Upgrading of zirconia membrane performance in removal of hazardous VOCs from water by surface functionalization

2019 ◽  
Vol 374 ◽  
pp. 155-169 ◽  
Author(s):  
Joanna Kujawa ◽  
Wojciech Kujawski ◽  
Aleksandra Cyganiuk ◽  
Ludovic F. Dumée ◽  
Samer Al-Gharabli
2020 ◽  
Author(s):  
Mikhail Trought ◽  
Isobel Wentworth ◽  
Timothy Leftwich ◽  
Kathryn Perrine

The knowledge of chemical functionalization for area selective deposition (ASD) is crucial for designing the next generation heterogeneous catalysis. Surface functionalization by oxidation was studied on the surface of highly oriented pyrolytic graphite (HOPG). The HOPG surface was exposed to with various concentrations of two different acids (HCl and HNO3). We show that exposure of the HOPG surface to the acid solutions produce primarily the same -OH functional group and also significant differences the surface topography. Mechanisms are suggested to explain these strikingly different surface morphologies after surface oxidation. This knowledge can be used to for ASD synthesis methods for future graphene-based technologies.


2020 ◽  
Author(s):  
Muayad Al-shaeli ◽  
Stefan J. D. Smith ◽  
Shanxue Jiang ◽  
Huanting Wang ◽  
Kaisong Zhang ◽  
...  

<p>In this study, novel <a>mixed matrix polyethersulfone (PES) membranes</a> were synthesized by using two different kinds of metal organic frameworks (MOFs), namely UiO-66 and UiO-66-NH<sub>2</sub>. The composite membranes were characterised by SEM, EDX, FTIR, PXRD, water contact angle, porosity, pore size, etc. Membrane performance was investigated by water permeation flux, flux recovery ratio, fouling resistance and anti-fouling performance. The stability test was also conducted for the prepared mixed matrix membranes. A higher reduction in the water contact angle was observed after adding both MOFs to the PES and sulfonated PES membranes compared to pristine PES membranes. An enhancement in membrane performance was observed by embedding the MOF into PES membrane matrix, which may be attributed to the super-hydrophilic porous structure of UiO-66-NH<sub>2</sub> nanoparticles and hydrophilic structure of UiO-66 nanoparticles that could accelerate the exchange rate between solvent and non-solvent during the phase inversion process. By adding the MOFs into PES matrix, the flux recovery ratio was increased greatly (more than 99% for most mixed matrix membranes). The mixed matrix membranes showed higher resistance to protein adsorption compared to pristine PES membranes. After immersing the membranes in water for 3 months, 6 months and 12 months, both MOFs were stable and retained their structure. This study indicates that UiO-66 and UiO-66-NH<sub>2</sub> are great candidates for designing long-term stable mixed matrix membranes with higher anti-fouling performance.</p>


2012 ◽  
Vol 8 (2) ◽  
pp. 202-207 ◽  
Author(s):  
Sonia Bailon-Ruiz ◽  
Luis Alamo-Nole ◽  
Oscar Perales-Perez

2020 ◽  
Vol 8 (36) ◽  
pp. 12380-12411
Author(s):  
Pan Jiang ◽  
Zhongying Ji ◽  
Xiaolong Wang ◽  
Feng Zhou

Various requirements for 3D printing raised by actual applications in different fields have provoked the rapid development of technologies together with various specific materials.


Polymers ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 1026
Author(s):  
Elisa Chiodi ◽  
Allison M. Marn ◽  
Matthew T. Geib ◽  
M. Selim Ünlü

The importance of microarrays in diagnostics and medicine has drastically increased in the last few years. Nevertheless, the efficiency of a microarray-based assay intrinsically depends on the density and functionality of the biorecognition elements immobilized onto each sensor spot. Recently, researchers have put effort into developing new functionalization strategies and technologies which provide efficient immobilization and stability of any sort of molecule. Here, we present an overview of the most widely used methods of surface functionalization of microarray substrates, as well as the most recent advances in the field, and compare their performance in terms of optimal immobilization of the bioreceptor molecules. We focus on label-free microarrays and, in particular, we aim to describe the impact of surface chemistry on two types of microarray-based sensors: microarrays for single particle imaging and for label-free measurements of binding kinetics. Both protein and DNA microarrays are taken into consideration, and the effect of different polymeric coatings on the molecules’ functionalities is critically analyzed.


RSC Advances ◽  
2021 ◽  
Vol 11 (15) ◽  
pp. 8552-8558
Author(s):  
Tuan V. Vu ◽  
A. I. Kartamyshev ◽  
Nguyen V. Hieu ◽  
Tran D. H. Dang ◽  
Sy-Ngoc Nguyen ◽  
...  

Surface functionalization is one of the useful techniques for modulating the mechanical and electronic properties of two-dimensional systems.


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