scholarly journals Polychlorinated biphenyls (PCBs) and hexachlorobenzene (HCB) in the equatorial Indian Ocean: Temporal trend, continental outflow and air–water exchange

2014 ◽  
Vol 80 (1-2) ◽  
pp. 194-199 ◽  
Author(s):  
Yumei Huang ◽  
Jun Li ◽  
Yue Xu ◽  
Weihai Xu ◽  
Zhineng Cheng ◽  
...  
2020 ◽  
Author(s):  
Sobhan Kumar Kompalli ◽  
Surendran Nair Suresh Babu ◽  
Krishnaswamy Krishnamoorthy ◽  
Sreedharan Krishnakumari Satheesh ◽  
Mukunda M. Gogoi ◽  
...  

Abstract. Regional climatic implications of aerosol black carbon (BC) are well recognized over South Asia, which has a wide variety of anthropogenic sources in a large abundance. Significant uncertainties remain in its quantification due to lack of sufficient information on the microphysical properties (its concentration, size, and mixing state with other aerosol components), which determine the absorption potential of BC. Especially the information on mixing state of BC is extremely sparse over this region. In this study, first-ever observations of the size distribution and mixing state of individual refractory black carbon (rBC) particles in the south Asian outflow to Southeastern Arabian Sea, northern and equatorial Indian Ocean regions are presented based on measurements using a single particle soot photometer (SP2) aboard the ship cruise of the Integrated Campaign for Aerosols, gases, and Radiation Budget (ICARB-2018) during winter-2018 (16 January to 13 February). The results revealed significant spatial heterogeneity of BC characteristics. Highest rBC mass concentrations (~ 938 ± 293 ng m−3) with the highest relative coating thickness (RCT; the ratio of BC core to its coating diameters) of ~ 2.16 ± 0.19 are found over the Southeast Arabian Sea (SEAS) region, which is in the proximity of the continental outflow. As we move to farther oceanic regions, though the mass concentrations decreased by nearly half (~ 546 ± 80 ng m−3), BC still remained thickly coated (RCT ~ 2.05 ± 0.07). The air over the remote equatorial Indian Ocean, which received considerable marine air masses compared to the other regions, showed the lowest rBC mass concentrations (~ 206 ± 114 ng m−3), with a moderately thick coating (RCT ~ 1.73 ± 0.16). Even over oceanic regions far from the landmass, regions which received the outflow from more industrialized east coast/the Bay of Bengal had thicker coating (~ 104 nm) compared to regions that received outflow from the west coast/peninsular India (~ 86 nm). Although different regions of the ocean depicted contrasting concentrations and mixing state parameters due to varying extent and nature of the continental outflow as well as the atmospheric lifetime of air masses, the modal parameters of rBC mass-size distributions were similar over all the regions. The observed mono-modal distribution with mean mass median diameters (MMD) in the range of 0.19–0.20 μm suggested mixed sources of BC. The mean fraction of BC containing particles (FBC) varied in the range 0.20–0.28 (suggesting significant amounts of non-BC particles), whereas the bulk mixing ratio of coating mass to rBC mass was highest (8.77 ± 2.77) over the outflow regions compared to the remote ocean (4.29 ± 1.54) highlighting the role of outflow in providing condensable material for coating on rBC. These parameters, along with the information on size-resolved mixing state of BC cores, throw light on the role of sources and secondary processing of their complex mixtures for coating on BC under highly polluted conditions. Examination of the non-refractory sub-micrometre aerosol chemical composition obtained using the aerosol chemical speciation monitor (ACSM) suggested that the overall aerosol system was sulfate dominated over the far-oceanic regions. In contrast, organics were equally prominent adjacent to the coastal landmass. Association between the BC mixing state and aerosol chemical composition suggested that sulfate was the probable dominant coating material on rBC cores.


2021 ◽  
Vol 21 (11) ◽  
pp. 9173-9199
Author(s):  
Sobhan Kumar Kompalli ◽  
Surendran Nair Suresh Babu ◽  
Krishnaswamy Krishna Moorthy ◽  
Sreedharan Krishnakumari Satheesh ◽  
Mukunda Madhab Gogoi ◽  
...  

Abstract. Regional climatic implications of aerosol black carbon (BC), which has a wide variety of anthropogenic sources in large abundance, are well recognized over South Asia. Significant uncertainties remain in its quantification due to a lack of sufficient information on the microphysical properties (its concentration, size, and mixing state with other aerosol components) that determine the absorption potential of BC. In particular, the information on the mixing state of BC is extremely sparse over this region. In this study, the first observations of the size distribution and mixing state of individual refractory black carbon (rBC) particles in the South Asian outflow to the south-eastern Arabian Sea and the northern and equatorial Indian Ocean regions are presented based on measurements using a single particle soot photometer (SP2) aboard the Integrated Campaign for Aerosols, gases, and Radiation Budget (ICARB-2018) ship during winter 2018 (16 January to 13 February). The results revealed significant spatial heterogeneity of BC characteristics. The highest rBC mass concentrations (∼938±293 ng m−3) with the highest relative coating thickness (RCT; the ratio of BC core to its coating diameters) of ∼2.16±0.19 are found over the south-east Arabian Sea (SEAS) region, which is in the proximity of the continental outflow. As we move to farther oceanic regions, though the mass concentrations decreased by nearly half (∼546±80 ng m−3), BC still remained thickly coated (RCT∼2.05±0.07). The air over the remote equatorial Indian Ocean, which received considerable marine air masses compared to the other regions, showed the lowest rBC mass concentrations (∼206±114 ng m−3) with a moderately thick coating (RCT∼1.73±0.16). Even over oceanic regions far from the landmass, regions that received the outflow from the more industrialized east coast/the Bay of Bengal had a thicker coating (∼104 nm) compared to regions that received outflow from the west coast and/or peninsular India (∼86 nm). Although different regions of the ocean depicted contrasting concentrations and mixing state parameters due to the varied extent and nature of the continental outflow as well as the atmospheric lifetime of air masses, the modal parameters of rBC mass–size distributions (mean mass median diameters ∼ 0.19–0.20 µm) were similar over all regions. The mean fraction of BC-containing particles (FBC) varied in the range of 0.08–0.12 (suggesting significant amounts of non-BC particles), whereas the bulk mixing ratio of coating mass to rBC mass was highest (8.31±2.40) over the outflow regions compared to the remote ocean (4.24±1.45), highlighting the role of outflow in providing condensable material for coatings on rBC. These parameters, along with the information on the size-resolved mixing state of BC cores, throw light on the role of sources and secondary processing of their complex mixtures for coatings on BC under highly polluted conditions. Examination of the non-refractory sub-micrometre aerosol chemical composition obtained using the aerosol chemical speciation monitor (ACSM) suggested that the overall aerosol system was sulfate-dominated over the far-oceanic regions. In contrast, organics were equally prominent adjacent to the coastal landmass. An association between the BC mixing state and aerosol chemical composition suggested that sulfate was the probable dominant coating material on rBC cores.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Wei Shi ◽  
Menghua Wang

AbstractThe 2019 positive Indian Ocean Dipole (IOD) event in the boreal autumn was the most serious IOD event of the century with reports of significant sea surface temperature (SST) changes in the east and west equatorial Indian Ocean. Observations of the Visible Infrared Imaging Radiometer Suite (VIIRS) onboard the Suomi National Polar-orbiting Partnership (SNPP) between 2012 and 2020 are used to study the significant biological dipole response that occurred in the equatorial Indian Ocean following the 2019 positive IOD event. For the first time, we propose, identify, characterize, and quantify the biological IOD. The 2019 positive IOD event led to anomalous biological activity in both the east IOD zone and west IOD zone. The average chlorophyll-a (Chl-a) concentration reached over ~ 0.5 mg m−3 in 2019 in comparison to the climatology Chl-a of ~ 0.3 mg m−3 in the east IOD zone. In the west IOD zone, the biological activity was significantly depressed. The depressed Chl-a lasted until May 2020. The anomalous ocean biological activity in the east IOD zone was attributed to the advection of the higher-nutrient surface water due to enhanced upwelling. On the other hand, the dampened ocean biological activity in the west IOD zone was attributed to the stronger convergence of the surface waters than that in a normal year.


2020 ◽  
Vol 125 (6) ◽  
Author(s):  
Ebenezer S. Nyadjro ◽  
Adam V. Rydbeck ◽  
Tommy G. Jensen ◽  
James G. Richman ◽  
Jay F. Shriver

2006 ◽  
Vol 36 (5) ◽  
pp. 827-846 ◽  
Author(s):  
Toru Miyama ◽  
Julian P. McCreary ◽  
Debasis Sengupta ◽  
Retish Senan

Abstract Variability of the wind field over the equatorial Indian Ocean is spread throughout the intraseasonal (10–60 day) band. In contrast, variability of the near-surface υ field in the eastern, equatorial ocean is concentrated at biweekly frequencies and is largely composed of Yanai waves. The excitation of this biweekly variability is investigated using an oceanic GCM and both analytic and numerical versions of a linear, continuously stratified (LCS) model in which solutions are represented as expansions in baroclinic modes. Solutions are forced by Quick Scatterometer (QuikSCAT) winds (the model control runs) and by idealized winds having the form of a propagating wave with frequency σ and wavenumber kw. The GCM and LCS control runs are remarkably similar in the biweekly band, indicating that the dynamics of biweekly variability are fundamentally linear and wind driven. The biweekly response is composed of local (nonradiating) and remote (Yanai wave) parts, with the former spread roughly uniformly along the equator and the latter strengthening to the east. Test runs to the numerical models separately forced by the τx and τy components of the QuikSCAT winds demonstrate that both forcings contribute to the biweekly signal, the response forced by τy being somewhat stronger. Without mixing, the analytic spectrum for Yanai waves forced by idealized winds has a narrowband (resonant) response for each baroclinic mode: Spectral peaks occur whenever the wavenumber of the Yanai wave for mode n is sufficiently close to kw and they shift from biweekly to lower frequencies with increasing modenumber n. With mixing, the higher-order modes are damped so that the largest ocean response is restricted to Yanai waves in the biweekly band. Thus, in the LCS model, resonance and mixing act together to account for the ocean's favoring the biweekly band. Because of the GCM's complexity, it cannot be confirmed that vertical mixing also damps its higher-order modes; other possible processes are nonlinear interactions with near-surface currents, and the model's low vertical resolution below the thermocline. Test runs to the LCS model show that Yanai waves from several modes superpose to form a beam (wave packet) that carries energy downward as well as eastward. Reflections of such beams from the near-surface pycnocline and bottom act to maintain near-surface energy levels, accounting for the eastward intensification of the near-surface, equatorial υ field in the control runs.


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