan Kuta ◽  
Cecilia Leoni ◽  
Roman Prokeš ◽  
...  
Keyword(s):  
Size Fraction ◽  
Ambient Air ◽  
Water Soluble ◽  
Solution Ph ◽  
Macrophage Activity ◽  
Mass Size ◽  
Water Soluble Organic Carbon ◽  
Monoaromatic Hydrocarbons ◽  
Toxic Potential ◽  
Bioaccessible Fraction

Abstract Nitrated monoaromatic hydrocarbons (NMAHs) are ubiquitous in the environment and an important part of atmospheric humic-like substances (HULIS) and brown carbon. They are ecotoxic and with underresearched toxic potential for humans. NMAHs were determined in size-segregated ambient particulate matter collected at two urban sites in central Europe, Ostrava and Kladno, Czech Republic. The average sums of 12 NMAHs (Σ12NMAH) measured in winter PM10 samples from Ostrava and Kladno were 102 and 93 ng m−3, respectively, and 8.8 ng m−3 in summer PM10 samples from Ostrava. The concentrations in winter corresponded to 6.3–7.3% and 2.6–3.1% of HULIS-C and water-soluble organic carbon (WSOC), respectively. Nitrocatechols represented 67–93%, 61–73% and 28–96% of NMAHs in PM10 samples collected in winter and summer at Ostrava and in winter at Kladno, respectively. The mass size distribution of the targeted substance classes peaked in the submicrometre size fractions (PM1), often in the PM0.5 size fraction especially in summer. The bioaccessible fraction of NMAHs was determined by leaching PM3 samples in two simulated lung fluids, Gamble’s solution and artificial lysosomal fluid (ALF). More than half of NMAH mass is found bioaccessible, almost complete for nitrosalicylic acids. The bioaccessible fraction was generally higher when using ALF (mimics the chemical environment created by macrophage activity, pH 4.5) than Gamble’s solution (pH 7.4). Bioaccessibility may be negligible for lipophilic substances (i.e. log KOW > 4.5).

scholarly journals Composition and mass size distribution of nitrated and oxygenated aromatic compounds in ambient particulate matter from southern and central Europe – implications for origin

2019 ◽  
Author(s):  
Zoran Kitanovski ◽  
Pourya Shahpoury ◽  
Constantini Samara ◽  
Aristeidis Voliotis ◽  
Gerhard Lammel
Keyword(s):  
Particulate Matter ◽  
Size Fraction ◽  
Ambient Air ◽  
Water Soluble ◽  
Atmospheric Particulate Matter ◽  
Polycyclic Aromatic ◽  
Mass Size ◽  
Water Soluble Organic Carbon ◽  
Soluble Organic Carbon ◽  
The Individual

Abstract. Nitro-monoaromatic hydrocarbons (NMAHs), such as nitrocatechols, nitrophenols and nitrosalicylic acids, are important constituents of atmospheric particulate matter (PM) water soluble organic carbon (WSOC) and humic-like substances (HULIS). Nitrated and oxygenated derivatives of polycyclic aromatic hydrocarbons (NPAHs, OPAHs) are toxic and ubiquitous in the ambient air; due to their light absorption properties, together with NMAHs they are part of aerosol brown carbon (BrC). We investigated the winter concentrations of these substance classes in size-resolved particulate matter (PM) from two urban sites in central and southern Europe, i.e. Mainz (MZ), Germany and Thessaloniki (TK), Greece. ∑11NMAH concentrations in PM10 and total PM were 0.51–8.38 and 12.1–72.1 ng m−3 at MZ and TK site, respectively, whereas ∑8OPAHs were 47–1636 and 858–4306 pg m−3, and ∑17NPAHs were ≤ 90 and 76–578 pg m−3, respectively. NMAHs and the water-soluble OPAHs contributed 0.4 and 1.8 %, and 0.0001 and 0.0002 % to the HULIS mass, at MZ and TK, respectively. The mass size distributions of the individual substances generally peaked in the smallest or second smallest size fraction i.e.,

scholarly journals Composition and mass size distribution of nitrated and oxygenated aromatic compounds in ambient particulate matter from southern and central Europe – implications for the origin

2020 ◽  
Vol 20 (4) ◽  
pp. 2471-2487 ◽  
Author(s):  
Zoran Kitanovski ◽  
Pourya Shahpoury ◽  
Constantini Samara ◽  
Aristeidis Voliotis ◽  
Gerhard Lammel
Keyword(s):  
Particulate Matter ◽  
Total Concentration ◽  
Size Fraction ◽  
Ambient Air ◽  
Water Soluble ◽  
Atmospheric Particulate Matter ◽  
Median Diameter ◽  
Polycyclic Aromatic ◽  
Mass Size ◽  
The Individual

Abstract. Nitro-monoaromatic hydrocarbons (NMAHs), such as nitrocatechols, nitrophenols and nitrosalicylic acids, are important constituents of atmospheric particulate matter (PM) water-soluble organic carbon (WSOC) and humic-like substances (HULIS). Nitrated and oxygenated derivatives of polycyclic aromatic hydrocarbons (NPAHs and OPAHs) are toxic and ubiquitous in the ambient air; due to their light absorption properties, together with NMAHs, they are part of aerosol brown carbon (BrC). We investigated the winter concentrations of these substance classes in size-resolved PM from two urban sites in central and southern Europe, i.e. Mainz (MZ), Germany, and Thessaloniki (TK), Greece. The total concentration of 11 NMAHs (∑11NMAH concentrations) measured in PM10 and total PM were 0.51–8.38 and 12.1–72.1 ng m−3 at the MZ and TK sites, respectively, whereas ∑7OPAHs were 47–1636 and 858–4306 pg m−3, and ∑8NPAHs were ≤90 and 76–578 pg m−3, respectively. NMAHs contributed 0.4 % and 1.8 % to the HULIS mass at MZ and TK, respectively. The mass size distributions of the individual substances generally peaked in the smallest or second smallest size fraction i.e. <0.49 or 0.49–0.95 µm. The mass median diameter (MMD) of NMAHs was 0.10 and 0.27 µm at MZ and TK, respectively, while the MMDs of NPAHs and OPAHs were both 0.06 µm at MZ and 0.12 and 0.10 µm at TK. Correlation analysis between NMAHs, NPAHs, and OPAHs from one side and WSOC, HULIS, sulfate, and potassium from the other suggested that fresh biomass burning (BB) and fossil fuel combustion emissions dominated at the TK site, while aged air masses were predominant at the MZ site.

scholarly journals Characteristics of Carbonaceous PM2.5 in a Small Residential City in Korea

Atmosphere ◽  
2018 ◽  
Vol 9 (12) ◽  
pp. 490 ◽  
Author(s):  
Jong-Min Park ◽  
Young-Ji Han ◽  
Sung-Hwan Cho ◽  
Hyun-Woong Kim
Keyword(s):  
Organic Carbon ◽  
Strong Correlation ◽  
Sampling Period ◽  
Ambient Air ◽  
Quality Standard ◽  
Water Soluble ◽  
Biomass Combustion ◽  
Polycyclic Aromatic ◽  
Water Soluble Organic Carbon ◽  
Ambient Air Quality Standard

PM2.5 has been a serious issue in South Korea not only in urban and industrial areas but also in rural and background areas. In this study, PM2.5 and its carbonaceous compounds including organic carbon (OC), elemental carbon (EC), water-soluble organic carbon (WSOC), and polycyclic aromatic hydrocarbons (PAHs) were collected and analyzed in a small residential city. The PM2.5 concentration frequently exceeded the national ambient air quality standard during the spring and the winter, which often occurred concurrently with fog and mist events. Over the whole sampling period, both OC and the OC/EC ratio were considerably higher than the ratios in other cities in Korea, which suggests that sources other than vehicular emissions were important. The top 10% of OC/EC ratio samples could be explained by regional and long-range transport because there was a strong correlation between primary and secondary organic carbon. However, biomass combustion was likely to account for the consistently high OC concentration due to a strong correlation between WSOC and primary OC as well as the diagnostic ratio results of PAHs.

scholarly journals Desiccation time and rainfall control gaseous carbon fluxes in an intermittent stream

2021 ◽  
Author(s):  
Maria Isabel Arce ◽  
Mia M. Bengtsson ◽  
Daniel von Schiller ◽  
Dominik Zak ◽  
Jana Täumer ◽  
...  
Keyword(s):  
Water Soluble ◽  
Intermittent Flow ◽  
Dry Period ◽  
Intermittent Stream ◽  
Aerobic Activity ◽  
Water Soluble Organic Carbon ◽  
Soluble Organic Carbon ◽  
Microbial C ◽  
Global Biogeochemical Cycles ◽  
The Impact

AbstractDroughts are recognized to impact global biogeochemical cycles. However, the implication of desiccation on in-stream carbon (C) cycling is not well understood yet. We subjected sediments from a lowland, organic rich intermittent stream to experimental desiccation over a 9-week-period to investigate temporal changes in microbial functional traits in relation to their redox requirements, carbon dioxide (CO2) and methane (CH4) fluxes and water-soluble organic carbon (WSOC). Concurrently, the implications of rewetting by simulated short rainfalls (4 and 21 mm) on gaseous C fluxes were tested. Early desiccation triggered dynamic fluxes of CO2 and CH4 with peak values of 383 and 30 mg C m−2 h−1 (mean ± SD), respectively, likely in response to enhanced aerobic mineralization and accelerated evasion. At longer desiccation, CH4 dropped abruptly, likely because of reduced abundance of anaerobic microbial traits. The CO2 fluxes ceased later, suggesting aerobic activity was constrained only by extended desiccation over time. We found that rainfall boosted fluxes of CO2, which were modulated by rainfall size and the preceding desiccation time. Desiccation also reduced the amount of WSOC and the proportion of labile compounds leaching from sediment. It remains questionable to which extent changes of the sediment C pool are influenced by respiration processes, microbial C uptake and cell lysis due to drying-rewetting cycles. We highlight that the severity of the dry period, which is controlled by its duration and the presence of precipitation events, needs detailed consideration to estimate the impact of intermittent flow on global riverine C fluxes.

scholarly journals Size-Segregated Atmospheric Humic-Like Substances (HULIS) in Shanghai: Abundance, Seasonal Variation, and Source Identification

Atmosphere ◽  
2021 ◽  
Vol 12 (5) ◽  
pp. 526
Author(s):  
Tianming Sun ◽  
Rui Li ◽  
Ya Meng ◽  
Yu Han ◽  
Hanyun Cheng ◽  
...  
Keyword(s):  
Seasonal Variation ◽  
Size Distribution ◽  
Principal Component ◽  
Water Soluble ◽  
Atmospheric Particulate Matter ◽  
Biomass Combustion ◽  
Vehicle Exhaust ◽  
Total Suspended Particulates ◽  
Condensation Mode ◽  
Water Soluble Organic Carbon

Humic-like substances (HULIS) are of great interest due to their optical and chemical characteristics. In this study, a total of 180 samples of atmospheric particulate matter (PM) of different sizes were collected from summer 2018 to spring 2019, in order to analyze the size distribution, to investigate the seasonal variation and then to identify the key sources of HULIS. The annual mean concentration of HULIS in the total suspended particulates reached 5.12 ± 1.42 μg/m3. The HULIS concentration was extremely higher in winter (8.35 ± 2.06 μg/m3) than in autumn (4.88 ± 0.95 μg/m3), in summer (3.62 ± 1.68 μg/m3) and in spring (3.36 ± 0.99 μg/m3). The average annual ratio of water-soluble organic carbon (WSOC) to OC and the ratio of HULIS to WSOC reached 0.546 ± 0.092 and 0.56 ± 0.06, respectively. Throughout the whole year, the size distributions of WSOC and HULIS-C were relatively smooth. The peaks of WSOC appeared at 1.8~3.2 μm and 0.56~1.0 μm, while the peaks of HULIS-C were located at 3.2~5.6 μm, 1.0~1.8 μm and 0.18~0.32 μm. The distribution of the HULIS particle mode was similar in spring, summer and autumn, while there was a lower proportion of the coarse mode and a higher proportion of the condensation mode in winter. By using the comprehensive analysis of principal component analysis (PCA), air mass backward trajectories (AMBTs) and fire point maps, key sources of WSOC and HULIS in Shanghai were identified as biomass combustion (48.42%), coal combustion (17.49%), secondary formation (16.07%) and vehicle exhaust (5.37%). The remaining part might be contributed by crustal dust sources, marine sources and/or other possible sources. This study provides new insight into the characteristics and size distribution of HULIS in Shanghai, thereby providing a practical base for further modeling.

Transport of soluble organic and inorganic carbon in sandy soils under nitrogen fertilization

1999 ◽  
Vol 79 (2) ◽  
pp. 303-310 ◽  
Author(s):  
F. L. Wang ◽  
A. K. Alva
Keyword(s):  
Nitrogen Fertilization ◽  
Inorganic Carbon ◽  
Average Rate ◽  
Sandy Soils ◽  
Water Soluble ◽  
Total Carbon ◽  
Total Carbon Content ◽  
Water Soluble Organic Carbon ◽  
Isobutylidene Diurea ◽  
Leaching Condition

Leaching of water soluble soil carbon plays an important role in downward transport of soil nutrients and pollutants and may be influenced by soil and management factors. We examined the leaching of water soluble carbon from two sandy soils under nitrogen fertilization by adapting an intermittent leaching-incubation technique using packed soil columns (94 × 10 cm). After 30 d, cumulative amounts of water-soluble organic carbon (SOC) leached from the Candler and Wabasso sand for various treatments in mg C column−1 were: 77 and 302 (NH4NO3), 64 and 265 (control), and 45 and 239 (isobutylidene diurea, IBDU), respectively. The IBDU and NH4NO3 treatments increased the leaching of water-soluble inorganic carbon (SIC), which ranged from 2 to 38 mg C column−1 over 30 d. At the end of eight cycles of leaching/incubation, the total carbon content increased at depth (control and NH4NO3 treatment) in the Candler sand, but decreased in the Wabasso sand. In the first leaching event, the average rate of SOC leaching from the Wabasso sand was 26 mg C column−1 d−1 which dropped rapidly to about 5 mg C column−1 d−1 towards the end of the experiment. The rate of SOC leaching from the Candler sand was much lower (<8 mg C column−1 d−1) than the rate of SOC leaching from the Wabasso sand. Compared with the unamended treatments, application of NH4NO3 increased and IBDU decreased the leaching of SOC in both soils. These effects of N application were considerable during the initial two to three leaching events only. Our results suggest that the initial rainfalls that follow a dry period may be critical for transporting SOC from the upper layer of these sandy soils. Key words: C leaching, sandy soil, intermittent leaching condition, isobutylidene

scholarly journals DUST FALL RATE AND ITS COMPOSITION IN CHANDRAPUR INDUSTRIAL CLUSTER, CENTRAL INDIA

2015 ◽  
Vol 4 (3) ◽  
pp. 96-110 ◽  
Author(s):  
R. K. Kamble
Keyword(s):  
Central India ◽  
Sampling Period ◽  
Industrial Cluster ◽  
Ambient Air ◽  
Industrial Area ◽  
Residential Area ◽  
Water Soluble ◽  
Fall Rate ◽  
Dust Fall ◽  
Sampling Locations

  Dust is one of the significant air pollutants in ambient air of Chandrapur industrial cluster. A study was carried out to ascertain the dust fall rate in four sampling locations in the Chandrapur industrial cluster of Chandrapur district, central India. The sampling was carried out by dust fall jar method in winter season (2014-2015) and dust fall rate was estimated gravimetrically. Maximum dust fall rate was recorded in Nakoda 246.67 MT sq km-1 month-1 (industrial area, downwind direction), followed by CSTPS colony 171.77 MT sq km-1 month-1 (industrial area, downwind direction) whereas minimum concentration was found in Babupeath 55.54 MT sq km-1 month-1 (residential area, downwind direction) for December-January. Whereas, during sampling period of February-March maximum dust fall rate was observed to be 278.14 MT sq km-1 month-1 at Babupeath (residential area, upwind direction) and minimum dust fall rate was observed at Ballarpur 173.74 MT sq km-1 month-1 (industrial, upwind direction). The results indicated that dust fall rate for the sampling period of December-January in industrial cluster region was higher as compared with residential region. It has been also observed that upwind direction sampling locations had lesser dust fall rate as compared with downwind direction. The composition of dust fall from study area was dominated by water soluble components. Water insoluble components were comprised of inorganic insoluble and volatile matter. Total inorganic component per cent by weight was maximum in dust.International Journal of Environment Volume-4, Issue-3, June-August 2015Page: 96-110

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