Response of hygroscopicity to heat treatment and its relation to durability of thermally modified wood

2017 ◽  
Vol 144 ◽  
pp. 671-676 ◽  
Author(s):  
Tao Li ◽  
Da-li Cheng ◽  
Stavros Avramidis ◽  
Magnus E.P. Wålinder ◽  
Ding-guo Zhou
Insects ◽  
2021 ◽  
Vol 12 (2) ◽  
pp. 139
Author(s):  
Sónia Duarte ◽  
Lina Nunes ◽  
Davor Kržišnik ◽  
Miha Humar ◽  
Dennis Jones

The majority of thermal modification processes are at temperatures greater than 180 °C, resulting in a product with some properties enhanced and some diminished (e.g., mechanical properties). However, the durability of thermally modified wood to termite attack is recognised as low. Recent attempts at combining thermal modification with chemical modification, either prior to or directly after the thermal process, are promising. Buffers, although not influencing the reaction systems, may interact on exposure to certain conditions, potentially acting as promoters of biological changes. In this study, two zwitterionic buffers, bicine and tricine, chosen for their potential to form Maillard-type products with fragmented hemicelluloses/volatiles, were assessed with and without thermal modification for two wood species (spruce and beech), with subsequent evaluation of their effect against subterranean termites (Reticulitermes grassei Clément) and their symbiotic protists. The effect of the wood treatments on termites and their symbionts was visible after four weeks, especially for spruce treated with tricine and bicine and heat treatment (bicine HT), and for beech treated with bicine and bicine and heat treatment (bicine HT). The chemical behaviour of these substances should be further investigated when in contact with wood and also after heat treatment. This is the first study evaluating the effect of potential Maillard reactions with zwitterionic buffers on subterranean termite symbiotic fauna.


2021 ◽  
Vol 274 ◽  
pp. 04014
Author(s):  
Shamil Mukhametzyanov ◽  
Ruslan Khasanshin ◽  
Ruslan Safin ◽  
Aigul Shaikhutdinova ◽  
Albina Safiullina

The greatest interest of researchers is focused on the processes of heat treatment of wood, taking place in an airless environment at temperatures of 180-250 °C, since heat treatment of wood allows increasing its moisture resistance, reduce hygroscopicity, and increase resistance to decay. However, a decrease in the hygroscopicity of wood adversely affects the process of obtaining glued materials due to a decrease in the wettability of thermowood surface and, as a consequence, a decrease in adhesion characteristics. This work is devoted to the study of the effect of ozone on the surface of thermally modified wood to increase the adhesive properties during gluing. It has been determined that the ozonation contributes to an increase in the wettability of the surface layer of thermal wood by more than 15% due to the reactivity of ozone to oxidize and degrade ligno-containing products of wood. It was revealed that the modification of wood, including preliminary volumetric heat treatment followed by surface treatment with ozone, causes an increase in the strength of the glue line when operated in high humidity conditions. In connection with the results obtained, an improved technology for the production of glued load-bearing structures for wooden housing construction is proposed.


Coatings ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 253
Author(s):  
Ruslan Rushanovich Safin ◽  
Aigul Ravilevna Shaikhutdinova ◽  
Ruslan Khasanshin ◽  
Shamil Mukhametzyanov ◽  
Albina Safina

This work is devoted to the study of the effect of ultraviolet rays for the surface activation of pine wood thermally modified at temperatures of 180−240 °C in order to increase the surface roughness, enhance the wettability of thermal wood and the adhesive strength of the glue in the production of wood block furniture panels. Studies were carried out to measure the contact angle of wettability of thermally modified wood samples of pine, as a result of which it was determined that the ultraviolet treatment process contributes to an increase in the adhesion properties of the surface layer of thermally modified wood by more than 13% due to the reactivity of ultraviolet rays to oxidize and degrade ligno-containing wood products. At the same time, the most active process of surface activation takes place during 60 min of ultraviolet irradiation of wood with a total irradiation of at least 125 W/cm2. It was revealed that the combined effect of two-stage wood processing, including preliminary volumetric thermal modification followed by surface ultraviolet treatment, causes an increase in the moisture resistance of glued wood products by 24%. So, if the strength of the glue seam when gluing natural wood samples after boiling decreased by 46%, then the samples that underwent two-stage processing showed a decrease only by 22%. In connection with the results obtained, an improved technology for the production of furniture boards for the manufacture of moisture-resistant wood products is proposed.


Polymers ◽  
2021 ◽  
Vol 13 (13) ◽  
pp. 2160
Author(s):  
Milan Gaff ◽  
Hana Čekovská ◽  
Jiří Bouček ◽  
Danica Kačíková ◽  
Ivan Kubovský ◽  
...  

This paper deals with the effect of synthetic and natural flame retardants on flammability characteristics and chemical changes in thermally treated meranti wood (Shorea spp.). The basic chemical composition (extractives, lignin, holocellulose, cellulose, and hemicelluloses) was evaluated to clarify the relationships of temperature modifications (160 °C, 180 °C, and 210 °C) and incineration for 600 s. Weight loss, burning speed, the maximum burning rate, and the time to reach the maximum burning rate were evaluated. Relationships between flammable properties and chemical changes in thermally modified wood were evaluated with the Spearman correlation. The thermal modification did not confirm a positive contribution to the flammability and combustion properties of meranti wood. The effect of the synthetic retardant on all combustion properties was significantly higher compared to that of the natural retardant.


2021 ◽  
Vol 114 ◽  
pp. 116-124
Author(s):  
Gabriela Slabejová ◽  
MÁRIA ŠMIDRIAKOVÁ

Colour stability of surface finishes on thermally modified beech wood. The paper deals with the influence of the type of transparent surface finish on the change of colour of the surfaces of native beech wood and thermally modified wood. At the same time, the colour stability of three surface finishes on the surfaces of native and thermally modified beech wood was monitored. Beech wood was thermally modified at temperature of 125 °C for 6 hours. The thermal treatment was performed in a pressure autoclave APDZ 240, by the company Sundermann s.r.o in Banská Štiavnica. Three various types of surface finishes (synthetic, wax-oil, water-based) were applied onto the wood surfaces. The colour of the surfaces of native wood and thermally modified wood was measured in the system CIELab before and after surface finishing; the coordinates L*, a*, b*, C*ab and h*ab were measured. From the coordinates measured before and after surface finishing, the differences were calculated and then the colour difference ∆E* was calculated. Subsequently, the test specimens with the surface finishes were exposed to natural sunlight, behind glass in the interior for 60 days. The surface colour was measured at specified time of the exposure (10, 20, 30, 60 days). The results showed that the colour of the wood surfaces changed after application of the individual surface finishes; and the colour difference reached a change visible with a medium quality filter up to a high colour difference. The wax-oil surface finish caused a high colour difference on native wood and on thermally modified wood as well. On native beech wood, the lowest colour difference after exposure to sunlight was noticeable on the synthetic surface finish. On the surface of wood thermally modified, after exposure to sunlight, the lowest colour difference was noticeable on the surface with no surface finish.


2021 ◽  
Vol 18 (1) ◽  
pp. 51-57
Author(s):  
F.A. Faruwa ◽  
K. Duru

The study investigated the use of thermal modification to improve the hygroscopic properties of False Iroko [Antiaris toxicaria (Lesch)]. Samples of Antiaris toxicara Lesch wood were subjected to thermal modification in a furnace at temperatures of 160, 180 and 200°C for 30 and 60 minutes. Results showed that wood properties were improved with exposure to different temperatures. Subsequent to the thermal process, a colour change from pale yellow to darkish brown was observed progressively with increase in temperature, accompanied by a weight loss in the range of 12.08% to 23.67%. The outcome of these treatments resulted in a decrease in volumetric swelling and increase in dimensional stability of modified wood; this can be attributed to observed decrease in moisture intake. The thermal modification of Antiaris toxicara Lesch wood affected the dimensional stability properties. Thus, due to significant changes via modification carried out on the selected species which is classified as lesser utilized wood species, lesser utilized wood,Antiaristoxicara Lesch wood is recommended for use due to its efficient dimensional stability after modification . keywords:, Thermally modified wood ;False Iroko


BioResources ◽  
2014 ◽  
Vol 9 (4) ◽  
Author(s):  
Laszlo Tolvaj ◽  
Robert Nemeth ◽  
Zoltan Pasztory ◽  
Laszlo Bejo ◽  
Peter Takats

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