Preparation by the double extraction process with preliminary neutron irradiation of yttria or calcia stabilised cubic zirconium dioxide microspheres

l-3,4-dihydroxyphenylalanine (l-DOPA) is a medically relevant compound in Parkinson’s disease therapy. Several extraction methods of l-DOPA from beans, including velvet and faba beans, have been described in the literature. However, these methods require the use of strong acids, long extraction times, or complex downstream processing, which makes the extraction of l-DOPA expensive and energy-demanding, limiting its industrial application. In addition, the stability of l-DOPA during the extraction process is critical, further complicating the extraction of adequate amounts of this amino acid. This work is the first report on a simple, rapid, greener, and robust extraction method of l-DOPA. The developed method consists of a quick homogenization step followed by a double extraction with 0.2% v/v acetic acid for 20 min and was applied to faba bean at a ratio of 1:25 with respect to the extracting solvent. This study also investigated the stability of l-DOPA during extraction and thermal treatment. The proposed method demonstrated to be robust and extraordinarily efficient for numerous cultivars of faba bean, velvet bean, and food products containing faba beans.

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Voids in Irradiated Tungsten and Molybdenum

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100062865 ◽

1969 ◽

Vol 27 ◽

pp. 190-191

Author(s):

Robert C. Rau ◽

Robert L. Ladd

Keyword(s):

Melting Point ◽

Fast Neutron ◽

Neutron Irradiation ◽

Elevated Temperatures ◽

Irradiation Temperature ◽

The Body ◽

Face Centered Cubic ◽

Body Centered Cubic ◽

Cubic Metals ◽

Face Centered

Recent studies have shown the presence of voids in several face-centered cubic metals after neutron irradiation at elevated temperatures. These voids were found when the irradiation temperature was above 0.3 Tm where Tm is the absolute melting point, and were ascribed to the agglomeration of lattice vacancies resulting from fast neutron generated displacement cascades. The present paper reports the existence of similar voids in the body-centered cubic metals tungsten and molybdenum.

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Surface Films on Zircaloy-2 Samples Cracked in Neutral Aqueous NaCl by Stress Corrosion

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100070679 ◽

1973 ◽

Vol 31 ◽

pp. 46-47

Author(s):

R.A. Ploc

Keyword(s):

Electron Microscopy ◽

Transmission Electron Microscopy ◽

Film Thickness ◽

Stress Corrosion ◽

Zirconium Dioxide ◽

Surface Film ◽

Surface Films ◽

Continuous Layer ◽

Transmission Electron ◽

Product Film

Samples of low-nickel Zircaloy-2 (material MLI-788-see(1)), when anodically polarized in neutral 5 wt% NaCl solutions, were found to be susceptible to pitting and stress corrosion cracking. The SEM revealed that pitting of stressed samples was occurring below a 2000Å thick surface film which behaved differently from normal zirconium dioxide in that it did not display interference colours. Since the initial film thickness was approximately 65Å, attempts were made to examine the product film by transmission electron microscopy to deduce composition and how the corrosion environment could penetrate the continuous layer.

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Freeze-Etch Crystal-Like Structures in Membranous Glomerulosclerosis

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100063883 ◽

1969 ◽

Vol 27 ◽

pp. 394-395

Author(s):

Burton B. Silver

Keyword(s):

Electron Microscopy ◽

Light Microscopy ◽

Sodium Hypochlorite ◽

Kidney Tissue ◽

Extraction Process ◽

Donor Kidney ◽

Unknown Substance ◽

Etched Surface ◽

Standard Fixation ◽

Diseased Kidney

Tissue from a non-functional kidney affected with chronic membranous glomerulosclerosis was removed at time of trnasplantation. Recipient kidney tissue and donor kidney tissue were simultaneously fixed for electron microscopy. Primary fixation was in phosphate buffered gluteraldehyde followed by infiltration in 20 and then 40% glycerol. The tissues were frozen in liquid Freon and finally in liquid nitrogen. Fracturing and replication of the etched surface was carried out in a Denton freeze-etch device. The etched surface was coated with platinum followed by carbon. These replicas were cleaned in a 50% solution of sodium hypochlorite and mounted on 400 mesh copper grids. They were examined in an Siemens Elmiskop IA. The pictures suggested that the diseased kidney had heavy deposits of an unknown substance which might account for its inoperative state at the time of surgery. Such deposits were not as apparent in light microscopy or in the standard fixation methods used for EM. This might have been due to some extraction process which removed such granular material in the dehydration steps.

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Biorefinery implementation for recovery debottlenecking at existing pulp mills- Part II: Techno-economic evaluation

TAPPI Journal ◽

10.32964/tj11.8.17 ◽

2012 ◽

Vol 11 (8) ◽

pp. 17-24 ◽

Cited By ~ 1

Author(s):

HAKIM GHEZZAZ ◽

LUC PELLETIER ◽

PAUL R. STUART

Keyword(s):

Cost Estimation ◽

Process Model ◽

Black Liquor ◽

Pulp Mill ◽

Value Added ◽

Economic Assessment ◽

Extraction Process ◽

Estimation Methods ◽

Precipitation Process

The evaluation and process risk assessment of (a) lignin precipitation from black liquor, and (b) the near-neutral hemicellulose pre-extraction for recovery boiler debottlenecking in an existing pulp mill is presented in Part I of this paper, which was published in the July 2012 issue of TAPPI Journal. In Part II, the economic assessment of the two biorefinery process options is presented and interpreted. A mill process model was developed using WinGEMS software and used for calculating the mass and energy balances. Investment costs, operating costs, and profitability of the two biorefinery options have been calculated using standard cost estimation methods. The results show that the two biorefinery options are profitable for the case study mill and effective at process debottlenecking. The after-tax internal rate of return (IRR) of the lignin precipitation process option was estimated to be 95%, while that of the hemicellulose pre-extraction process option was 28%. Sensitivity analysis showed that the after tax-IRR of the lignin precipitation process remains higher than that of the hemicellulose pre-extraction process option, for all changes in the selected sensitivity parameters. If we consider the after-tax IRR, as well as capital cost, as selection criteria, the results show that for the case study mill, the lignin precipitation process is more promising than the near-neutral hemicellulose pre-extraction process. However, the comparison between the two biorefinery options should include long-term evaluation criteria. The potential of high value-added products that could be produced from lignin in the case of the lignin precipitation process, or from ethanol and acetic acid in the case of the hemicellulose pre-extraction process, should also be considered in the selection of the most promising process option.

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Effect of Fast Neutron Irradiation on AISI 316 Steel Tube

Journal of the Atomic Energy Society of Japan / Atomic Energy Society of Japan ◽

10.3327/jaesj.14.283 ◽

1972 ◽

Vol 14 (6) ◽

pp. 283-289

Author(s):

Satoru KAWASAKI ◽

Kiyoshi FUKAYA ◽

Ryukichi NAGASAKI

Keyword(s):

Fast Neutron ◽

Neutron Irradiation ◽

Steel Tube ◽

Fast Neutron Irradiation ◽

Aisi 316

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Evaluation of Resistant Starch Quality from Different Types of Banana in Batter Coating Formulation to Reduce Oil Absorption in Fried Food

ICONIET PROCEEDING ◽

10.33555/iconiet.v2i2.21 ◽

2019 ◽

Vol 2 (2) ◽

pp. 115-120

Author(s):

Karissha Fritzi Della ◽

Mutiara Pratiwi ◽

Purwa Tri Cahyana ◽

Maria DPT Gunawan-Puteri

Keyword(s):

Resistant Starch ◽

Extraction Process ◽

Fat Content ◽

Water Retention Capacity ◽

Oil Absorption ◽

Retention Capacity ◽

Fried Food ◽

Musa Paradisiaca ◽

Different Types ◽

Coating Formulation

Fried food is convenient for many people due to its pleasant texture and taste. On the other hand, it comes with the risk of high oil absorption which might lead to certain health problems. Resistant starch (RS) has been known to have a functionality of reducing oil absorption. Three different types of banana: Kepok (Musa paradisiaca formatypica), Raja Bulu (Musa paradisiaca L.) and Ambon (Musa paradisiaca L. var sapientum) were evaluated on its performance when utilized as source of resistant starch especially on their application in reducing oil absorption in fried food. Tempeh was used as the food model. Banana starch (RS2) was isolated through water alkaline extraction process, continued with modification process through three repeated cycles of autoclaving-cooling process to obtain the RS3. RS3 was added into the batter coating formulation at three substitution ratios (10%, 30% and 50%) and then used to coat tempeh before frying. Evaluation of resistant starch in batter and battered productwas conducted on the following parameters: fat content, water retention capacity (WRC), coating pick up and sensory analysis. The result of this study revealed that Raja Bulu showed the most effective result on reducing oil absorption in the food tested. In the three bananas used, the ratio of 50% performed best in coating pick up (highest), WRC (highest) and fat content(lowest) parameters, but not significantly different with the 30% ratio. In terms of sensory acceptance, using Raja Bulu as the selected banana type, 30% of substitution ratio was significantly more preferable by the panelists in crispness, oiliness, and overall acceptance attributes compared to control and other substitution ratios.

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