Research progress on nano-Fe0/PS system for degradation of refractory organics in aqueous solution

2021 ◽  
Vol 9 (4) ◽  
pp. 105345
Author(s):  
Yanjiao Gao ◽  
Jiacheng Luo ◽  
Tiehong Song ◽  
Xiaodan Yu
2015 ◽  
Vol 737 ◽  
pp. 661-663
Author(s):  
Xiao Ming Sun ◽  
Jing Yang Liu ◽  
Qi Qiao ◽  
Yue Zhang ◽  
Na Zhang ◽  
...  

Reverse osmosis membrane is usually used to desalination. With the development of membrane materials and technology, the performance of reverse osmosis membrane is improved continuously, and the interception rate of organic matter is higher, the separation rate of the organic matter is obviously improved. The research progress and application status of separating organics in aqueous solution by reverse osmosis membrane is presented in this paper. The future research direction and application of reverse osmosis membrane for separating organics from aqueous solution were also analyzed and prospected.


2016 ◽  
Vol 70 (1) ◽  
Author(s):  
D SANTOSO ◽  
A RAHMAWAN

SummaryIndonesia cacao plantations have relatively low productivity, which actually can be improved by reducing cherelle wilt using vegetative growth retardant (VGR) formula with proper composition. This paper describes research progress aimed to formulate molecular inducer capable of reducing cherelle wilt in cacao plantation. The main constituent of the formula was VGR of chloro choline type with additional component of a acidic buffer. Chemical environment was adjusted for better effectiveness of the formula. The application to examine the affectivity was conducted by several ways with the aqueous solution at 25 to 200 ppm. The observation was recorded twice a week. Examination in experimentation showed that foliar spray at upper side was the best among 6 methods tested. Experiments done in a commercial plantation demonstrated that VGR was able to reduce cherelle wilt in cacao. Addition of acidic buffer improved the performance of VGR formula. At 3 and 4 weeks after the treatments with the VGR formulas, cherelle wilt were decreased to become 18.8% and 39.9%. These numbers were significantly lower than the percentages of cherelle wilt on the trees sprayed only with water, which reached to 48.8% dan 64.6% at 3 and 4 weeks after treatments respectively. RingkasanProduktivitas perkebunan kakao Indonesia relatif rendah. Usaha peningkatan produktivitasnya dapat ditempuh melalui pengurangan jumlah layu pentil kakao, dengan cara mengaplikasikan formula zat pengatur tumbuh dari jenis penghambat pertumbuhan vegetatif (VGR) berkomposisi sesuai. Makalah ini membahas hasil penelitian tentang pengembangan suatu teknologi praktis untuk menurunkan tingkat layu pentil kakao. Sebagai komponen utama adalah VGR jenis kloro kolin dengan suplemen bufer asam. Kondisi kimiawi tertentu formula tersebut merupakan pertimbangan tambahan dalam mendapatkan keefektifan yang lebih baik. Aplikasinya dilakukan dengan berbagai cara pada tanaman yang sedang berbuah kecil (pentil) dengan konsentrasi VGR bervariasi antara 25 hingga 200 ppm. Pengamatan dilakukan secara periodik dua kali dalam satu minggu. Dari enam cara aplikasi yang diuji, penyemprotan lapis atas daun merupakan cara yang terefektif. Percobaan pada tanaman kakao di kebun percobaan maupun kebun komersial menunjukkan bahwa VGR mampu menekan layu pentil kakao. Formula VGR yang mengandung bufer asam memiliki daya pengurangan layu pentil lebih baik daripada yang tanpa bufer. Pada pengamatan 3 dan 4 minggu setelah aplikasi formula VGR, tingkat layu pentil pada pohon kakao yang disemprot dengan formula VGR berbufer hanya sekitar 18,8% dan 39,9%. Sementara itu pada pohonpohon yang hanya disemprot dengan air, layu pentil pada waktu pengamatan tersebut mencapai 48,8% dan 64,6%.


2016 ◽  
Vol 70 (1) ◽  
Author(s):  
D SANTOSO ◽  
A RAHMAWAN

SummaryIndonesia cacao plantations have relatively low productivity, which actually can be improved by reducing cherelle wilt using vegetative growth retardant (VGR) formula with proper composition. This paper describes research progress aimed to formulate molecular inducer capable of reducing cherelle wilt in cacao plantation. The main constituent of the formula was VGR of chloro choline type with additional component of a acidic buffer. Chemical environment was adjusted for better effectiveness of the formula. The application to examine the affectivity was conducted by several ways with the aqueous solution at 25 to 200 ppm. The observation was recorded twice a week. Examination in experimentation showed that foliar spray at upper side was the best among 6 methods tested. Experiments done in a commercial plantation demonstrated that VGR was able to reduce cherelle wilt in cacao. Addition of acidic buffer improved the performance of VGR formula. At 3 and 4 weeks after the treatments with the VGR formulas, cherelle wilt were decreased to become 18.8% and 39.9%. These numbers were significantly lower than the percentages of cherelle wilt on the trees sprayed only with water, which reached to 48.8% dan 64.6% at 3 and 4 weeks after treatments respectively. RingkasanProduktivitas perkebunan kakao Indonesia relatif rendah. Usaha peningkatan produktivitasnya dapat ditempuh melalui pengurangan jumlah layu pentil kakao, dengan cara mengaplikasikan formula zat pengatur tumbuh dari jenis penghambat pertumbuhan vegetatif (VGR) berkomposisi sesuai. Makalah ini membahas hasil penelitian tentang pengembangan suatu teknologi praktis untuk menurunkan tingkat layu pentil kakao. Sebagai komponen utama adalah VGR jenis kloro kolin dengan suplemen bufer asam. Kondisi kimiawi tertentu formula tersebut merupakan pertimbangan tambahan dalam mendapatkan keefektifan yang lebih baik. Aplikasinya dilakukan dengan berbagai cara pada tanaman yang sedang berbuah kecil (pentil) dengan konsentrasi VGR bervariasi antara 25 hingga 200 ppm. Pengamatan dilakukan secara periodik dua kali dalam satu minggu. Dari enam cara aplikasi yang diuji, penyemprotan lapis atas daun merupakan cara yang terefektif. Percobaan pada tanaman kakao di kebun percobaan maupun kebun komersial menunjukkan bahwa VGR mampu menekan layu pentil kakao. Formula VGR yang mengandung bufer asam memiliki daya pengurangan layu pentil lebih baik daripada yang tanpa bufer. Pada pengamatan 3 dan 4 minggu setelah aplikasi formula VGR, tingkat layu pentil pada pohon kakao yang disemprot dengan formula VGR berbufer hanya sekitar 18,8% dan 39,9%. Sementara itu pada pohonpohon yang hanya disemprot dengan air, layu pentil pada waktu pengamatan tersebut mencapai 48,8% dan 64,6%.


2020 ◽  
Vol 2 (4) ◽  
pp. 97-112
Author(s):  
Liu Xinliang ◽  
Chen qianyin ◽  
Yin Hailiang ◽  
Guo Ziqi ◽  
Liu Zhen

2021 ◽  
Vol 2076 (1) ◽  
pp. 012117
Author(s):  
Xiaoyu Yang ◽  
Ling Tong ◽  
Lin Wu ◽  
Baoguo Zhang ◽  
Zhiyuan Liao ◽  
...  

Abstract Metal-assisted etching of silicon in HF aqueous solution has attracted widespread attention due to its potential applications in electronics, photonics, renewable energy, and biotechnology. In this paper, the basic process and mechanism of metal assisted electrochemical etching of silicon in vapor or liquid atmosphere based on galvanic cells are reviewed. This paper focuses on the use of gas-phase oxidants O2 and H2O2 instead of liquid phase oxidants Fe(NO3)3 and H2O2 to catalyze the etching of silicon in the vapor atmosphere of HF aqueous solution. The mechanism of substrate enhanced metal-assisted chemical etching for the preparation of large-area silicon micro nanostructure arrays is summarized, and the impact of substrate type and surface area on reactive etching is discussed.


Author(s):  
G. G. Cocks ◽  
C. E. Cluthe

The freeze etching technique is potentially useful for examining dilute solutions or suspensions of macromolecular materials. Quick freezing of aqueous solutions in Freon or propane at or near liquid nitrogen temperature produces relatively large ice crystals and these crystals may damage the structures to be examined. Cryoprotective agents may reduce damage to the specimem, hut their use often results in the formation of a different set of specimem artifacts.In a study of the structure of polyethylene oxide gels glycerol and sucrose were used as cryoprotective agents. The experiments reported here show some of the structures which can appear when these cryoprotective agents are used.Figure 1 shows a fractured surface of a frozen 25% aqueous solution of sucrose. The branches of dendritic ice crystals surrounded hy ice-sucrose eutectic can be seen. When this fractured surface is etched the ice in the dendrites sublimes giving the type of structure shown in Figure 2. The ice-sucrose eutectic etches much more slowly. It is the smooth continuous structural constituent surrounding the branches of the dendrites.


Author(s):  
A. Legrouri

The industrial importance of metal catalysts supported on reducible oxides has stimulated considerable interest during the last few years. This presentation reports on the study of the physicochemical properties of metallic rhodium supported on vanadium pentoxide (Rh/V2O5). Electron optical methods, in conjunction with other techniques, were used to characterise the catalyst before its use in the hydrogenolysis of butane; a reaction for which Rh metal is known to be among the most active catalysts.V2O5 powder was prepared by thermal decomposition of high purity ammonium metavanadate in air at 400 °C for 2 hours. Previous studies of the microstructure of this compound, by HREM, SEM and gas adsorption, showed it to be non— porous with a very low surface area of 6m2/g3. The metal loading of the catalyst used was lwt%Rh on V2Q5. It was prepared by wet impregnating the support with an aqueous solution of RhCI3.3H2O.


Author(s):  
H. Mori ◽  
Y. Murata ◽  
H. Yoneyama ◽  
H. Fujita

Recently, a new sort of nano-composites has been prepared by incorporating such fine particles as metal oxide microcrystallites and organic polymers into the interlayer space of montmorillonite. Owing to their extremely large specific surface area, the nano-composites are finding wide application[1∼3]. However, the topographic features of the microstructures have not been elucidated as yet In the present work, the microstructures of iron oxide-pillared montmorillonite have been investigated by high-resolution transmission electron microscopy.Iron oxide-pillared montmorillonite was prepared through the procedure essentially the same as that reported by Yamanaka et al. Firstly, 0.125 M aqueous solution of trinuclear acetato-hydroxo iron(III) nitrate, [Fe3(OCOCH3)7 OH.2H2O]NO3, was prepared and then the solution was mixed with an aqueous suspension of 1 wt% clay by continuously stirring at 308 K. The final volume ratio of the latter aqueous solution to the former was 0.4. The clay used was sodium montmorillonite (Kunimine Industrial Co.), having a cation exchange capacity of 100 mequiv/100g. The montmorillonite in the mixed suspension was then centrifuged, followed by washing with deionized water. The washed samples were spread on glass plates, air dried, and then annealed at 673 K for 72 ks in air. The resultant film products were approximately 20 μm in thickness and brown in color.


Author(s):  
Eduardo A. Kamenetzky ◽  
David A. Ley

The microstructure of polyacrylonitrile (PAN) beads for affinity chromatography bioseparations was studied by TEM of stained ultramicrotomed thin-sections. Microstructural aspects such as overall pore size distribution, the distribution of pores within the beads, and surface coverage of functionalized beads affect performance properties. Stereological methods are used to quantify the internal structure of these chromatographic supports. Details of the process for making the PAN beads are given elsewhere. TEM specimens were obtained by vacuum impregnation with a low-viscosity epoxy and sectioning with a diamond knife. The beads can be observed unstained. However, different surface functionalities can be made evident by selective staining. Amide surface coverage was studied by staining in vapor of a 0.5.% RuO4 aqueous solution for 1 h. RuO4 does not stain PAN but stains, amongst many others, polymers containing an amide moiety.


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