Enhanced cryogenic interfacial normal bond property between carbon fibers and epoxy matrix by carbon nanotubes

2014 ◽  
Vol 104 ◽  
pp. 59-65 ◽  
Author(s):  
Qing-Ping Feng ◽  
Yin-Hu Deng ◽  
Hong-Mei Xiao ◽  
Yu Liu ◽  
Cheng-Bing Qu ◽  
...  

2018 ◽  
Vol 18 (7) ◽  
pp. 4940-4952 ◽  
Author(s):  
Luo Zhanjun ◽  
Chen Hui ◽  
Wu Jing ◽  
Xia Xiaohong ◽  
Liu Hongbo ◽  
...  


2019 ◽  
Vol 41 (4) ◽  
pp. 655-655
Author(s):  
Muhammad Abdul Basit Muhammad Abdul Basit ◽  
Sybt e anwar Qais Sybt e anwar Qais ◽  
Muhammad Saffee Ullah Malik and Ghufran Ur Rehman Muhammad Saffee Ullah Malik and Ghufran Ur Rehman ◽  
Faizan Siddique Awan Faizan Siddique Awan ◽  
Laraib Alam Khan and Tayyab Subhani Laraib Alam Khan and Tayyab Subhani

Carbon fiber reinforced polymeric matrix composites are enormously used in aerospace and automotive industries due to their enhanced specific properties. However, the area of interlaminar shear properties still needs investigation so as to produce composites with improved through-the-thickness properties. To improve interlaminar shear properties of these composites, acid-functionalized multiwalled carbon nanotubes were deposited on de-sized carbon fibers through electrophoretic deposition. De-sizing of carbon fabric was performed through three different methods: furnace heating, acidic treatment and chloroform usage. As the acid-treatment provided better results than other two techniques, the acid-de-sized carbon fibers were coated with nanotubes and subsequently incorporated in epoxy matrix to prepare a novel class of multiscale composites using vacuum assisted resin transfer molding technique. Nearly 30% rise in the interlaminar shear strength of the composites was obtained which was credited to the coating of nanotubes on the surface of carbon fibers. The increased adhesion between carbon fibers and epoxy matrix due to mechanical interlocking of nanotubes was found to be the possible reason of improved interlaminar shear properties.



2019 ◽  
Vol 38 (11) ◽  
pp. 506-520 ◽  
Author(s):  
Jacob O’Donnell ◽  
Vijaya Chalivendra ◽  
Asha Hall ◽  
Mulugeta Haile ◽  
Latha Nataraj ◽  
...  

An experimental study is performed to investigate the electro-mechanical response of three-dimensionally conductive multi-functional glass fiber/epoxy laminated composites under quasi-static tensile loading. To generate a three-dimensional conductive network within the composites, multi-wall carbon nanotubes are embedded within the epoxy matrix and carbon fibers are reinforced between the glass fiber laminates using an electro-flocking technique. A combination of shear mixing and ultrasonication is employed to disperse carbon nanotubes inside the epoxy matrix. A vacuum infusion process is used to fabricate the laminated composites of two different carbon fiber lengths (150 µm and 350 µm) and four different carbon fiber densities (500, 1000, 1500, 2000 fibers/mm2). A four circumferential probe technique is employed to measure the in-situ electrical resistance of composites under tensile load. Although composites of both carbon fiber lengths showed significant decrease of sheet resistance under no mechanical load conditions, composites of 350 µm long carbon fibers showed the lowest resistivity of 10 Ω/sq. Unlike the resistance values, composites of 350 µm carbon fibers showed a significant decrease in Young’s modulus compared to 150 µm counterparts. For the electro-mechanical response, composites containing carbon fibers of 150 µm long demonstrated a maximum value of percentage change in resistance. These results were then compared to both 350 µm and no added carbon fibers under quasi-static tensile loading.





2011 ◽  
Vol 13 (2) ◽  
pp. 62-69 ◽  
Author(s):  
Maria Wladyka-Przybylak ◽  
Dorota Wesolek ◽  
Weronika Gieparda ◽  
Anna Boczkowska ◽  
Ewelina Ciecierska

The effect of the surface modification of carbon nanotubes on their dispersion in the epoxy matrix Functionalization of multi-walled carbon nanotubes (MWCNTs) has an effect on the dispersion of MWCNT in the epoxy matrix. Samples based on two kinds of epoxy resin and different weight percentage of MWCNTs (functionalized and non-functionalized) were prepared. Epoxy/carbon nanotubes composites were prepared by different mixing methods (ultrasounds and a combination of ultrasounds and mechanical mixing). CNTs modified with different functional groups were investigated. Surfactants were used to lower the surface tension of the liquid, which enabled easier spreading and reducing the interfacial tension. Solvents were also used to reduce the liquid viscosity. Some of them facilitate homogeneous dispersion of nanotubes in the resin. The properties of epoxy/nanotubes composites strongly depend on a uniform distribution of carbon nanotubes in the epoxy matrix. The type of epoxy resin, solvent, surfactant and mixing method for homogeneous dispersion of CNTs in the epoxy matrix was evaluated. The effect of CNTs functionalization type on their dispersion in the epoxy resins was evaluated on the basis of viscosity and microstructure studies.



Author(s):  
Gasan M. Magomedov ◽  
Guseyn M. Magomedov ◽  
I. V. Dolbin

The theoretical model, using the notions of fractal analysis is proposed for description of strength of nanocomposites polymer/2D-nanofiller on the example of nanocomposites polyvinylalcohol/boron nitride. For correct description of strength of these two-phase nanomaterial the knowledge of initial characteristics of matrix polymer (stress of fracture), geometrical parameters of nanofiller and level of interfacial adhesion polymer matrix-nanofiller is necessary. The indicated level, characterizing by shear interfacial strength, was determined theoretically within the framework of fractal conception of adhesion. Its absolute values found high enough – they are comparable with this characteristic in systems polymer-carbon nanotubes and are higher essentially than in systems polymer-microfiber (glassy and carbon fibers). This factor defines high enough strength of the considered nanocomposites. The important factor for fracture process of nanomaterials is aggregation of initial platelets of nanofiller, which forms “packets” (tactoids) of such platelets. The relatively small aggregation degree of nanofiller gives appreciable reduction of strength of nanocomposites polymer/2D-nanofiller. The indicated reduction is connected with transition of 2D-nanofiller structure from exfoliated to intercalated one, i.e. from separate platelets to their tactoids.



2018 ◽  
Vol 10 (7) ◽  
pp. 168781401878528 ◽  
Author(s):  
Zirong Luo ◽  
Xin Li ◽  
Jianzhong Shang ◽  
Hong Zhu ◽  
Delei Fang

A modified rule of mixtures is required to account for the experimentally observed nonlinear variation of tensile strength. A modified Halpin–Tsai model was presented to predict the Young’s modulus of multiscale reinforced composites with both micron-sized and nano-sized reinforcements. In the composites, both micron-sized fillers—carbon fibers—and nano-sized fillers—rubber nanoparticles and carbon nanotubes—are added into the epoxy resin matrix. Carbon fibers can help epoxy resins increase both the tensile strength and Young’s modulus, while rubber nanoparticles and carbon nanotubes can improve the toughness without sacrificing other properties. Mechanical experiments and scanning electron microscopy observations were used to study the effects of the micron-sized and nano-sized reinforcements and their combination on tensile and toughness properties of the composites. The results showed that the combined use of multiscale reinforcements had synergetic effects on both the strength and the toughness of the composites.



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