Insights into the phase evolution-composition-structural aspect of silicon carbide powders preparing from nature silica sands of south Libya

Author(s):  
Ftema W. Aldbea ◽  
Subhiyah Aboulqasim Alameen ◽  
Carlos Vázquez Vázquez ◽  
A. Sharma ◽  
Mabrouk Kraini ◽  
...  
2020 ◽  
Vol 10 (18) ◽  
pp. 6161
Author(s):  
Kyoung-Jin Lee ◽  
Yanggu Kang ◽  
Young Hun Kim ◽  
Se Won Baek ◽  
Haejin Hwang

β-silicon carbide (SiC) powders were synthesized by the carbothermal reduction of methyl-modified silica aerogel/carbon mixtures. The correlations between the phase evolution and morphologies of the SiC powders and the C/SiO2 ratio were investigated. At a C/SiO2 ratio of 3, β-SiC formed at 1425 °C and single-phase SiC powders were obtained at 1525 °C. The methyl groups (-CH3) on the silica aerogel surfaces played important roles in the formation of SiC during the carbothermal reduction. SiC could be synthesized from the silica aerogel/carbon mixtures under lower temperature and C/SiO2 ratios than those needed for quartz or hydrophilic silica. The morphology of the SiC powder depended on the C/SiO2 ratio. A low C/SiO2 ratio resulted in β-SiC powder with spherical morphology, while agglomerates consisting of fine SiC particles were obtained at the C/SiO2 ratio of 3. High-purity SiC powder (99.95%) could be obtained with C/SiO2 = 0.5 and 3 at 1525 °C for 5 h.


2007 ◽  
Vol 555 ◽  
pp. 261-265 ◽  
Author(s):  
A. Devečerski ◽  
A. Radosavljević-Mihajlović ◽  
A. Egelja ◽  
M. Pošarac ◽  
B. Matović

The objective of this manuscript was to investigate the synthesis of SiC by carbothermal– reduction reactions of sepiolite. Sepiolite of Serbian origin and carbon (from various precursors) as a reducing agent were used. The green bodies with various C/SiO2 ratios were carbonized at 1073 K and heattreated at 1673 K in a controlled Ar flow atmosphere. Phase evolution and phase content were followed as a function of C/SiO2 ratio and carbon origin. The starting materials and products were characterized by means of XRD and SEM. The results show that sepiolite can be very effective source for obtaining silicon carbide powders.


Author(s):  
S. Ram Kumar ◽  
Vikram Ramanan

Gas turbine, or the jet engines have seen a rise in thrust output by increasing the chamber temperatures, advancement in compressor staging etc. On due of increased temperature limits, the turbine has particularly been subjected to higher thermomechanical stresses on the first stage high pressure stators, caused by the hot combustion product gases at high velocities. Thermal strains also get induced due to non-uniform temperature distribution from the hub to tip of the vanes. Improvements in material technologies to curb for higher temperatures have brought ceramic matrix composites into implementation. These are lighter in weight and have higher melting points than the conventionally used metal super alloys, with silicon carbide SiC/SiC matrix being specially used as the material for turbine stage of the engine. This consists of long unidirectional sic fibers as reinforcement, embedded in sic matrix phase, with fibre volume fractions in the range 30–40 percentages. But with further increase in thrust requirements, the turbine inlet temperature is also increased, affecting the material and the performance life of the component. Hence furthermore innovation in materials with higher strengths and melting points has to be incorporated. This work is on the use of vanadium carbide fibers as the reinforcement phase of silicon carbide matrix composite for the high pressure turbine stator. Structural analysis is carried out for the blade for both the composites, in ansys software using time stepped increment in temperature upto 1600°c. Results are compared to that for Sic/Sic composites. Thus the comparative analysis between the two composites is carried out on the thermo-structural aspect to predict their performance in the elevated temperatures.


2016 ◽  
Vol 48 (1) ◽  
pp. 501-512 ◽  
Author(s):  
M. Sribalaji ◽  
O. S. Asiq Rahman ◽  
P. Arun Kumar ◽  
K. Suresh Babu ◽  
Nitin P. Wasekar ◽  
...  

Author(s):  
R. J. Lauf

Fuel particles for the High-Temperature Gas-Cooled Reactor (HTGR) contain a layer of pyrolytic silicon carbide to act as a miniature pressure vessel and primary fission product barrier. Optimization of the SiC with respect to fuel performance involves four areas of study: (a) characterization of as-deposited SiC coatings; (b) thermodynamics and kinetics of chemical reactions between SiC and fission products; (c) irradiation behavior of SiC in the absence of fission products; and (d) combined effects of irradiation and fission products. This paper reports the behavior of SiC deposited on inert microspheres and irradiated to fast neutron fluences typical of HTGR fuel at end-of-life.


Author(s):  
K. B. Alexander ◽  
P. F. Becher

The presence of interfacial films at the whisker-matrix interface can significantly influence the fracture toughness of ceramic composites. The film may alter the interface debonding process though changes in either the interfacial fracture energy or the residual stress at the interface. In addition, the films may affect the whisker pullout process through the frictional sliding coefficients or the extent of mechanical interlocking of the interface due to the whisker surface topography.Composites containing ACMC silicon carbide whiskers (SiCw) which had been coated with 5-10 nm of carbon and Tokai whiskers coated with 2 nm of carbon have been examined. High resolution electron microscopy (HREM) images of the interface were obtained with a JEOL 4000EX electron microscope. The whisker geometry used for HREM imaging is described in Reference 2. High spatial resolution (< 2-nm-diameter probe) parallel-collection electron energy loss spectroscopy (PEELS) measurements were obtained with a Philips EM400T/FEG microscope equipped with a Gatan Model 666 spectrometer.


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