Fabrication of IPDI-LDHs/SBS modified asphalt with enhanced thermal aging and UV aging resistance

2021 ◽  
Vol 302 ◽  
pp. 124131
Author(s):  
Jing Li ◽  
Jing Yang ◽  
Yu Liu ◽  
Zhenxia Zhao ◽  
Xiaoying Tang ◽  
...  
2015 ◽  
Vol 2015 ◽  
pp. 1-13 ◽  
Author(s):  
Chao Peng ◽  
Jianying Yu ◽  
Jing Dai ◽  
Jian Yin

UV radiation is a main factor to reduce the service life of asphalt pavement due to the UV aging of asphalt binder. To obtain enhanced UV aging resistance, an organic UV absorber called 2-hydroxy-4-n-octoxy-benzophenone (HNOB) had been intercalated into an inorganic UV absorber called Zn/Al layered double hydroxide (LDH) to play a combined anti-UV role in asphalt binder. Fourier transform infrared spectroscopy revealed that HNOB anions have been intercalated into the interlayer galleries of Zn/Al-LDH containing HNOB anions (Zn/Al-HNOB−-LDH). X-ray diffraction results of Zn/Al-LDH containingCO32−anions (Zn/Al-CO32--LDH) andZn/Al-CO32--LDH/styrene-butadiene-styrene (SBS) modified asphalt disclosed that asphalt molecules entered into LDH interlayer galleries to form an expanded phase structure. UV-Vis absorbance patterns showed that Zn/Al-HNOB−-LDH has a better capacity of blocking UV light due to the synergetic effect of HNOB and Zn/Al-LDH. The chemical fractions analysis, conventional physical tests, and rheological tests of SBS modified asphalt,Zn/Al-CO32--LDH/SBSmodified asphalt, and Zn/Al-HNOB−-LDH/SBS modified asphalt before and after UV aging testified that Zn/Al-HNOB−-LDH can improve the UV aging resistance of SBS modified asphalt more significantly.


2021 ◽  
pp. 128139
Author(s):  
Hengbin Liu ◽  
Zhengqi Zhang ◽  
Jinqian Xie ◽  
Zengjian Gui ◽  
Naiqiang Li ◽  
...  

Materials ◽  
2021 ◽  
Vol 14 (19) ◽  
pp. 5672
Author(s):  
Xuewen Zheng ◽  
Wenyuan Xu ◽  
Shuangrui Xie

In order to explore the influence mechanism of carbon nanotubes on the ultraviolet (UV) aging properties of the SBS-modified asphalt binder, the changes of functional groups in the one-dimensional infrared spectrum and two-dimensional infrared correlation spectrum are studied in this paper. The results show that the UV aging process of the SBS-modified asphalt binder is the process of alkane chain cleavage and reorganization, the formation of oxygen-containing functional groups and decomposition of SBS. The incorporation of carbon nanotubes can reduce the mutual conversion of methyl and methylene functional groups, inhibit the decomposition of butadiene and the destruction of C = C double bonds in SBS. The degradation of SBS during the process of UV aging leads to the change of many functional groups and acceleration of the aging of the SBS-modified asphalt binder. The addition of carbon nanotubes can effectively alleviate the degradation of SBS and the formation of oxygen-containing functional groups at the early stage of UV aging, and reduce the influence of these two changes on other functional groups; thus, improving the anti-aging performance of the SBS-modified asphalt binder.


2017 ◽  
Vol 145 ◽  
pp. 126-134 ◽  
Author(s):  
Raqiqa tur Rasool ◽  
Shifeng Wang ◽  
Yong Zhang ◽  
Yue Li ◽  
Guangtai Zhang

Polymers ◽  
2019 ◽  
Vol 11 (7) ◽  
pp. 1111 ◽  
Author(s):  
Huanan Yu ◽  
Xianping Bai ◽  
Guoping Qian ◽  
Hui Wei ◽  
Xiangbing Gong ◽  
...  

Styrene Butadiene Styrene (SBS) polymer-modified asphalt binders have become widely used in asphalt pavement because of their advantages in high- and low-temperature performance and fatigue resistance. Asphalt pavement is inevitably exposed to sunlight and ultraviolet (UV) radiation during its construction and service life. However, consideration of the aging effect of UV radiation is still limited in current pavement design and evaluation systems. In order to evaluate the impact of UV radiation on the aging properties of SBS-modified asphalt binders, UV aging tests were performed on Rolling Thin Film Oven Test (RTFOT)-aged samples with different UV radiation intensities and aging times. Sixteen different groups of tests were conducted to compare the rheological properties and functional group characteristics of SBS-modified asphalt binders. Dynamic Shear Rheometer (DSR), Bending Beam Rheometer (BBR), FTIR, and SEM tests were conducted to evaluate the aging mechanisms in various UV aging conditions. The results found that UV radiation seriously destroys the network structure formed by the cross-linking effect in SBS-modified asphalt binders, which aggravates the degradation of SBS and results in a great change of rheological properties after UV aging. The nature of SBS-modified asphalt binder aging resulted from the degradation of SBS and the changes of asphalt binder base composition, which lead to the transformation of colloidal structure and the deterioration of asphalt binder performance. The tests also found that continuous UV radiation can increase shrinkage stress in the asphalt binder surface and leads to surface cracking of the asphalt binder.


2014 ◽  
Vol 490-491 ◽  
pp. 218-221
Author(s):  
Xiao Wang ◽  
Sai Sai Xie ◽  
Qing Lin Wu

The purpose of this work is to investigate the thermal aging and ultraviolet (UV) radiations aging of SBSMA. Antioxidants and UV absorbers were employed to improve the antiaging resistance of SBSMA in this study. The results indicated that the SBSMA with antioxidants has good heat aging resistance, and SBSMA with UV absorbers blends have good photostability. The compound antiaging agents containing antioxidants and UV absorbers are a best choice to prepare SBSMA with better physical and antiaging resistance. The experimental results also indicated that the effects of antiaging agents on the physical properties of SBSMA are little at low contents. Especially conventional physical properties of SBSMA with 1 wt% of ZDDP and 0.5 wt% of UV531 are close to that of SBSMA.


2014 ◽  
Vol 1065-1069 ◽  
pp. 1752-1755
Author(s):  
Shuai Tuan Tian ◽  
Feng Tang

SBS modified asphalt has good abilities to resisting pressure of high or low temperature and rutting in areas where changes of temperature is large. In our country,It is one of the important engineering materials which can solve the problem of heavy traffic on asphalt pavement and rutting in long and steep roads.In order to deeply understand the changes of rheological properties during the Thermal aging reaction of SBS modified asphalt,under different temperature conditions.regarded 90 # asphalt with CNOOC as lateral reference standard, Systematic study has been applied on the rheological properties of SBS modified asphalt and 90 # asphalt at different temperatures by using methods of DSR.The results showed that:during 28°C~34°C,with the rising of Temperature,performance of Resistance to fatigue cracking of the original modified asphalt and the original 90 # asphalt has became more and more strong.At the same temperature,the original modified asphalt’s performance of Resistance to fatigue cracking is stronger than the original 90 # asphalt’s.Long and short-term aging reactions weaken the performance of resistance to fatigue cracking of SBS modified asphalt and 90 # asphalt, and the effects of long-term weakening is more obvious.during 52°C~76°C,the anti-rutting performance of SBS modified asphalts and the 90 # original asphalts became more an more bad with the rising of Temperature.


2016 ◽  
Vol 2016 ◽  
pp. 1-9 ◽  
Author(s):  
Xiangbing Xie ◽  
Shenjia Tong ◽  
Yabi Ding ◽  
Hongni Liu ◽  
Linyuan Liang

Mortar has an important influence on the viscosity and durability of a mixture. The effects of the amount of mineral powder in asphalt mortar on the ultraviolet (UV) aging properties of asphalt were investigated by a Fourier transform infrared spectrum (FTIR), gel permeation chromatography (GPC), and dynamic shear rheometer (DSR). The FTIR results show that the UV-resistant aging ability of asphalt mortar was superior to asphalt and that the carbonyl indices of the SBS- (styrene-butadiene-styrene-) asphalt mortar and matrix asphalt mortar were more significant. The GPC results show that the molecular weight distribution coefficient (Mw/Mn) of the SBS-asphalt-filler mastic is 1.0 and that of the matrix asphalt-filler mastic is 1.2, which is the largest. The macro-property is the most stable. The DSR results show that the matrix asphalt-filler mastic ranging from 1.0 to 1.2 and the SBS-modified asphalt-filler mastic ranging from 0.8 to 1.0 show the best UV aging resistance. Therefore, the effects of the amount of mineral powder cannot be ignored, suggesting that the best mass ratio of the matrix asphalt mortar is 1.2 and that of the SBS-modified asphalt mortar is 1.0 during the UV aging process.


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