Cement composites prepared with nanoparticles have been widely studied in order to achieve superior performance structures. The incorporation of carbon nanotubes (CNTs) is an excellent alternative due to their mechanical, electrical, and thermal properties. However, effective dispersion is essential to ensure strength gains. In the present work, cement pastes were prepared incorporating CNTs in proportions up to 0.10% by weight of cement, dispersed on the surface of anhydrous cement particles in isopropanol suspension and using ultrasonic agitation. Digital image correlation was employed to obtain basic mechanical parameters of three-point bending tests. The results indicated a 34% gain in compressive strength and 12% in flexural tensile strength gains, respectively, as well as a 70% gain in fracture energy and 14% in fracture toughness in the presence of 0.05% CNTs were recorded. These results suggest that CNTs act as crack propagation controllers. Moreover, CNT presence contributes to pore volume reduction, increases the density of cement pastes, and suggests that CNTs additionally act as nucleation sites of the cement hydration products. Scanning electron microscopy images indicate effective dispersion as a result of the methodology adopted, plus strong bonding between CNTs and the cement hydration product. Therefore, CNTs can be used to obtain more resistant and durable cement-based composites.
Impact of π-π Interaction Mode and Vinylene Bond Geometry on Helical Wrapping of Carbon Nanotubes
