Experimental determination of the complex fresnel reflection coefficient of a three-phase system by combination of modulated reflectance spectroscopy and modulated interferometry

1977 ◽  
Vol 66 (1) ◽  
pp. 357-360 ◽  
1995 ◽  
Vol 49 (3) ◽  
pp. 354-360 ◽  
Author(s):  
Stephen V. Pepper

A grazing angle objective on an infrared microspectrometer is studied for quantitative spectroscopy by considering the angular dependence of the incident intensity within the objective's angular aperture. The assumption that there is no angular dependence is tested by comparing the experimental reflectance of Si and KBr surfaces with the reflectance calculated by integrating the Fresnel reflection coefficient over the angular aperture under this assumption. Good agreement was found, indicating that the specular reflectance of surfaces can straightforwardly be quantitatively integrated over the angular aperture without considering nonuniform incident intensity. This quantitative approach is applied to the thickness determination of dipcoated Krytox on gold. The infrared optical constants of both materials are known, allowing the integration to be carried out. The thickness obtained is in fair agreement with the value determined by ellipsometry in the visible. Therefore, this paper illustrates a method for more quantitative use of a grazing angle objective for infrared reflectance microspectroscopy.


Sensors ◽  
2018 ◽  
Vol 18 (11) ◽  
pp. 3727 ◽  
Author(s):  
Giovanna Capparelli ◽  
Gennaro Spolverino ◽  
Roberto Greco

Time domain reflectometry (TDR) is one of the most widely used techniques for indirect determination of soil volumetric water content (θ). TDR measures the relative dielectric constant (εr) which, in a three-phase system like the soil, depends on water, air, and solid matrix dielectric constants. Since dielectric constant of water is much larger than the other two, εr of bulk soil mainly depends on water content. In many cases, the application of TDR requires a specific calibration of the relationship θ(εr) to get quantitatively accurate estimates of soil water content. In fact, the relationship θ(εr) is influenced by various soil properties, such as clay content, organic matter content, bulk density, and aggregation. Numerous studies have shown that pyroclastic soils often exhibit a peculiar dielectric behavior. In Campania (Southern Italy) wide mountainous areas are covered by layered pyroclastic deposits of ashes (loamy sands) and pumices (sandy gravels), often involved in the triggering of landslides induced by rainwater infiltration. Reliable field measurements of water content of such soils are therefore important for the assessment of landslide risk. Hence, in this paper, the θ(εr) relationship has been experimentally determined on samples of typical pyroclastic soil of Campania, collected around Sarno, reconstituted with different porosities. The aim of the study is to identify specific calibration relationships for such soils based not only on empirical approaches. In this respect, a three-phase dielectric mixing model with a variable exponent is introduced, and the variable value of the exponent is related to the different dielectric properties of bond and free water within the soil pores.


2019 ◽  
Vol 55 (2) ◽  
pp. 1-8
Author(s):  
Yusuke Kanto ◽  
Georgi Shilyashki ◽  
Helmut Pfutzner ◽  
Ivo Matkovic

2013 ◽  
Vol 57 (2) ◽  
pp. 81-90 ◽  
Author(s):  
Elbert A. Hogendoorn ◽  
Marinus J. Sommeijer ◽  
Marjo J. Vredenbregt

Abstract A convenient method has been developed for the separation and determination of beeswax in propolis from beehives located in the Netherlands. The method is based on differences in specific density and involves the adding of water and microwave heating of a propolis sample. After cooling to room temperature, the resulting three phase system provides a full separation of the beeswax from the propolis in the upper layer. This layer can easily be collected to quantify the authentic beeswax content of the raw propolis sample. Confirmation of the identity of beeswax isolated from propolis with this procedure, was obtained using Near Infrared Spectroscopy (NIR). Propolis samples from 27 Dutch apiaries from various locations were analyzed using this method. The beeswax content varied between 1.0 and 42.5% with an average of 11.1%. This method may also serve for the de-waxing of raw propolis prior to the isolation of biologically active compounds to be used in medicinal products.


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