scholarly journals Alkali-activated grouts based on slag-fly ash mixtures: From early-age characterization to long-term phase composition

2020 ◽  
Vol 260 ◽  
pp. 120510 ◽  
Author(s):  
Abdelilah Aboulayt ◽  
Faten Souayfan ◽  
Emmanuel Roziere ◽  
Reda Jaafri ◽  
Anass Cherki El Idrissi ◽  
...  
2018 ◽  
Vol 10 (10) ◽  
pp. 3538 ◽  
Author(s):  
Sol Park ◽  
Hammad Khalid ◽  
Joon Seo ◽  
Hyun Yoon ◽  
Hyeong Son ◽  
...  

The present study investigated geopolymerization in alkali-activated fly ash under elevated pressure conditions. The fly ash was activated using either sodium hydroxide or a combination of sodium silicate solution and sodium hydroxide, and was cured at 120 °C at a pressure of 0.22 MPa for the first 24 h. The pressure-induced evolution of the binder gel in the alkali-activated fly ash was investigated by employing synchrotron X-ray diffraction and solid-state 29Si and 27Al MAS NMR spectroscopy. The results showed that the reactivity of the raw fly ash and the growth of the zeolite crystals were significantly enhanced in the samples activated with sodium hydroxide. In contrast, the effects of the elevated pressure conditions were found to be less apparent in the samples activated with the sodium silicate solution. These results may have important implications for the binder design of geopolymers, since the crystallization of geopolymers relates highly to its long-term properties and functionality.


2010 ◽  
Vol 168-170 ◽  
pp. 2008-2012 ◽  
Author(s):  
Yong Hao Fang ◽  
Ya Min Gu ◽  
Qiu Boa Kang

The chemical shrinkages of alkali-activated slag cement (AASC), and the effect of fly ash, MgO burnt at 900°C and the curing solutions were studied. The shrinkages were compared with that of ordinary portland cement (OPC). The results show that the chemical shrinkage of AASC is lower than that of OPC. Adding fly ash and light-burnt MgO reduced the early age chemical shrinkage, while the shrinkage-reduction effect decreased with the age. The alkality of the curing solution has significant effect on the hydration and shrinkage of AASC. The chemical shrinkage of AASC increased with the alkali concentration of the curing solution. The mechanisms of fly ash, MgO and curing solution on the shrinkage were discussed.


2021 ◽  
Vol 2021 ◽  
pp. 1-14
Author(s):  
Fotini Kesikidou ◽  
Stavroula Konopisi ◽  
Eleftherios K. Anastasiou

This study investigated the use of concrete sludge, a by-product of the ready-mix concrete industry, in combination with high-calcium fly ash in binary cementless binders. Concrete sludge was used in substitution rates ranging from 0% to 60% in test fly ash-based mortars to determine potential synergy. The mortars were tested for fresh and hardened properties; workability, viscosity, strength development, open porosity, early-age shrinkage, and analytical tests were carried out. A mortar with 50% fly ash and 50% limestone filler as binders was used for comparison purposes. Furthermore, a series of mortars with fly ash and concrete sludge were alkali-activated in order to determine potential strength gain. In the activated mortars, two fractions of concrete sludge were used, under 75 μm and 200 μm, due to different silicon oxide contents, while one mortar was cured at 40°C to investigate the effect of heating on alkali activation. Results show that sludge contributes to the formation of C-S-H and strength development when used in combination with high-calcium fly ash even at high replacement rates. The alkali activation of fly ash-concrete sludge system contributed to early-age strength development and to early-age shrinkage reduction.


Polymers ◽  
2021 ◽  
Vol 14 (1) ◽  
pp. 63
Author(s):  
Chan-Yi Lin ◽  
Tai-An Chen

The compressive strengths of fly ash-based alkali-activated materials (AAM), produced using various activators of only sodium hydroxide, were measured. Fly ash-based AAM specimens, produced by mixing different kinds of fly ash and ground granulated blast-furnace slag (GGBFs) with an activator containing only sodium hydroxide, were cured at ambient temperature, and then placed in air for different numbers of days. The short- and long-term compressive strengths and shrinkage of fly ash-based AAM were measured and compared to one another. The effects of type of fly ash, alkali-equivalent content, GGBFs replace percentage, and ages on the compressive strengths and shrinkage of fly ash-based AAM were investigated. Even when different fly ash was used as the raw material for AAM, a similar compressive strength can be achieved by alkali-equivalent content, GGBFs replaces percentage. However, the performance of shrinkage due to different types of fly ash differed significantly.


2018 ◽  
Vol 761 ◽  
pp. 65-68 ◽  
Author(s):  
Yi Bing Zuo ◽  
Marija Nedeljković ◽  
Guang Ye

Pore solution of hardened alkali-activated fly ash paste was extracted by the steel-die method. The aqueous phase composition of pore solution was analyzed using ICP-OES analysis technique. The results show that the concentrations of Si, Al, Ca, K and OH- decrease with curing time regardless of the curing temperatures (40°C/60°C) and alkaline activators (sodium hydroxide with/without sodium silicate). On the contrary, the concentration of S increases with curing time. A higher temperature curing decreases the solubility of Si, Al, Ca and K in the alkali-activated fly ash, while it doesn’t show much influence on the solubility of S. The plot of the concentration of Al versus the concentration of Si displays a quasi-linear logarithmic relationship. This relationship implies congruent removal of Si and Al from the frameworks of fly ash.


Author(s):  
Xiaodi Dai ◽  
Serdar Aydin ◽  
Mert Yücel Yardimci ◽  
R.E.N. Qiang ◽  
Karel Lesage ◽  
...  

2014 ◽  
Vol 1000 ◽  
pp. 338-341
Author(s):  
Jaromír Poláček ◽  
Rostislav Šulc

This article deals with the basic properties of materials based on alkali-activated fly ash which contains a portion of fly ash produced during fluid burning. The primary task of our research was characterization of physical and chemical properties of each type of fly ash and fly ash mixture. The new materials composed of fly ash mixture and fly ash may have the similar mechanical and physical properties. The work focused on findingan appropriate technological procedure, the optimum composition of mixtures. Long-term stability was simulated by means of accelerated aging of these materials.


2016 ◽  
Vol 53 (1) ◽  
pp. 18-23 ◽  
Author(s):  
Sol-Moi Park ◽  
Jeong-Gook Jang ◽  
Gwang-Mok Kim ◽  
Haeng-Ki Lee

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