scholarly journals Synthesis of Novel Phenyl Porous Organic Polymers and Their Excellent Visible Light Photocatalytic Performance on Antibiotics

Materials ◽  
2019 ◽  
Vol 12 (20) ◽  
pp. 3296 ◽  
Author(s):  
Xiang Gao ◽  
Jiao Liu ◽  
Zhaopeng Liu ◽  
Yuehua Deng ◽  
Wenjie Nie ◽  
...  
Keyword(s):  
Photocatalytic Performance ◽  
Removal Rate ◽  
Photocatalytic Property ◽  
Nitrogen Adsorption ◽  
Organic Polymers ◽  
Reaction Conditions ◽  
Porous Organic Polymers ◽  
Ft Ir ◽  
High Removal Rate ◽  
Considerable Loss

The efficient and green removal of residual antibiotics in the environment is an attractive topic. In this work, four different phenyl porous organic polymers (P-POPs) photocatalysts were successfully synthesized, and a series of techniques, such as Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), nitrogen adsorption and desorption experimentation, and solid ultraviolet visible spectroscopy (UV-vis) were conducted to characterize the obtained P-POPs. Moreover, the photocatalytic property of P-POPs in the removal of tetracycline was studied, and the reaction conditions were optimized. Further study indicated that the P-POPs were also efficient for removing other antibiotics, such as chloramphenicol, in a high removal rate of 77%. Furthermore, the separation of the photocatalysts from the solution was easy, and the photocatalysts could be reused at least four times without a considerable loss in catalytic activity.

Preparation of Calcium Sulfate Anhydrate Whisker and a Primary Investigation of its Arsenic Removal Performance

2013 ◽  
Vol 690-693 ◽  
pp. 1013-1019
Author(s):  
Xiao Juan Chen ◽  
Liu Chun Yang ◽  
Jun Feng Zhang ◽  
Yan Huang
Keyword(s):  
Calcium Sulfate ◽  
Arsenic Removal ◽  
Removal Rate ◽  
Optical Microscope ◽  
Alkaline Condition ◽  
Crystal Water ◽  
Arsenic Uptake ◽  
Ft Ir ◽  
High Removal Rate ◽  
Calcium Sulfate Whisker

Calcium sulfate whisker (CSW) was prepared through the method of cooling recrystallization. In an attempt to develop its new application in environmental protection, we investigated the effect of calcination on the material properties and arsenic uptake performance of calcium sulfate whisker anhydrate (CSAW), which was obtained from CSW calcined at 600 °C for 2 h. Moreover, XRD, SEM, optical microscope, and FT-IR were used to characterize CSW samples. It was found that calcination played an important role in the whisker structure through changing the content of crystal water and the morphology. The CSAW material exhibited a high removal rate of As3+/As5+under strongly alkaline condition.

A Study on the Preparation and Flocculation Properties of Boracic Poly-Aluminum-Ferric-Silicate

2013 ◽  
Vol 726-731 ◽  
pp. 3025-3029 ◽  
Author(s):  
Xiao Wei Tian ◽  
Chun Ying Han ◽  
Li Dan Zhang ◽  
Wei Zhao Du ◽  
Zeng He Li
Keyword(s):  
Removal Rate ◽  
Water Solution ◽  
Molar Ratio ◽  
Sodium Borate ◽  
Rapid Coagulation ◽  
Ft Ir ◽  
High Removal Rate ◽  
Micro Morphology ◽  
Polymerization Method ◽  
Electronic Microscope

The boracic poly-aluminum-ferric-silicate (B-PSAF) coagulant was prepared by water solution co-polymerization method, which was synthesized from sodium silicate, aluminum sulfate, ferric chloride and sodium borate. In addition, the best molar ratio of boron and silicon was determined by single factor process. The micro-morphology and structure of B-PSAF were studied by scanning electronic microscope (SEM) and Fourier transform infrared spectrum (FT-IR). It has been studied the operation of B-PSAF as the flocculating agent, the dosage and its effects on the flocculability. Experiments show that B-PSAF is a good effective flocculant, which can be used to treat alkaline dyeing wastewater and it has the features of less consumption, rapid coagulation and high removal rate of CODCr.

scholarly journals Silver Coordination-Polymer based of 4,6-Diamino-2-pyrimidinethiol as Organic Ligand: a Highly Reusable Heterogeneous Nanocatalyst for the Asymmetric Hantzsch Synthesis of Polyhydroquinolines under Green Conditions

2021 ◽  
Author(s):  
Noorullah Hussain-Khil ◽  
Arash Ghorbani-Choghamarani ◽  
Masoud Mohammadi
Keyword(s):  
Catalytic Activity ◽  
Coordination Polymer ◽  
Organic Ligand ◽  
Reaction Times ◽  
Nitrogen Adsorption ◽  
Significant Loss ◽  
Hantzsch Synthesis ◽  
Reaction Conditions ◽  
Ft Ir ◽  
Adsorption Desorption

Abstract A highly efficient and stable heterogeneous coordination polymer (CP) was successfully prepared by hydrothermal combination of silver and 4,6-diamino-2-pyrimidinethiol. The prepared coordination polymer was characterized by FT-IR, XRD, TGA, SEM, EDX, X-ray mapping and Nitrogen adsorption-desorption analysis. The prepared Ag-CP exhibit excellent catalytic activity in multicomponent Hantzsch synthesis of polyhydroquinolines under mild reaction conditions in relatively short reaction times. The heterogeneity of the catalyst was confirmed by the hot filtration test; also, the catalyst was reused for at least four times under the optimized reaction conditions without any significant loss of its catalytic activity.

scholarly journals Characterization of Tio2 And An As-Prepared Tio2/Sio2 Composite And Their Photocatalytic Performance For The Reduction Of Low-Concentration N-NO3- In Water

2021 ◽  
Author(s):  
Wanzhen Zhong ◽  
Weizhang Fu ◽  
Shujuan Sun ◽  
Lingsheng Wang ◽  
Huaihao Liu ◽  
...  
Keyword(s):  
Photoelectron Spectroscopy ◽  
Photocatalytic Performance ◽  
Uv Light ◽  
Removal Rate ◽  
Sol Gel ◽  
X Ray Diffraction ◽  
X Ray ◽  
Load Rate ◽  
Hole Scavenger ◽  
Ft Ir

Abstract Excessive N-NO3- water pollution has become a widespread and serious problem that threatens human and ecosystem health. Here, a TiO2/SiO2 composite photocatalyst was prepared via the sol-gel/hydrothermal method. TiO2 and TiO2/SiO2 were characterized by X-ray diffraction (XRD), UV-Vis differential reflectance spectroscopy (DRS), Fourier infrared (FT-IR) spectroscopy, X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), and energy-dispersive X-ray spectroscopy (EDS). Afterward, the photocatalytic performance of TiO2 and TiO2/SiO2 to reduce low nitrate concentrations (30 mgN·L-1) under UV light were evaluated and the effects of different factors on this process were investigated, after which the reaction conditions were optimized. Removal rates of up to 99.93% were achieved at a hole scavenger (formic acid) concentration of 0.6 mL·L-1, a CO2 flow rate of 0.1 m3·h-1, and a TiO2 concentration of 0.9 g·L-1. In contrast, TiO2/SiO2 at a 1.4 g·L-1 concentration and a TiO2 load rate of 40% achieved a removal rate of 83.48%,But with more than 98% of nitrogen generation rate.NO2- and NH4+ were the minor products, whereas N2 was the main product.

scholarly journals A new silver coordination polymer based on 4,6-diamino-2-pyrimidinethiol: synthesis, characterization and catalytic application in asymmetric Hantzsch synthesis of polyhydroquinolines

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Noorullah Hussain-Khil ◽  
Arash Ghorbani-Choghamarani ◽  
Masoud Mohammadi
Keyword(s):  
Catalytic Activity ◽  
Coordination Polymer ◽  
Reaction Times ◽  
Nitrogen Adsorption ◽  
Significant Loss ◽  
Hantzsch Synthesis ◽  
Reaction Conditions ◽  
Catalytic Application ◽  
Ft Ir ◽  
Adsorption Desorption

AbstractA highly efficient and stable heterogeneous coordination polymer (CP) was successfully prepared by hydrothermal combination of silver and 4,6-diamino-2-pyrimidinethiol. The prepared coordination polymer was characterized by FT-IR, XRD, TGA, SEM, EDX, X-ray mapping and Nitrogen adsorption–desorption analysis. The prepared Ag–CP exhibit excellent catalytic activity in multicomponent Hantzsch synthesis of polyhydroquinolines under mild reaction conditions in relatively short reaction times. The heterogeneity of the catalyst was confirmed by the hot filtration test; also, the catalyst was reused for at least four times under the optimized reaction conditions without any significant loss of its catalytic activity.

Immobilization of Pd (II)-containing N-heterocyclic carbene ligand on porous organic polymers: efficient and recyclable catalysts for Suzuki-Miyaura reactions

2021 ◽  
Author(s):  
Hongwei Lin ◽  
Gao Xiyue ◽  
Yao Huan ◽  
Qionglin Luo ◽  
Cijie Liu ◽  
...  
Keyword(s):  
Coupling Reaction ◽  
Organic Polymer ◽  
High Yield ◽  
Organic Polymers ◽  
Reaction Conditions ◽  
Porous Organic Polymers ◽  
Simple Reaction ◽  
Porous Organic Polymer ◽  
Recyclable Catalysts ◽  
Immobilization Method

Palladium coordinated with N-heterocyclic carbene-functionalized porous organic polymer (Pd@POPs) was successfully prepared via Scholl coupling reaction and successive immobilization method. The protocol features simple reaction conditions, easy separation, high yield...

Solid State Analysis and Theoretical Explorations on Polymorphic and Hydrate Forms of p-Hydroxybenzaldehyde Isonicotinichydrazone: Effect of Additives on Polymorphic Crystallization

2018 ◽  
Author(s):  
Lincy Tom ◽  
Victoria A. Smolenski ◽  
Jerry P. Jasinski ◽  
M.R. Prathapachandra Kurup
Keyword(s):  
Hirshfeld Surface ◽  
Framework Analysis ◽  
Reaction Conditions ◽  
Space Groups ◽  
Effect Of Additives ◽  
Ft Ir ◽  
Packing Arrangement ◽  
The Stability ◽  
Ir And Raman ◽  
Isonicotinic Hydrazide

The reaction of p-hydroxybenzaldehyde with an equimolar amount of isonicotinic hydrazide afforded two polymorphic and hydrate forms of p-hydroxybenzaldehyde isonicotinichydrazone (HBIH) by varying the experimental reaction conditions. The compounds are fully characterized by means of single crystal and powder diffraction methods, vibrational spectroscopy (FT-IR and Raman), thermal and elemental analysis. The compound crystallizes in three different forms in two different space groups, P21/c (form PA and PB) and Pbca (PC). The Hirshfeld surface analysis shows the differences in the relative contributions of intermolecular interactions to the total Hirshfeld surface area for the HBIH molecules. The calculated pairwise interaction energies (104-116 kJ/mol) can be related to the stability of the crystals. Energy framework analysis identifies the interaction hierarchy and their topology. The geometry and conformation of the three forms are essentially similar which differ only by packing arrangement.

Solid State Analysis and Theoretical Explorations on Polymorphic and Hydrate Forms of p-Hydroxybenzaldehyde Isonicotinichydrazone: Effect of Additives on Polymorphic Crystallization

2018 ◽  
Author(s):  
Lincy Tom ◽  
Victoria A. Smolenski ◽  
Jerry P. Jasinski ◽  
M.R. Prathapachandra Kurup
Keyword(s):  
Hirshfeld Surface ◽  
Framework Analysis ◽  
Reaction Conditions ◽  
Space Groups ◽  
Effect Of Additives ◽  
Ft Ir ◽  
Packing Arrangement ◽  
The Stability ◽  
Ir And Raman ◽  
Isonicotinic Hydrazide

The reaction of p-hydroxybenzaldehyde with an equimolar amount of isonicotinic hydrazide afforded two polymorphic and hydrate forms of p-hydroxybenzaldehyde isonicotinichydrazone (HBIH) by varying the experimental reaction conditions. The compounds are fully characterized by means of single crystal and powder diffraction methods, vibrational spectroscopy (FT-IR and Raman), thermal and elemental analysis. The compound crystallizes in three different forms in two different space groups, P21/c (form PA and PB) and Pbca (PC). The Hirshfeld surface analysis shows the differences in the relative contributions of intermolecular interactions to the total Hirshfeld surface area for the HBIH molecules. The calculated pairwise interaction energies (104-116 kJ/mol) can be related to the stability of the crystals. Energy framework analysis identifies the interaction hierarchy and their topology. The geometry and conformation of the three forms are essentially similar which differ only by packing arrangement.

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