scholarly journals Fourier transform infrared (FTIR) analysis identifies microplastics in stranded common dolphins (Delphinus delphis) from New Zealand waters

2021 ◽  
Vol 173 ◽  
pp. 113084
Author(s):  
Karen A. Stockin ◽  
Olga Pantos ◽  
Emma L. Betty ◽  
Matthew D.M. Pawley ◽  
Fraser Doake ◽  
...  
Molecules ◽  
2021 ◽  
Vol 26 (12) ◽  
pp. 3588
Author(s):  
Jiayi Chen ◽  
Yansong Liu ◽  
Jiayue Zhang ◽  
Yuanlin Ren ◽  
Xiaohui Liu

Lyocell fabrics are widely applied in textiles, however, its high flammability increases the risk of fire. Therefore, to resolve the issue, a novel biomass-based flame retardant with phosphorus and nitrogen elements was designed and synthesized by the reaction of arginine with phosphoric acid and urea. It was then grafted onto the lyocell fabric by a dip-dry-cure technique to prepare durable flame-retardant lyocell fabric (FR-lyocell). X-ray photoelectron spectroscopy (XPS) and Fourier-transform infrared spectroscopy (FTIR) analysis demonstrated that the flame retardant was successfully introduced into the lyocell sample. Thermogravimetric (TG) and Raman analyses confirmed that the modified lyocell fabric featured excellent thermal stability and significantly increased char residue. Vertical combustion results indicated that FR-lyocell before and after washing formed a complete and dense char layer. Thermogravimetric Fourier-transform infrared (TG-FTIR) analysis suggested that incombustible substances (such as H2O and CO2) were produced and played a significant fire retarding role in the gas phase. The cone calorimeter test corroborated that the peak of heat release rate (PHRR) and total heat release (THR) declined by 89.4% and 56.4%, respectively. These results indicated that the flame retardancy of the lyocell fabric was observably ameliorated.


2019 ◽  
Vol 1 (2) ◽  
pp. 1-7
Author(s):  
O.O. Shonekan ◽  
◽  
A.C. Otuka ◽  
D.K. Adeyemi ◽  
O.T. Fatunsin ◽  
...  

Background: Syzygium guineenses, (the most common and abundant specie in Nigeria) is a medicinal plant used by traditional practitioners in northern Nigeria for a variety of healing purposes. Objective: The main objective of this project was to carry out a comparison of antioxidant activities and Fourier Transform Infrared Spectrophotometric (FTIR) analysis on both methanol and hexane leaf extracts of S. guineenses. Methods: Phytochemical screening, Semi-quantitative DPPH (1,1-diphenyl-2-picrylhydrazyl)- dot blot assay and FTIR analysis were performed on both extracts to determine antioxidant activity and identify the functional groups present. Results: Phytochemicals tested for, were observed to be more prominent in the methanol extract than hexane. The in vitro antioxidant assay also revealed a more intense yellow colour of inhibition in methanol extract than the hexane extract. The FTIR spectra revealed different characteristic peak values with various functional compounds in both extracts. The methanol extract displayed major peaks of absorption at 3341 cm-1 (-OH) for alcohol, 1736 cm-1 (C=O) carbonyl group, 1161.83 cm-1, 1036.49 cm-1 (C-O) of esters. Other absorption bands like 1452.25 cm-1 and 1612.20 cm-1 for alkenes were present in both extracts. Conclusion: This result shows that the methanol extract of S. guineenseshas a higher potential of phytochemicals, antioxidants and functional groups than the hexane extract.


2022 ◽  
pp. 295-320
Author(s):  
Mukesh Kumar Singh ◽  
Annika Singh

2013 ◽  
Vol 67 (11) ◽  
pp. 2602-2607 ◽  
Author(s):  
K. Kimura ◽  
R. Ogyu ◽  
T. Miyoshi ◽  
T. Naruse ◽  
T. Tsuyuhara ◽  
...  

Membrane fouling needs to be mitigated for widespread use of membrane bioreactors (MBRs). It has been pointed out that particles with small sizes found in supernatants (sub-micron particles) of mixed liquor suspensions of MBRs are important in the evolution of membrane fouling of this technology. However, information on characteristics of sub-micron particles in MBRs is still insufficient. In this study, a pilot-scale MBR treating municipal wastewater was used to investigate and characterize sub-micron particles in an MBR and to identify the size fraction(s) responsible for irreversible fouling in an MBR. It was clearly shown that characteristics of sub-micron particles in the MBR varied considerably depending on their sizes. Results of Fourier transform infrared (FTIR) analysis and monosaccharide analysis suggested that irreversible fouling in this study was mainly caused by the specific size fraction of 0.1–0.45 μm, which was close to the size of micropores of the membrane used. Pore plugging might explain this to some extent.


2012 ◽  
Vol 2012 ◽  
pp. 1-6 ◽  
Author(s):  
Bjørn Petter Jelle ◽  
Petra Rüther ◽  
Per Jostein Hovde

Fourier transform infrared (FTIR) material characterization by applying the attenuated total reflectance (ATR) experimental technique represents a powerful measurement tool. The ATR technique may be applied on both solid state materials, liquids and gases with none or only minor sample preparations, also including materials which are nontransparent to infrared radiation. This facilitation is made possible by pressing the sample directly onto various crystals, for example, diamond, with high refractive indices, in a special reflectance setup. Materials undergoing ageing processes by natural and accelerated climate exposure, decomposition and formation of chemical bonds and products, may be studied in an ATR-FTIR analysis. In this work, the ATR-FTIR technique is utilized to detect changes in selected wood building material substrates subjected to accelerated climate exposure conditions. Changes in specific FTIR absorbance peaks are designated to different wood deterioration processes. One aim is by ATR-FTIR analysis to be able to quantitatively determine the length of the wood ageing time before priming/treatment. Climate parameters like temperature (including freezing/thawing), relative air humidity, wind driven rain amount, solar and/or ultraviolet radiation, and exposure duration may be controlled in different climate ageing apparatuses. Both impregnated and raw wood samples have been employed in the experimental investigations.


The Analyst ◽  
2013 ◽  
Vol 138 (14) ◽  
pp. 3891 ◽  
Author(s):  
Donna R. Whelan ◽  
Keith R. Bambery ◽  
Ljiljana Puskar ◽  
Don McNaughton ◽  
Bayden R. Wood

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