Novel calixarene-based porous organic polymers with superfast removal rate and ultrahigh adsorption capacity for selective separation of cationic dyes

2022 ◽  
pp. 134442
Author(s):  
Shiyuan Zhou ◽  
Liujun Jin ◽  
Peiyang Gu ◽  
Lechen Tian ◽  
Najun Li ◽  
...  
2018 ◽  
Vol 54 (61) ◽  
pp. 8450-8453 ◽  
Author(s):  
Shaohui Xiong ◽  
Jian Tao ◽  
Yuanyuan Wang ◽  
Juntao Tang ◽  
Cheng Liu ◽  
...  

The iodine adsorption capacity of porous organic polymers is greatly enhanced due to the extended π-conjugated units on the backbone.


2019 ◽  
Vol 7 (1) ◽  
pp. 393-404 ◽  
Author(s):  
Gang Xiong ◽  
Bin-Bin Wang ◽  
Li-Xin You ◽  
Bao-Yi Ren ◽  
Yong-Ke He ◽  
...  

Two silicon-based anionic porous organic polymers with solid microsphere or hollow nanotube morphologies exhibited unprecedented capacity for selective adsorption of cationic dyes.


Nanoscale ◽  
2021 ◽  
Author(s):  
Devin S. Rollins ◽  
Charles P. Easterling ◽  
Andrea N. Zeppuhar ◽  
Jacob A. Krawchuck ◽  
Timothy A. Dreier ◽  
...  

A templated synthetic approach to porous organic polymers, in which branched, rigid monomers are pre-assembled around a target ion before polymerization, can significantly enhance the ion adsorption capacity of the resulting polymer.


Materials ◽  
2019 ◽  
Vol 12 (20) ◽  
pp. 3296 ◽  
Author(s):  
Xiang Gao ◽  
Jiao Liu ◽  
Zhaopeng Liu ◽  
Yuehua Deng ◽  
Wenjie Nie ◽  
...  

The efficient and green removal of residual antibiotics in the environment is an attractive topic. In this work, four different phenyl porous organic polymers (P-POPs) photocatalysts were successfully synthesized, and a series of techniques, such as Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), nitrogen adsorption and desorption experimentation, and solid ultraviolet visible spectroscopy (UV-vis) were conducted to characterize the obtained P-POPs. Moreover, the photocatalytic property of P-POPs in the removal of tetracycline was studied, and the reaction conditions were optimized. Further study indicated that the P-POPs were also efficient for removing other antibiotics, such as chloramphenicol, in a high removal rate of 77%. Furthermore, the separation of the photocatalysts from the solution was easy, and the photocatalysts could be reused at least four times without a considerable loss in catalytic activity.


2018 ◽  
Vol 6 (14) ◽  
pp. 5608-5612 ◽  
Author(s):  
Jin-Xiu Zhou ◽  
Xian-Sheng Luo ◽  
Xiangxiang Liu ◽  
Yan Qiao ◽  
Pengfei Wang ◽  
...  

Time-efficient synthetic methods of porous organic polymers are searched in order to extend the applications of these materials.


Polymers ◽  
2022 ◽  
Vol 14 (1) ◽  
pp. 203
Author(s):  
Wenjie Nie ◽  
Jiao Liu ◽  
Xue Bai ◽  
Zefeng Xing ◽  
Ying Gao

Adsorption is an effective method to remove tetracycline (TC) from water, and developing efficient and environment-friendly adsorbents is an interesting topic. Herein, a series of novel phenyl porous organic polymers (P-POPs), synthesized by one-pot polymerization of different ratios of biphenyl and triphenylbenzene under AlCl3 catalysis in CH2Cl2, was studied as a highly efficient adsorbent to removal of TC in water. Notably, the obtained POPs possessed abundant phenyl-containing functional groups, large specific surface area (1098 m2/g) with abundant microporous structure, high pore volume (0.579 cm3/g), favoring the removal of TC molecules. The maximum adsorption capacity (fitted by the Sips model) could achieve 581 mg/g, and the adsorption equilibrium is completed quickly within 1 h while obtaining excellent removal efficiency (98%). The TC adsorption process obeyed pseudo-second-order kinetics and fitted the Sips adsorption model well. Moreover, the adsorption of POPs to TC exhibited a wide range of pH (2–10) adaptability and outstanding reusability, which could be reused at least 5 times without significant changes in structure and efficiency. These results lay a theoretical foundation for the application of porous organic polymer adsorbents in antibiotic wastewater treatment.


2018 ◽  
Vol 9 (33) ◽  
pp. 6871-6877 ◽  
Author(s):  
Dong Won Kang ◽  
Minjung Kang ◽  
Minkyu Moon ◽  
Hyojin Kim ◽  
Sunhwi Eom ◽  
...  

Double postsynthetic acidifications of a hypercrosslinked polymer afforded record high NH3 adsorption capacity per surface area. Its PDMS coating provided an 40-fold enhancement of low-pressure NH3 adsorption capacity and hydrophobicity.


2021 ◽  
Vol 13 (15) ◽  
pp. 8552
Author(s):  
Vahid Alimohammadi ◽  
Mehdi Maghfouri ◽  
Delaram Nourmohammadi ◽  
Pejman Azarsa ◽  
Rishi Gupta ◽  
...  

Clean water is a vital need for all living creatures during their lifespan. However, contaminated stormwater is a major issue around the globe. A wide range of contaminants, including heavy metals, organic and inorganic impurities, has been discovered in stormwater. Some commonly utilized methods, such as biological, physical and chemical procedures, have been considered to overcome these issues. However, these current approaches result in moderate to low contaminant removal efficiencies for certain classes of contaminants. Of late, filtration and adsorption processes have become more featured in permeable concretes (PCs) for the treatment of stormwater. As nanoparticles have vast potential and unique characterizations, such as a higher surface area to cure polluted stormwater, employing them to improve permeable concretes’ capabilities in stormwater treatment systems is an effective way to increase filtration and adsorption mechanisms. The present study reviews the removal rate of different stormwater contaminants such as heavy metals, organic and other pollutants using nanoparticle-improved PC. The application of different kinds of nanomaterials in PC as porous media to investigate their influences on the properties of PC, including the permeability rate, compressive strength, adsorption capacity and mix design of such concrete, was also studied. The findings of this review show that different types of nanomaterials improve the removal efficiency, compressive strength and adsorption capacity and decrease the infiltration rate of PC during the stormwater treatment process. With regard to the lack of comprehensive investigation concerning the use of nanomaterials in PC to treat polluted stormwater runoff, this study reviews 242 published articles on the removal rate of different stormwater contaminants by using PC improved with nanoparticles.


Author(s):  
Pramod Kumar ◽  
Animesh Das ◽  
Biplab Maji

The phosphorous-containing porous organic polymer is a trending material for the synthesis of heterogeneous catalysts. Decades of investigations have established phosphines as versatile ligands in homogeneous catalysis. Recently, phosphine-based heterogeneous...


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