High Temperature Thermoelectric Device Concept Using Large Area PN Junctions

2014 ◽  
Vol 43 (6) ◽  
pp. 2376-2383 ◽  
Author(s):  
R. Chavez ◽  
S. Angst ◽  
J. Hall ◽  
J. Stoetzel ◽  
V. Kessler ◽  
...  
2008 ◽  
Vol 1069 ◽  
Author(s):  
Ryoji Kosugi ◽  
Toyokazu Sakata ◽  
Yuuki Sakuma ◽  
Tsutomu Yatsuo ◽  
Hirofumi Matsuhata ◽  
...  

ABSTRACTIn practical use of the SiC power MOSFETs, further reduction of the channel resistance, high stability under harsh environments, and also, high product yield of large area devices are indispensable. Pn diodes with large chip area have been already reported with high fabrication yield, however, there is few reports in terms of the power MOSFETs. To clarify the difference between the simple pn diodes and power MOSFETs, we have fabricated four pn-type junction TEGs having the different structural features. Those pn junctions are close to the similar structure of DIMOS (Double-implanted MOS) step-by-step from the simple pn diodes. We have surveyed the V-I characteristics dependence on each structural features over the 2inch wafer. Before their fabrication, we formed grid patterns with numbering over the 2inch wafer, then performed the synchrotron x-ray topography observation. This enables the direct comparison the electrical and spectrographic characteristics of each pn junctions with the fingerprints of defects.Four structural features from TypeA to TypeD are as follows. TypeA is the most simple structure as same as the standard pn diodes formed by Al+ ion implantation (I/I), except that the Al+ I/I condition conforms to that of the p-well I/I in the DIMOS. The JTE structure was used for the edge termination on all junctions. While the TypeA consists of one p-type region, TypeB and TypeC consists of a lot of p-wells. The difference of Type B and C is a difference of the oxide between the adjacent p-wells. The oxide of TypeB consists of the thick field oxide, while that of TypeC consists of the thermal oxide corresponding to the gate oxide in the DIMOS. In the TypeD structure, n+ region corresponding to the source in the DIMOS was added by the P+ I/I. The TypeD is the same structure of the DIMOS, except that the gate and source contacts are shorted. The V-I measurements of the pn junctions are performed using the KEITHLEY 237 voltage source meters with semi-auto probe machine. An active area of the fabricated pn junctions TEGs are 150um2 and 1mm2. Concentration and thickness of the drift layer are 1e16cm−3 and 10um, respectively.In order to compare the V-I characteristics of fabricated pn junctions with their defects information that obtained from x-ray topography measurements directly, the grid patterns are formed before the fabrication. The grid patterns were formed over the 2inch wafer by the SiC etching. The synchrotron x-ray topography measurements are carried out at the Beam-Line 15C in Photon-Factory in High-Energy-Accelerator-Research-Organization. Three diffraction conditions, g=11-28, -1-128, and 1-108, are chosen in grazing-incidence geometry (improved Berg-Barrett method).In the presentation, the V-I characteristics mapping on the 2inch wafer for each pn junctions, and the comparison of V-I characteristics with x-ray topography will be reported.


Author(s):  
Timur Sh. KOMBAEV ◽  
Mikhail K. ARTEMOV ◽  
Valentin K. SYSOEV ◽  
Dmitry S. DEZHIN

It is proposed to develop a small spacecraft for an experiment using high-temperature superconductors (HTS) and shape memory materials. The purpose of the experiment is to test a technological capability of creating a strong magnetic field on the small spacecraft using HTS and shape memory materials for deployed large-area structures, and study the magnetic field interaction with the solar wind plasma and the resulting force impact on the small spacecraft. This article is of a polemical character and makes it possible to take a fresh look at the applicability of new technologies in space-system engineering. Key words: high-temperature superconductors, shape memory materials, solar wind, spacecraft.


2011 ◽  
Vol 679-680 ◽  
pp. 777-780 ◽  
Author(s):  
Shoji Ushio ◽  
Ayumu Adachi ◽  
Kazuhiro Matsuda ◽  
Noboru Ohtani ◽  
Tadaaki Kaneko

As a new graphene functionality applicable to post-implantation high temperature annealing of SiC, a method of in situ formation and removal of large area epitaxial few-layer graphene on 4H-SiC(0001) Si-face is proposed. It is demonstrated that the homogeneous graphene layer formed by Si sublimation can be preserved without the decomposition of the underlying SiC substrate even in the excess of 2000 oC in ultrahigh vacuum. It is due to the existence of the stable (6√3×6√3) buffer layer at the interface. To ensure this cap function, the homogeneity of the interface must be guaranteed. In order to do that, precise control of the initial SiC surface flatness is required. Si-vapor etching is a simple and versatile SiC surface pre/post- treatment method, where thermally decomposed SiC surface is compensated by a Si-vapor flux from Si solid source in the same semi-closed TaC container. While this Si-vapor etching allows precise control of SiC etch depth and surface step-terrace structures, it also provides a “decap” function to remove of the graphene layer. The surface properties after the each process were characterized by AFM and Raman spectroscopy.


MRS Bulletin ◽  
1998 ◽  
Vol 23 (9) ◽  
pp. 16-21 ◽  
Author(s):  
Dieter M. Gruen ◽  
Ian Buckley-Golder

Carbon in the form of diamond is the stuff of dreams, and the image of the diamond evokes deep and powerful emotions in humans. Following the successful synthesis of diamond by high-pressure methods in the 1950s, the startling development of the low-pressure synthesis of diamond films in the 1970s and 1980s almost immediately engendered great expectations of utility. The many remarkable properties of diamond due in part to its being the most atomically dense material in the universe (hardness, thermal conductivity, friction coefficient, transparency, etc.) could at last be put to use in a multitude of practical applications. “The holy grail”—it was realized early on—would be the development of large-area, doped, single-crystal diamond wafers for the fabrication of high-temperature, extremely fast integrated circuits leading to a revolution in computer technology.Excitement in the community of chemical-vapor-deposition (CVD) diamond researchers, funding agencies, and industrial companies ran high in expectation of early realization for many of the commercial goals that had been envisioned: tool, optical, and corrosion-resistant coatings; flat-panel displays; thermomanagement for electronic components, etc. Market projection predicting diamond-film sales in the billions of dollars by the year 2000 was commonplace. Hopes were dashed when these optimistic predictions ran up against the enormous scientific and technical problems that had to be overcome in order for those involved to fully exploit the potential of diamond. This experience is not new to the scientific community. One need only remind oneself of the hopes for cheap nuclear power or for high-temperature superconducting wires available at hardware stores to realize that the lag between scientific discoveries and their large-scale applications can be very long. Diamond films are in fact being used today in commercial applications.


Author(s):  
Timur KOMBAEV ◽  
Mikhail ARTEMOV ◽  
Valentin SYSOEV ◽  
Dmitry DEZHIN ◽  

It is proposed to develop a small spacecraft for an experiment using high-temperature superconductors (HTS) and shape memory materials. The purpose of the experiment is to test a technological capability of creating a strong magnetic field on the small spacecraft using HTS and shape memory materials for deployed large-area structures, and study the magnetic field interaction with the solar wind plasma and the resulting force impact on the small spacecraft. This article is of a polemical character and makes it possible to take a fresh look at the applicability of new technologies in space-system engineering.


Author(s):  
K. Elliott Cramer ◽  
William P. Winfree ◽  
Edward R. Generazio ◽  
Ramakrishna Bhatt ◽  
Dennis S. Fox ◽  
...  

Strong, tough, high temperature ceramic matrix composites are currently being developed for application in advanced heat engines. One of the most promising of these new materials is a SiC fiber-reinforced silicon nitride ceramic matrix composite (SiCf/Si3N4). The interfacial shear strength in such composites is dependant on the integrity of the fiber’s carbon coating at the fiber-matrix interface. The integrity of the carbon rich interface can be significantly reduced if the carbon is oxidized. Since the thermal diffusivity of the fiber is greater than that of the matrix material, the removal of carbon increases the contact resistance at the interface reducing the thermal diffusivity of the composite. Therefore thermal diffusivity images can be used to characterize the progression of carbon depletion and degradation of the composite. A new thermal imaging technique has been developed to provide rapid large area measurements of the thermal diffusivity perpendicular to the fiber direction in these composites. Results of diffusivity measurements will be presented for a series of SiCf/Si3N4 (reaction bonded silicon nitride) composite samples heat-treated under various conditions. Additionally, the ability of this technique to characterize damage in both ceramic and other high temperature composites will be shown.


2009 ◽  
Vol 615-617 ◽  
pp. 683-686 ◽  
Author(s):  
Ryouji Kosugi ◽  
T. Sakata ◽  
Y. Sakuma ◽  
K. Suzuki ◽  
Tsutomu Yatsuo ◽  
...  

We have fabricated the four pn-type junction TEGs (Test Element Groups) having different structure. Those TEGs are close to the double-implanted (Di) MOSFETs, step by step from the simple pn diode. Voltage-current (V-I) characteristics of the hundred TEGs having p-well structure show similar blocking characteristics of those of simple pn diodes on the same wafer. This indicates that the p-well structure itself does not cause a significant deterioration on the blocking yield. On the other hand, the yield is significantly influenced by the annealing condition for ion-implanted layer. The oxide-related hard breakdown on the JFET region dominates the blocking yield. The reach-through breakdown of the TEGs having the n+ region within each p-well becomes largely suppressed by the high-temperature and short-time annealing.


1987 ◽  
Vol 97 ◽  
Author(s):  
J. Anthony Powell

ABSTRACTSilicon carbide (SiC), with a favorable combination of semiconducting and refractory properties, has long been a candidate for high temperature semiconductor applications. Research on processes for producing the needed large-area high quality single crystals has proceeded sporadically for many years. Two characteristics of SiC have aggravated the problem of its crystal growth. First, it cannot be melted at any reasonable pressure, and second, it forms many different crystalline structures, called polytypes. Recent progress in the development of two crystal growth processes will be described. These processes are the modified Lely process for the growth of the alpha polytypes (e.g. 6H SiC), and a process for the epitaxial growth of the beta polytype (i.e. 3C or cubic SiC) on single crystal silicon substrates. A discussion of the semiconducting qualities of crystals grown by various techniques will also be included.


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