Long-term accelerated weathering of HAS stabilized PE and PP plaques: Compliance of ESRI, IR, and microhardness data characterizing heterogeneity of photooxidation

2015 ◽  
Vol 120 ◽  
pp. 114-121 ◽  
Author(s):  
J. Pilař ◽  
D. Michálková ◽  
M. Šlouf ◽  
T. Vacková
Author(s):  
Courtney Magill ◽  
Frank Matero

Beginning in the summer of 2015, research was conducted on protective wood coatings and accelerated weathering testing methods for architectural log and timber. A rack for supplementary natural weathering testing of hydrophobic and ultraviolet protective surface treatments for logs was also erected as a subsequent phase at Grand Teton National Park. This laboratory and field research is part of an ongoing project to develop an appropriate treatment for historic log structures in the region that will preserve their original fabric while maintaining the intended historic appearance of the buildings, i.e., unpainted. The weathering rack will be in place for upwards of five years to verify the lab-based results from Phase I and to determine the long-term durability of the chosen treatments on already aged materials in situ. This report addresses the methods and materials for preparation of the weathering rack and samples as well as the methods being used to monitor their progress and initial results. Readings will be taken yearly to monitor the effects of weathering on each treatment.


Author(s):  
Monika Remzova ◽  
Radek Zouzelka ◽  
Jaroslav Lukes ◽  
Jiri Rathousky

To achieve efficient and durable consolidation of weathered sandstone, the selection of a suitable consolidant is essential. To reasonably assess the suitability of different formulations, it is fundamental to compare their performance as a consolidant within a substrate, which reliably models the properties of deteriorated material. As a test substrate, the sandstone from quarries in Mšené in central Bohemia was selected, for its developed porosity and relatively low mechanical strength. To obtain relevant comparison of their application potential, both commercial (Remmers KSE OH and Surfapore) and self-developed consolidants were included. To test the long-term stability of each consolidant, the stone was subjected to accelerated weathering. The characterization of texture properties was based on the physical sorption of nitrogen and krypton, mercury intrusion porosimetry and water uptake. While the mechanical properties in microscale were determined by nanoindentation, the mechanical strength in macroscale before and after consolidation was measured by drilling resistance. Both commercial exhibited good mechanical performance with reasonable durability. The performance of our developed samples was comparable or, in some cases, superior. Very interesting were the consolidants containing TiO2 and ZnO nanoparticles, the former exhibiting comparable degree of consolidation and durability as commercial ones, with additional photocatalytic function, the latter unusually high increase in the mechanical strength, even after the weathering test. The diammonium hydrogen phosphate based consolidant showed exceptional durability in the weathering test, which makes it a promising product not only for carbonate but also sandstone materials.


2015 ◽  
Vol 77 (32) ◽  
Author(s):  
Syarifah Hanisah Syed Mokhtarruddin ◽  
Zakiah Ahmad ◽  
Rohana Hassan ◽  
Zaidon Ashaari

History of accelerated weathering testing as a tool to explain the nature of weathering with a faster outcome has been documented since the 1940s. There are various method applied as accelerated weathering testing, i.e., cyclic boil-dry test, automatic boil test and QUV instrument. One of the recently conducted worldwide in accelerated weathering testing was QUV accelerated weathering. QUV instrument gives information about how materials degrade to the extended exposure environment within a reasonable time frame. Furthermore, QUV instrument employs the wavelength simulating with real-life solar radiation. Thus, applications of accelerated weathering testing in timber industry really give fast response to manufacturer in improving their timber product for long term usage. The conceptual review has studied on the application of QUV instrument in the accelerated weathering testing since 1997 till 2014. Accelerated weathering testing as a simulation of natural weathering was used in determining the long-term serviceability of Malaysian tropical timber in the extended environmental exposure.


2020 ◽  
Vol 29 (1) ◽  
pp. 57-64
Author(s):  
Hasret Ece Sönmez ◽  
Mehmet Safa Bodur ◽  
Alper Adrian Baysan ◽  
Mustafa Bakkal ◽  
Ersin Serhatli

In this work, various stabilizers have been introduced to prevent or delay degradation due to ultraviolet (UV) light exposure to prolong the service life of cotton fiber-reinforced composites. The effect of various additives like hindered amine light stabilizer, UV absorber (UVA), and antioxidant as photostabilizers of CF/low-density polyethylene (CF/LDPE) composites was compared. We showed how they influence to delay or eliminate the photodegradation of CF/LDPE subjected accelerated weathering. Surface analysis was performed by Fourier transform infrared spectroscopy and color measurements. The results showed us the insight of the photodegradation mechanism of weathered CF/LDPE composites undergoing photooxidative reactions which causes a loss surface quality such as micro-cracking and color change. Among the stabilizers, UVA was found to be the most effective to delay some color changes in long term.


Polymers ◽  
2021 ◽  
Vol 13 (23) ◽  
pp. 4092
Author(s):  
Dionisis Semitekolos ◽  
Georgios Konstantopoulos ◽  
Aikaterini-Flora Trompeta ◽  
Craig Jones ◽  
Amit Rana ◽  
...  

The present study focuses on the effect of two novel carbon fibre surface treatments, electropolymerisation of methacrylic acid and air pressure plasma, on the mechanical properties and structural integrity of carbon-fibre-reinforced composites under operational conditions. Extensive mechanical testing was applied, both in nano- and macro-scale, to assess the performance of the composites and the interphase properties after ultraviolet/humidity weathering. The results of the mechanical assessment are supported by structure, surface, and chemistry examination in order to reveal the failure mechanism of the composites. Composites with the electropolymerisation treatment exhibited an increase of 11.8% in interlaminar shear strength, while APP treatment improved the property of 23.9%, rendering both surface treatments effective in increasing the fibre-matrix adhesion. Finally, it was proven that the developed composites can withstand operational conditions in the long term, rendering them suitable for a wide variety of structural and engineering applications.


2019 ◽  
Vol 70 (4) ◽  
pp. 383-390
Author(s):  
Ayhan Gençer ◽  
Ahmet Can ◽  
Aysun Mustak ◽  
Ülkü Burcu Gitti

Depending on the use of wood in the forest industry, wood bark is mostly peeled and used as fuel. The ash and smoke left from the burned bark causes environmental pollution. The most environmentally friendly method for waste disposal is to convert waste into a valuable commodity. In this study, cherry tree bark was used as a dyestuff in paper production. Wild cherry (Cerasus avium L.) bark was boiled with water and KOH. The purpose of using KOH is to increase the solubility of the bark compounds. The chemi-thermomechanical pulp (CTMP) was dyed using the dyestuff. The alum mordant is used to fi x the dyestuff. Paper can be exposed to external influences (mechanical, physical and biological) depending on the place of use. One of these effects is sunshine. When paper is exposed to direct or indirect sunlight, paper changes its color. Depending on the place of use, it is expected that the color of the paper will not be affected by the sunlight or that it will provide long-term strength after the application. Accelerated weathering test was chosen to measure the UV resistance of the dyestuff. The results have shown that the mordant has a significant effect on the fixation of dyestuff. After a total of 150 hours of weathering test, the color change was observed to be the lowest in the paper samples to which alum mordant was added to the dyestuff.


2008 ◽  
Vol 1107 ◽  
Author(s):  
Paulo H. R. Borges ◽  
Neil B. Milestone ◽  
Roger E. Streatfield

AbstractTrying to estimate the long-term durability of cemented wasteforms is a difficult task as the cement matrix is a reactive medium and interactions can occur with the encapsulated waste as well as with the environment. There are few studies of samples that have been stored under controlled conditions for more than 10-15 years. Wasteforms are now being expected to last hundreds of years, much of that likely to be in some form of storage where sample integrity is important. There is also the concern that results from any long-term samples may only be indicative as both formulations and materials change with time.This paper discusses changes in physical properties that occur in composite cements when some of the short-term accelerated procedures employed in construction testing are applied to encapsulating matrices. Changes after increased temperature of curing, wetting/drying and accelerated carbonation are discussed.Many of the encapsulating formulations currently used are composite cements where large replacement levels of OPC with supplementary cementing materials (SCMs) such as PFA or BFS are made, primarily to reduce heat output. Accelerating the exposure conditions, either by increasing temperature or through wetting/drying has the effect of changing the hydration pattern of the composite cement by generating more hydration in the SCMs than would normally occur. The large amount of porosity that occurs because of limited hydration allows intrusion of gases and ready movement of water, so the samples subjected to accelerated testing do not appear as durable as expected if stored at ambient.


2007 ◽  
Vol 130 (1) ◽  
Author(s):  
Gema San Vicente ◽  
Rocío Bayón ◽  
Angel Morales

Generally, single layer antireflective (AR) coatings are based on SiO2 for which the low refractive index is achieved by increasing the porosity of the films. On the other hand, the increase of porosity on any material results in a decrease of its mechanical properties. In addition to increasing the solar transmittance, it is equally important that the AR film is long-term stable for its application in solar collectors. In this sense, the objective of our work has been to develop a film that exhibits good AR properties and physical durability as well. In the present study, sol-gel silica films have been deposited on borosilicate glass. The effect of adding some organic compounds to the precursor solution in the properties of the films has been studied. Moreover, accelerated weathering tests have been performed in order to investigate the outdoor durability. A value of solar transmittance as high as 0.974 has been obtained by using a porosity promoter additive. However, the durability tests have shown the necessity of incorporating a hydrophobic additive to the precursor solutions in order to avoid the degradation of the optical properties of the films. 1.5% decrease in solar transmittance is observed after 1900h in the weathering chamber for films prepared with methyltriethoxysilane.


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