Thermosetting polyimide resin matrix composites with interpenetrating polymer networks for precision foil resistor chips based on special mechanical performance requirements

2014 ◽  
Vol 299 ◽  
pp. 73-80 ◽  
Author(s):  
X.Y. Wang ◽  
J.X. Ma ◽  
C.G. Li ◽  
H.X. Wang
Polymers ◽  
2018 ◽  
Vol 10 (10) ◽  
pp. 1128 ◽  
Author(s):  
Dengxun Ren ◽  
Lin Chen ◽  
Yue Yuan ◽  
Kui Li ◽  
Mingzhen Xu ◽  
...  

The interfacial properties between fibers and resin matrices show great influence on the properties of fiber-reinforced composites. In this work, phthalonitrile containing benzoxazine (BA-ph) was chosen as the resin matrix, which combined with the glass fiber (GF) to prepare reinforced composite laminates at low temperature (200 °C). The poly(arylene ether nitrile) (PEN) was used to modify the GF and BA-ph matrix. Curing behaviors of the BA-ph/PEN were investigated with Differential scanning calorimetric (DSC) and Dynamic rheological analysis (DRA), and results indicated that the polymerization would be hindered by PEN due to the dilution effects. Moreover, the formation of triazine rings which assigning to the ring-forming polymerization of nitrile groups in BA-ph and PEN could improve the compatibility of BA-ph and PEN in the matrix. The SEM images of the fracture surface of the composites revealed that the brittleness of BA-ph matrix and interfacial adhesion between GFs and matrix was improved. The enhanced interfacial adhesion was detailedly discussed from the perspective of physical entanglement and the copolymerization between PEN chains on the surface of GFs and BA-ph/PEN matrix. The results of DMA also explained the toughness of BA-ph/PEN matrix, the semi-interpenetrating polymer networks and the interfacial adhesion. In sum, a feasible strategy that modifies the surface of GFs and the brittleness of the thermosetting matrix by high-performance thermoplastic polymers, which can be employed to prepare the composite laminates with improved properties.


2020 ◽  
Vol 2020 ◽  
pp. 1-15
Author(s):  
Kuan-Liang Liu ◽  
Pei-Yu Kuo ◽  
Jin-Lin Han ◽  
Kuo-Huang Hsieh

To achieve a sustainable bioeconomy, various bioderived additives have been developed to produce biocomposites, but only a handful of research on biocomposites focuses on the effect of bioderived additives on interpenetrating polymer networks (IPNs). This study is aimed at understanding the interaction between bioadditives and interpenetrating polymer networks and is the first study to build the relationship between bioadditive ratio and damping factor based on dynamic mechanical analysis. The IPNs were prepolymerized in bulk by isocyanate and poly(oxypropylene) polyol (PPG) with two different molecular weights (PPG 700 and PPG 1000), and then, they were grafted with bisphenol A diglycidyl ether epoxy. The bioadditives were prepared from agricultural waste, sugarcane bagasse, and the effect of the coupling agent 3-glycidoxypropyltrimethoxysilane on a bioadditive surface was also discussed in this study. The results show that modified bioadditives have significant enhancement on tensile strength and tensile modulus of polyurethane-grafted epoxy resin interpenetrating polymer networks (PU(PPG)-EP graft-IPNs). However, the enhancement is not from a strong covalent bond between matrix and additives, that is, due to the well-dispersed bioadditives which provide stiff segments. The static and dynamic mechanical performance, water absorption ratio, and morphology of the (PU(PPG)-EP graft-IPNs) elastomers were also thoroughly discussed in this study.


2021 ◽  
Vol 41 (3) ◽  
pp. 1810-1816
Author(s):  
Zhenyue Zou ◽  
Yan Qin ◽  
Huadong Fu ◽  
Di Zhu ◽  
Zhuangzhuang Li ◽  
...  

Polymer ◽  
2021 ◽  
Vol 224 ◽  
pp. 123671
Author(s):  
Gregory N. Smith ◽  
Erik Brok ◽  
Martin Schmiele ◽  
Kell Mortensen ◽  
Wim G. Bouwman ◽  
...  

2021 ◽  
Vol 11 (9) ◽  
pp. 4028
Author(s):  
Asghar Gholizadeh Vayghan ◽  
Liesbeth Horckmans ◽  
Ruben Snellings ◽  
Arne Peys ◽  
Priscilla Teck ◽  
...  

This research investigated the possibility of using metallurgical slags from the copper and lead industries as partial replacement for cement. The studied slags were fayalitic, having a mainly ferro-silicate composition with minor contents of Al2O3 and CaO. The slags were treated at 1200–1300 °C (to reduce the heavy metal content) and then granulated in water to promote the formation of reactive phases. A full hydration study was carried out to assess the kinetics of reactions, the phases formed during hydration, the reactivity of the slags and their strength activity as supplementary cementitious material (SCM). The batch-leaching behaviour of cementitious mixtures incorporating treated slags was also investigated. The results showed that all three slags have satisfactory leaching behaviour and similar performance in terms of reactivity and contribution to the strength development. All slags were found to have mediocre reactivity and contribution to strength, especially at early ages. Nonetheless, they passed the minimum mechanical performance requirements and were found to qualify for use in cement.


2021 ◽  
Author(s):  
Hang Mei ◽  
Huajing Liu ◽  
Qianqian Shang ◽  
Ying Dong ◽  
Stig Pedersen-Bjergaard ◽  
...  

A versatile organic-solvent-free electromembrane extraction (EME) system, which could be successfully used for the extraction of both basic and acidic analytes, is proposed based on semi-interpenetrating polymer networks.


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