Down-conversion particles as internal UV-source assist in UV-curing systems: Physical and mechanical properties of UV-curable micro-composites

2018 ◽  
Vol 122 ◽  
pp. 263-269 ◽  
Author(s):  
Masoume Kaviani Darani ◽  
Saeed Bastani ◽  
Mehdi Ghahari ◽  
Pooneh Kardar ◽  
Ezeddin Mohajerani
Keyword(s):  
Mechanical Properties ◽  
Physical And Mechanical Properties ◽  
Uv Curing ◽  
Uv Curable ◽  
Down Conversion ◽  
Curing Systems

Preparation and Characterization of UV Curable Hybrid System Based on Free Radical and Cationic Mechanism

2013 ◽  
Vol 470 ◽  
pp. 141-145 ◽  
Author(s):  
Li Juan Zhang ◽  
Chen Bo Wu ◽  
Fei Yang ◽  
Xiao Yi Geng ◽  
Meng Qian Li ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Free Radical ◽  
Hybrid System ◽  
Epoxy Group ◽  
Physical And Mechanical Properties ◽  
Uv Curing ◽  
Decomposition Temperature ◽  
Scanning Calorimetry ◽  
Uv Curable ◽  
Low Viscosity

A UV curable hybrid system with a dual mechanism of radical and cationic photo-polymerization, was investigated. A kind of free radical oligomer with low viscosity named hexahydrophthalic acid diglycidyl acrylate was first synthesized. The structure of the oligomer was characterization by FTIR. The UV curing processing of hybrid system was traced by real-time FTIR, and compared with free radical, cationic system. Thermal decomposition temperature and glass transition temperature of UV curing film for various system were determined by thermogravimetric analysis (TGA) and differental scanning calorimetry (DSC), respectively. And physical and mechanical properties of those curing films were analyzed and compared. The results show that the radical polymerization of double bond and cationic polymerization of epoxy group could occur simultaneously in hybrid system. The conversion rate of epoxy group for hybrid system was higher than that of epoxy group for cationic system, which demonstrated that the cationic photo-initiator (DPI·PF6) can be sensitized by the free radical photo-initiator (Irgacure 184). Compared with free radical and cationic system, the hardness and mechanical properties of hybrid system curing film were better than those of the cationic system curing film, while closed to those of free radical system.

scholarly journals Cationic UV-Curing of Epoxidized Biobased Resins

Polymers ◽  
2020 ◽  
Vol 13 (1) ◽  
pp. 89
Author(s):  
Camilla Noè ◽  
Minna Hakkarainen ◽  
Marco Sangermano
Keyword(s):  
Mechanical Properties ◽  
Organic Compound ◽  
Epoxy Resins ◽  
Chemical Resistance ◽  
State Of The Art ◽  
Uv Curing ◽  
Building Blocks ◽  
Uv Curable ◽  
Curing Conditions ◽  
Volatile Organic

Epoxy resins are among the most important building blocks for fabrication of thermosets for many different applications thanks to their superior thermo-mechanical properties and chemical resistance. The recent concerns on the environmental problems and the progressive depletion of petroleum feedstocks have drawn the research interest in finding biobased alternatives. Many curing techniques can be used to obtain the final crosslinked thermoset networks. The UV-curing technology can be considered the most environmentally friendly because of the absence of volatile organic compound (VOC) emissions and mild curing conditions. This review provides an overview of the state of the art of bio-based cationic UV-curable epoxy resins. Particular focus has been given to the sources of the bio-based epoxy monomers and the applications of the obtained products.

scholarly journals Preparation and Performance of a Waterborne UV/Al Low Infrared Emissivity Coating

2020 ◽  
Vol 10 (18) ◽  
pp. 6423 ◽  
Author(s):  
Xiaoxing Yan ◽  
Lin Wang
Keyword(s):  
Mechanical Properties ◽  
Corrosion Resistance ◽  
Orthogonal Experiment ◽  
Uv Curing ◽  
Infrared Emissivity ◽  
Nano Silica ◽  
Uv Curable ◽  
Powder Concentration ◽  
Al Powder ◽  
Silica Slurry

An Al powder filler, nano silica slurry and KH560 were mixed with a prepared waterborne UV-curable coating, and the coating was optimized by an orthogonal experiment. Influences of the Al powder concentration on the gloss, infrared emissivity, brightness, mechanical properties, corrosion resistance and other related properties of the coating were further discussed. The results show that the influence of the Al powder concentration on the gloss was more significant, followed by the UV curing time and nano silica slurry concentration. After studying the key role of the concentration of the Al powder, we found that as the concentration of the Al powder is augmented from 10.0% to 25.0%, the gloss lessened from 19.1% to 8.5%. As the concentration of the Al powder was augmented from 10.0% to 40.0%, the infrared emissivity lessened from 0.649 to 0.083 and the brightness L’ value of the coating was step-by-step augmented and inclined to be stable; in addition, the coating’s mechanical properties reached an excellent level. The coating containing 25.0% Al powder had the best corrosion resistance, surface morphology and comprehensive properties, which can potentially be used for infrared stealth technology.

UV curable urethane acrylate coatings formulation: experimental design approach

2014 ◽  
Vol 43 (2) ◽  
pp. 61-68 ◽  
Author(s):  
Ghodsieh Mashouf ◽  
Morteza Ebrahimi ◽  
Saeed Bastani
Keyword(s):  
Mechanical Properties ◽  
Experimental Design ◽  
Physical And Mechanical Properties ◽  
Scratch Resistance ◽  
Urethane Acrylate ◽  
Uv Curable ◽  
Content Type ◽  
Mathematical Equations ◽  
Acrylate Monomers ◽  
Mixture Experimental Design

Purpose – The purpose of this work was to perform a systematic study on the effect of formulation on the physical and mechanical properties of ultaviolet (UV) curable urethane acrylate resins. In addition, the authors wanted to derive mathematical formula for the prediction of physical and mechanical properties for the aforementioned system. Design/methodology/approach – The experiments were carried out based on mixture experimental design to determine the effect of different multifunctional acrylates (i.e. 1,6-hexanediol diacrylate (HDDA), tripropylene glycol diacrylate (TPGDA), trimethyolpropane triactylate (TMPTA)) concentration on the physical and mechanical properties of a UV curable polyurethane acrylate system. The urethane oligomer was synthesized and characterized by the research team. Microhardness, adhesion strength and scratch resistance of the cured films were evaluated as the physical and mechanical properties. Findings – The results revealed that the resin and TMPTA concentrations had the most significant effects on the microhardness property. Adhesion strength of the films showed a linear trend with respect to all variables. Moreover, all components also had a significant and complex influence on the scratch resistance of the cured systems. In addition, mathematical equations proposed by mixture experimental design were derived for all the mentioned properties. Research limitations/implications – Other multifunctional acrylate monomers (i.e. more than three functional) can be used in the formulations. The kinetics of the curing can affect on the network formation and consequently on the properties of the cured films. Practical implications – The obtained results can be used by the researchers who are active in the field of structure-property relationship of polymers and surface coatings. The reported data and the mathematical equations can also be used for the formulating of an appropriate formulation based on a specific application. Originality/value – A systematic and statistical-based approach, i.e. mixture experimental design, was used to evaluate the effect of formulation on some of the properties of a UV curable polyurethane acrylate system. A urethane oligomer and three different multifunctional acrylate monomers as reactive diluents were used in the formulations. Noteworthy to mention that several mathematical models were derived by using analysis of variance for the prediction of the properties studied in this system.

PEMANFAATAN KAYU AKASIA MANGIUM (Acacia mangium Willd) UNTUK MEBEL

2012 ◽  
Vol 4 (1) ◽  
pp. 1
Author(s):  
Djoko Purwanto
Keyword(s):  
Mechanical Properties ◽  
Compressive Strength ◽  
Physical Properties ◽  
Treatment Process ◽  
Acacia Mangium ◽  
Physical And Mechanical Properties ◽  
Wood Fibers ◽  
Test Parameters ◽  
Mechanical And Physical Properties ◽  
Scale Scores

Timber Acacia mangium (Acacia mangium, Willd) for Furniture. The study aims to determine the mechanical and physical properties and the decorative value (color and fiber) wood of acacia mangium with using finishing materials. This type of finishing material used is ultran lasur natural dof ,ultran lasur classic teak, aqua politur clear dof, aqua politur akasia dan aqua politur cherry. After finishing the wood is stored for 3 months. Test parameters were observed, namely, physical and mechanical properties of wood, adhesion of finishing materials, color and appearance of the fiber, and timber dimensions expansion. The results showed that the mechanical physical properties of acacia wood qualified SNI. 01-0608-89 about the physical and mechanical properties of wood for furniture, air dry the moisture content from 13.78 to 14.89%, flexural strength from 509.25 to 680.50 kg/cm2, and compressive strength parallel to fiber 342.1 - 412.9 kg/cm2. Finishing the treatment process using five types of finishing materials can increase the decorative value (color and fiber) wood. Before finishing the process of acacia mangium wood has the appearance of colors and fibers and less attractive (scale scores 2-3), after finishing acacia wood fibers have the appearance of colors and interesting and very interesting (scale 4-5).Keywords: mangium wood, mechanical properties, decorative value, finishing, furniture.

Physical and Mechanical Properties of Tenun Pahang Fabrics using Alternative Yarns

2016 ◽  
Vol 13 (2) ◽  
pp. 67
Author(s):  
Engku Liyana Zafirah Engku Mohd Suhaimi ◽  
Jamil Salleh ◽  
Suzaini Abd Ghani ◽  
Mohamad Faizul Yahya ◽  
Mohd Rozi Ahmad
Keyword(s):  
Mechanical Properties ◽  
Physical And Mechanical Properties ◽  
The Other ◽  
Silk Fabrics ◽  
Recovery Angle ◽  
Made In

An investigation on the properties of Tenun Pahang fabric performances using alternative yarns was conducted. The studies were made in order to evaluate whether the Tenun Pahang fabric could be produced economically and at the same time maintain the fabric quality. Traditional Tenun Pahang fabric uses silk for both warp and weft. For this project, two alternative yarns were used which were bamboo and modal, which were a little lower in cost compared to silk. These yarns were woven with two variations, one with the yarns as weft only while maintaining the silk warp and the other with both warp and weft using the alternative yarns. Four (4) physical testings and three (3) mechanical testings conducted on the fabric samples. The fabric samples were evaluated including weight, thickness, thread density, crease recovery angle, stiffness and drapability. The results show that modal/silk and bamboo silk fabrics are comparable in terms of stiffness and drapability, hence they have the potential to replace 100% silk Tenun Pahang.

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