Microcrystalline calcium hydroxide in Portland cement pastes of low water/cement ratio

1981 ◽  
Vol 11 (5-6) ◽  
pp. 713-718 ◽  
Author(s):  
G.W. Groves
2014 ◽  
Vol 875-877 ◽  
pp. 177-182 ◽  
Author(s):  
Xiang Li ◽  
Hua Quan Yang ◽  
Ming Xia Li

The hydration degree of fly ash and the calcium hydroxide (CH) content were measured. Combined with the equilibrium calculation of cement hydration, a new method for assessment of the hydration degree of cement in the fly ash-cement (FC) pastes based on the CH content was developed. The results reveal that as the fly ash content increase, the hydration degree of fly ash and the CH content decrease gradually; at the same time, the hydration degree of cement increase. The hydration degree of cement in the FC pastes containing a high content of fly ash (more than 35%) at 360 days is as high as 80%, even some of which hydrates nearly completely. The effect of water-cement ratio to the hydration degree of cement in the FC pastes is far less distinct than that of the content of fly ash.


2012 ◽  
Vol 517 ◽  
pp. 338-341
Author(s):  
Ulisses Targino Bezerra ◽  
Normando Perazzo Barbosa

Papers presented at ICPIC 2010, Madeira Island, Portugal, dealing with the use of polymers in cementitious materials, show the need to combine different admixtures to optimize the properties of cement. This work is a continuation of a paper presented at NOCMAT 2010, Cairo-Egypt, about the incorporation of several materials in Portland cement to increase mechanical properties and workability. The best performance admixtures were chosen and they were combined considering the superposition of effects. Cement pastes were prepared with chalcedony and sulfonate (to increase compressive strength) and sugar (to increase workability). Two percent of cement was replaced by the admixtures. The water/cement ratio was constant and equal to 0.44. Results show that the combination of 0.05% of sugar and 1.95% of sulfonate and 0.10% of sugar and 1.90% of chalcedony produced a paste with the greatest compressive strength and good workability. Compression strength was respectively 27.4 MPa and 36.6 MPa, which represent increases of 33.5% and 78.6%, respectively, relative to the reference paste without admixtures. While increasing the paste compression strength with sulfonate has been significant, the results of the paste with chalcedony were the more surprising because the water/cement ratio of pastes was kept constant. The chalcedony is a type of crystalline silica, which shows deformation in their structure. So because of crystalline structure of chalcedony, there should be, probably, no significant reactivity of it with the cement hydrates, just the fact that its structure be deformed can explain this reactivity. The most important conclusion concerns is that the combinations of admixtures can improve a lot the properties of Portland cement paste.


2013 ◽  
Vol 6 (1) ◽  
pp. 50-61
Author(s):  
Amer M. Ibrahem ◽  
Shakir A. Al-Mishhadani ◽  
Zeinab H.Naji

This investigation aimed to study the effect of nano metakaolin ( NMK ) on some properties (compressive strength ,splitting tensile strength & water absorption ) of concrete. The nano metakaolin (NMK) was prepared by thermal activation of kaolin clay for 2 hours at 750 Ċ. The cement used in this investigation consists of ordinary Portland cement (OPC). The OPC was partially substituted by NMK of ( 3, 5 & 10%) by weight of cement. The C45 concrete was prepared , using water/cement ratio ( W/c) of (0.53) .The Water absorption was tested at 28 days while the tests (compressive strength ,splitting tensile strength) were tested at ages of (7, 28, 60,& 90) days . The compressive strength and splitting tensile strength of concrete with NMK were higher than that of reference concrete with the same W/c ratio.The improvement in the compressive strength when using NMK was (42.2, 55.8 , 63.1% ) at age 28 days for ( 3%, 5%, &10% ) replacement of NMK respectively whereas the improvement in the splitting tensile strength was (0% , 36% & 46.8 %) at age of 28 days when using (3%, 5%, &10% ) NMK respectively. The improvement in the water absorption was (16.6%, 21.79%, &25.6 ) when using (3, 5, &10% )NMK.


1984 ◽  
Vol 42 ◽  
Author(s):  
M. Regourd

AbstractHigh strength cement pastes include hot pressed, autoclaved, impregnated low water/cement ratio, macrodefect free, ultrafine particles arrangement systems. The densification of the microstrucure is mainly related to a low porosity and to the formation of poorly crystalline hydrates. In composite systems like mortars and concretes, the interfacial bond between the cement paste and aggregates is moreover less porous and more finely crystallized than the normal “auréole de transition”.


1984 ◽  
Vol 42 ◽  
Author(s):  
N. B. Eden ◽  
J. E. Bailey

AbstractA model has been developed for the flexural strength of Portland cement pastes, based upon observed fracture behaviour of both normal and high strength pastes. Fibrillar or foil-like elements pull apart at a yield stress which is characteristic of the number of elements and interfacial shear strength. The former can be maximised by using a low water/cement ratio and the latter by inclusion of water-soluble polymer, followed by suitable drying. It is proposed that this is the mechanism by which high strength may be attained in Portland cement.


2021 ◽  
Vol 25 (Special) ◽  
pp. 2-78-2-82
Author(s):  
Haider K. Ahmed ◽  
◽  
Mohammed A. Abdulrehman ◽  

Two types of nanomaterial: Tio2 nanoparticles (NPs) and carbon black NPs have used in this research to study their effect on compressive strength, shrinkage and flow table tests Cement mortar. The mixing ratio was 1:2.7:0.485 (cement, sand, water/cement ratio) for compressive strength test and 1:2 (cement, sand) with the water/cement ratio was a variable value for dry shrinkage test. The two nanoparticles’ ratios are (0.25%, 0.75%, 1.25 % and 1.75%) by weight of the Portland cement. The test results show that the highest value of compressive strength was obtained when using Tio2 at 1.25% wt. of cement. But when using carbon black nanoparticles, the greatest value was obtained when adding it with a ratio of 1.75 % wt. of cement. Using two NPs when added to cement mortar has a negative effect on the shrinkage value.


2012 ◽  
Vol 20 (8) ◽  
pp. 725-736 ◽  
Author(s):  
Xiongyi Peng ◽  
Conghua Yi ◽  
Xueqing Qiu ◽  
Yonghong Deng

In order to study the effect of molecular weight of polycarboxylate-type superplasticizer (PC) on the rheological properties of cement pastes, PCs with different molecular weights (low, medium, high) were synthesized, and used as superplasticizers for cement suspensions. The effect of molecular weight of PC on the zeta potential, adsorption, and rheological behaviour of the corresponding cement suspensions were investigated systematically. Among the PCs, PC with a medium molecular weight always produced the lowest apparent viscosity for cement pastes at the same shear rate. Compared to PC with a low molecular weight, PC with a high molecular weight presented a stronger initial dispersing ability and a weaker dispersing stabilizing ability for cement pastes. In addition, PC with a low molecular weight had an advantage over PC with a high molecular weight for reducing the viscosity of paste in the low added dosage or low water/cement ratio, but the latter had the advantage of reducing the viscosity of the paste when the added dosage or water/cement ratio was high. This understanding of the rheological properties of cement pastes incorporating PC will provide an important reference for the application and synthesis of PC with high efficiency.


2020 ◽  
Vol 2020 ◽  
pp. 1-12
Author(s):  
Son Bui Truong ◽  
Nu Nguyen Thi ◽  
Duong Nguyen Thanh

Soft soil is widely distributed in Vietnam, especially in the coastal area. In engineering practice, soft soil cannot be used to build any construction and needs to be improved or treated before building construction. In addition, Vietnam has many pig-iron or thermal power plants, which annually produce a huge amount of granulated blast furnace slag (GBFS). Thus, the use of this material for soft soil improvement needs to be considered. This paper presents experimental results on the unconfined compressive strength (UCS) of three Vietnam’s soft soils treated with Portland cement and Portland cement with ground granulated blast furnace slag (GGBFS). Binder dosage used in this study is 250, 300, and 350 kg/m3 with the three different water/cement ratios of 0.8, 0.9, and 1.0, respectively. The research results showed that the UCS of soil-cement mixtures depends on soil type, water/cement ratio, cement type, and binder content. Accordingly, the unconfined compressive strength increased with the increase of binder contents, the decrease of the natural water content of soft soil, water/cement ratios, and clay content. The highest value of UCS of treated soils was found for the soil at Site II with the Portland cement content, cement GGBFS, and water/cement ratio of 873 kg/m3, 2355 kg/m3, and 0.8, respectively. Besides, for all the three soils and two binder types, the water/cement ratio of 0.8 was found to be suitable to reach the highest UCS values of treated soil. The research results also showed that the UCS of treated soil with cement GGBFS was higher than that of treated soil with Portland cement. This indicated the effectiveness of the use of Portland cement with GGBFS in soft soil improvement. There is great potential for reducing the environmental problems regarding the waste materials from pig-iron plants in Vietnam and the construction cost as well.


1985 ◽  
Vol 65 ◽  
Author(s):  
R. H. Mills

ABSTRACTCombinations of two types of commercially available Fly Ash (FA) and Portland cement (PC) were tested for compressive strength and permeance to gas flow. The cementitious components were combined in the concrete mixture in proportions PC/FA = 100/0, 75/25, 60/40 and 45/55 for a range of water/cement ratio, and equal workability. Strength and maturity efficiency factors were satisfactory for 75/25 and 60/40 blends. Gas tightness was improved at all levels of Fly Ash substitution.


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