Mesoporous titania films with adjustable pore size coated on stainless steel substrates

2009 ◽  
Vol 44 (12) ◽  
pp. 2222-2227 ◽  
Author(s):  
Sergey Sokolov ◽  
Erik Ortel ◽  
Ralph Kraehnert
2003 ◽  
Vol 32 (1-3) ◽  
pp. 387-395 ◽  
Author(s):  
Mikihiro Nomura ◽  
Ben Meester ◽  
Joop Schoonman ◽  
Freek Kapteijn ◽  
Jacob A. Moulijn

Author(s):  
Thomas Coquil ◽  
Laurent Pilon ◽  
Christian Reitz ◽  
Torsten Brezesinski ◽  
Joseph E. Nemanick ◽  
...  

This paper reports the cross-plane thermal conductivity of amorphous and crystalline templated mesoporous titania thin films synthesized by evaporation-induced self-assembly. Both sol-gel and nanocrystal-based films were considered, with respective average porosities of 30% and 35%. The pore diameter ranged from 7 to 25 nm and film thickness from 60 to 370 nm while the average wall thickness varied from 3 to 25 nm. Nanocrystals in crystalline mesoporous films featured diameters between 9 and 13 nm. The thermal conductivity was measured at room temperature using the 3ω method. The experimental setup and the associated analysis were validated by comparing the thermal conductivity measurements with data reported in the literature for dense titania films with thickness ranging from 95 to 1000 nm. The cross-plane thermal conductivity of the amorphous mesoporous titania thin films did not show strong dependence on pore size, wall thickness, or film thickness. This can be attributed to the high atomic scale disorder of amorphous materials. Heat is thus mainly carried by localized non-propagating vibrational modes. The average thermal conductivity of the amorphous mesoporous titania films was identical to that of the nanocrystal-based films and equal to 0.37 W/m.K. Thermal conductivity of sol-gel crystalline mesoporous titania thin films was significantly larger than that of their amorphous counterparts. It also depended on the organic template used to make the films. The results indicated that the pore size was not an important factor. Instead thermal conductivity depended only on porosity, crystallinity, nanocrystal size and connectivity.


Materials ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 3657
Author(s):  
Alexander E. Wilson-Heid ◽  
Erik T. Furton ◽  
Allison M. Beese

This study investigates the disparate impact of internal pores on the fracture behavior of two metal alloys fabricated via laser powder bed fusion (L-PBF) additive manufacturing (AM)—316L stainless steel and Ti-6Al-4V. Data from mechanical tests over a range of stress states for dense samples and those with intentionally introduced penny-shaped pores of various diameters were used to contrast the combined impact of pore size and stress state on the fracture behavior of these two materials. The fracture data were used to calibrate and compare multiple fracture models (Mohr-Coulomb, Hosford-Coulomb, and maximum stress criteria), with results compared in equivalent stress (versus stress triaxiality and Lode angle) space, as well as in their conversions to equivalent strain space. For L-PBF 316L, the strain-based fracture models captured the stress state dependent failure behavior up to the largest pore size studied (2400 µm diameter, 16% cross-sectional area of gauge region), while for L-PBF Ti-6Al-4V, the stress-based fracture models better captured the change in failure behavior with pore size up to the largest pore size studied. This difference can be attributed to the relatively high ductility of 316L stainless steel, for which all samples underwent significant plastic deformation prior to failure, contrasted with the relatively low ductility of Ti-6Al-4V, for which, with increasing pore size, the displacement to failure was dominated by elastic deformation.


2005 ◽  
Vol 579 (2) ◽  
pp. 267-275 ◽  
Author(s):  
Katy J. McKenzie ◽  
Pauline M. King ◽  
Frank Marken ◽  
Catherine E. Gardner ◽  
Julie V. Macpherson

2011 ◽  
Vol 61 (2) ◽  
pp. 355-361 ◽  
Author(s):  
P. Karasiński ◽  
E. Gondek ◽  
S. Drewniak ◽  
I. V. Kityk

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