UV curable urethane acrylate coatings formulation: experimental design approach

2014 ◽  
Vol 43 (2) ◽  
pp. 61-68 ◽  
Author(s):  
Ghodsieh Mashouf ◽  
Morteza Ebrahimi ◽  
Saeed Bastani
Keyword(s):  
Mechanical Properties ◽  
Experimental Design ◽  
Physical And Mechanical Properties ◽  
Scratch Resistance ◽  
Urethane Acrylate ◽  
Uv Curable ◽  
Content Type ◽  
Mathematical Equations ◽  
Acrylate Monomers ◽  
Mixture Experimental Design

Purpose – The purpose of this work was to perform a systematic study on the effect of formulation on the physical and mechanical properties of ultaviolet (UV) curable urethane acrylate resins. In addition, the authors wanted to derive mathematical formula for the prediction of physical and mechanical properties for the aforementioned system. Design/methodology/approach – The experiments were carried out based on mixture experimental design to determine the effect of different multifunctional acrylates (i.e. 1,6-hexanediol diacrylate (HDDA), tripropylene glycol diacrylate (TPGDA), trimethyolpropane triactylate (TMPTA)) concentration on the physical and mechanical properties of a UV curable polyurethane acrylate system. The urethane oligomer was synthesized and characterized by the research team. Microhardness, adhesion strength and scratch resistance of the cured films were evaluated as the physical and mechanical properties. Findings – The results revealed that the resin and TMPTA concentrations had the most significant effects on the microhardness property. Adhesion strength of the films showed a linear trend with respect to all variables. Moreover, all components also had a significant and complex influence on the scratch resistance of the cured systems. In addition, mathematical equations proposed by mixture experimental design were derived for all the mentioned properties. Research limitations/implications – Other multifunctional acrylate monomers (i.e. more than three functional) can be used in the formulations. The kinetics of the curing can affect on the network formation and consequently on the properties of the cured films. Practical implications – The obtained results can be used by the researchers who are active in the field of structure-property relationship of polymers and surface coatings. The reported data and the mathematical equations can also be used for the formulating of an appropriate formulation based on a specific application. Originality/value – A systematic and statistical-based approach, i.e. mixture experimental design, was used to evaluate the effect of formulation on some of the properties of a UV curable polyurethane acrylate system. A urethane oligomer and three different multifunctional acrylate monomers as reactive diluents were used in the formulations. Noteworthy to mention that several mathematical models were derived by using analysis of variance for the prediction of the properties studied in this system.

Curing behaviour and mechanical properties of pigmented UV-curable epoxy acrylate coatings

2014 ◽  
Vol 43 (4) ◽  
pp. 177-184 ◽  
Author(s):  
Pooneh Kardar ◽  
Morteza Ebrahimi ◽  
Saeed Bastani
Keyword(s):  
Mechanical Properties ◽  
Titanium Dioxide ◽  
Chemical Structure ◽  
Epoxy Acrylate ◽  
Acrylate Monomer ◽  
Uv Curable ◽  
Content Type ◽  
Reactive Diluents ◽  
Acrylate Monomers ◽  
And Storage

Purpose – The purpose of this work was to study the effect of chemical structure of reactive diluents on the curing behaviour and physical–mechanical properties of a titanium dioxide pigmented UV-curable epoxy acrylate system. Design/methodology/approach – Two different tri-functional and two different tetra-functional acrylate monomers were used as reactive diluents in the formulations. The curing behaviour of the formulations was studied by using photo-differential scanning calorimetry analysis. The rate of curing, conversion at the maximum rate and ultimate conversion for different formulations were calculated. In addition, the physical and mechanical characteristics of the cured films, including glass transition temperature and modulus, were measured by using a dynamic mechanical analysis technique. Findings – The results showed that the ultimate conversion for non-pigmented pentaerythritol triacrylate (PETA) and trimethylol propane triacrylate (TMPTA) formulations were almost similar, but the interference effect of titanium dioxide particles on the curing of the PETA formulations was found to be more considerable in comparison to the TMPTA formulations. The extent of reaction for tetra-functional acrylate monomers was considerably less than those for tri-functional acrylate monomers. The Tg and storage modulus of non-pigmented PETA, TMPTA and pentaerythritol tetraacrylate (PE4TA) formulations were almost the same and higher than that for ditrimethylol propane tetraacrylate (DiTMP4TA) formulations. However, Tg and storage modulus of pigmented tetra-functional acrylate monomer formulations were higher than those for tri-acrylate monomer formulations. Research limitations/implications – The curing conditions (temperature and UV intensity) can affect the network formation and consequently will affect on the properties of the cured films. Practical implications – The pigmented UV-curable coatings are interested for many industries such as wood and automotive industries. The reported data can be used by the formulators working in the R&D departments. In addition, the results obtained can be used by the researchers who are active in the field of structure–property relationship for UV-curable coatings. Social implications – UV-curing systems are considered as one of the most environment-friendly coatings system. Therefore, the developing of its knowledge can help to extend its usage to different applications. Originality/value – The photopolymerisation of pigmented coatings is a great challenge and is hardly investigated in the literature. Therefore, in this research, the effect of chemical structure and functionality of different multifunctional acrylate monomers on the curing behaviour of pigmented formulations was investigated.

scholarly journals Sialon and Alumina Modified UV-Curable Coatings with Improved Mechanical Properties and Hydrophobicity

Coatings ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 1424
Author(s):  
Mariola Robakowska ◽  
Łukasz Gierz ◽  
Hubert Gojzewski
Keyword(s):  
Mechanical Properties ◽  
Contact Angle ◽  
Inorganic Compounds ◽  
Surface Hydrophobicity ◽  
Scratch Resistance ◽  
Aluminum Oxynitride ◽  
Uv Curable ◽  
Scratch Hardness ◽  
Coating Surface ◽  
Inorganic Fillers

This article describes the modification of UV-curable coatings with silicon aluminum oxynitride (Sialon) and aluminum oxide (Alu C), which improve the hydrophobicity of the coating surface and the scratch hardness. The contact angle is greater due to surface roughness being enhanced with inorganic fillers. Improved scratch resistance results from the formation of a sliding layer triggered by the diffusion of Sialon or alumina on the coating surface. One can observed an increase in the surface hydrophobicity as well as in the scratch hardness (up to 100%) when small amounts (5 wt.%) of the inorganic compounds are added. Imaging microscopies, i.e., SEM, OM, and AFM (with nanoscopic Young’s modulus determination), revealed the good distribution of both types of fillers in the studied matrix.

Graphene oxide/epoxy acrylate nanocomposite production via SLA and importance of graphene oxide surface modification for mechanical properties

2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Emrah Uysal ◽  
Mustafa Çakir ◽  
Bülent Ekici
Keyword(s):  
Mechanical Properties ◽  
Surface Modification ◽  
Graphene Oxide ◽  
Three Dimensional ◽  
Oxide Nanoparticles ◽  
Epoxy Acrylate ◽  
Uv Curable ◽  
Content Type ◽  
Modified Graphene Oxide ◽  
Modified Graphene

Purpose Traditional nanocomposite production methods such as in situ polymerization, melt blending and solvent technique, have some deficits. Some of these are non-homogeneous particle distribution, setup difficulties, time-consuming and costly. On the other hand, three-dimensional printing technology is a quite popular method. Especially, Stereolithography (SLA) printing offers some benefits such as fast printing, easy setup and smooth surface specialties. Furthermore, surface modification of Graphene Oxide (GO) and its effects on polymer nanocomposites are quite important. The purpose of this study is to examine the effect of surface modification of GO nanoparticles on the mechanical properties and morphology of epoxy acrylate (BisGMA/1,6 hexane diol diacrylate) matrix nanocomposites. Design/methodology/approach In this study, Ultraviolet (UV) curable end groups of synthesized resin were linked to functional groups of graphene oxide, which are synthesized by the Tour method, which is a kind of modified Hummer method. In addition, synthesized GO nanoparticle’s surfaces were modified by 3-(methacryloyloxy) propyl trimethoxysilane. Significant weight percentages of GO were added into the epoxy acrylate resin. Different Wt.% of modified graphene oxide/acrylate resins was used to print test specimens with SLA type three-dimensional printer. Findings Surface modification has a significant effect on tensile strength for graphene oxide nanoparticles contained composites. In addition, a specific trend was not observed for tensile test results of non-modified graphene oxide. The tendency of impact and hardness test finding were similar for both surfaces modified and non-modified nanoparticles. Finally, the distribution of particles was homogeneous. Originality/value This paper is unique because of the inclusion of both surface modifications of graphene oxide nanoparticles and SLA production of nanocomposites with its own production of three-dimensional printer and photocurable polymer resin.

Study on properties of decolorizing yakwool fiber and spun yarn

2019 ◽  
Vol 31 (1) ◽  
pp. 90-102
Author(s):  
Qin Xiaoxuan ◽  
Hui’e Liang ◽  
Xuzhong Su ◽  
Xinjin Liu
Keyword(s):  
Mechanical Properties ◽  
Design Methodology ◽  
Natural Fiber ◽  
Physical And Mechanical Properties ◽  
Optimal Process ◽  
Textile Processing ◽  
Content Type ◽  
Oxidation Reduction ◽  
Spun Yarn

Purpose As a natural fiber, yakwool has attracted much attention in textile processing due to its excellent properties and wearabilities. However, the main colors of yakwool are black and brown. Therefore, for extending the application scopes of the fiber, the decolorization of the yakwool fiber is usually needed, especially for the black fiber. The paper aims to discuss this issue. Design/methodology/approach In the paper, the properties of the yakwool fiber were tested first, especially the melanin granules in the fiber. Then, the decolorization of the yakwool fiber was studied using the oxidation–reduction decolorization method, and corresponding optimal process of the decolorization was given. Then, the properties of the decolorized yakwool fiber were tested and compared with those of the original fiber. Findings It is shown that, after decolorization, the physical and mechanical properties of the fiber were deteriorated, especially in terms of the strength and elongation. Therefore, the fiber became shorter and thinner, and the scales were damaged. When compared with the yarn spun from the original yakwool fiber, it was observed that the properties of the yarn spun from the decolorized yakwool fiber deteriorated because of the deterioration in the properties of the original fiber. Originality/value In the paper, for extending the application scopes of the yakwool fiber, the decolorization of the yakwool fiber was studied.

The potential of metal epoxy composite (MEC) as hybrid mold inserts in rapid tooling application: a review

2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Radhwan Bin Hussin ◽  
Safian Bin Sharif ◽  
Shayfull Zamree Bin Abd Rahim ◽  
Mohd Azlan Bin Suhaimi ◽  
Mohd Tanwyn Bin Mohd Khushairi ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Epoxy Composite ◽  
Mold Insert ◽  
Physical And Mechanical Properties ◽  
Rapid Tooling ◽  
Current Application ◽  
Content Type ◽  
Manufacturing Technologies ◽  
New Formulation ◽  
Research Studies

Purpose Rapid tooling (RT) integrated with additive manufacturing technologies have been implemented in various sectors of the RT industry in recent years with various kinds of prototype applications, especially in the development of new products. The purpose of this study is to analyze the current application trends of RT techniques in producing hybrid mold inserts. Design/methodology/approach The direct and indirect RT techniques discussed in this paper are aimed at developing a hybrid mold insert using metal epoxy composite (MEC) in increasing the speed of tooling development and performance. An extensive review of the suitable development approach of hybrid mold inserts, material preparation and filler effect on physical and mechanical properties has been conducted. Findings Latest research studies indicate that it is possible to develop a hybrid material through the combination of different shapes/sizes of filler particles and it is expected to improve the compressive strength, thermal conductivity and consequently increasing the hybrid mold performance (cooling time and a number of molding cycles). Research limitations/implications The number of research studies on RT for hybrid mold inserts is still lacking as compared to research studies on conventional manufacturing technology. One of the significant limitations is on the ways to improve physical and mechanical properties due to the limited type, size and shape of materials that are currently available. Originality/value This review presents the related information and highlights the current gaps related to this field of study. In addition, it appraises the new formulation of MEC materials for the hybrid mold inserts in injection molding application and RT for non-metal products.

Preparation and Characterization of UV Curable Hybrid System Based on Free Radical and Cationic Mechanism

2013 ◽  
Vol 470 ◽  
pp. 141-145 ◽  
Author(s):  
Li Juan Zhang ◽  
Chen Bo Wu ◽  
Fei Yang ◽  
Xiao Yi Geng ◽  
Meng Qian Li ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Free Radical ◽  
Hybrid System ◽  
Epoxy Group ◽  
Physical And Mechanical Properties ◽  
Uv Curing ◽  
Decomposition Temperature ◽  
Scanning Calorimetry ◽  
Uv Curable ◽  
Low Viscosity

A UV curable hybrid system with a dual mechanism of radical and cationic photo-polymerization, was investigated. A kind of free radical oligomer with low viscosity named hexahydrophthalic acid diglycidyl acrylate was first synthesized. The structure of the oligomer was characterization by FTIR. The UV curing processing of hybrid system was traced by real-time FTIR, and compared with free radical, cationic system. Thermal decomposition temperature and glass transition temperature of UV curing film for various system were determined by thermogravimetric analysis (TGA) and differental scanning calorimetry (DSC), respectively. And physical and mechanical properties of those curing films were analyzed and compared. The results show that the radical polymerization of double bond and cationic polymerization of epoxy group could occur simultaneously in hybrid system. The conversion rate of epoxy group for hybrid system was higher than that of epoxy group for cationic system, which demonstrated that the cationic photo-initiator (DPI·PF6) can be sensitized by the free radical photo-initiator (Irgacure 184). Compared with free radical and cationic system, the hardness and mechanical properties of hybrid system curing film were better than those of the cationic system curing film, while closed to those of free radical system.

Effect of using Trilobal® polyester on the functional performance of fencing suit

2020 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Mohamed A. Saad ◽  
Fatma Metwaly ◽  
Sarah Yahia Gad ◽  
Khaled Mansour Mansour ◽  
Marwa A. Ali
Keyword(s):  
Mechanical Properties ◽  
Functional Performance ◽  
Physical And Mechanical Properties ◽  
Test Analysis ◽  
Content Type ◽  
Weave Structure ◽  
Vertical Wicking ◽  
Long Time ◽  
Density Factor ◽  
Face Structure

Purpose The paper aims to use the Trilobal® polyester (Y cross-section) for producing fabrics suitable for fencing suits and evaluating their various properties. Design/methodology/approach Double weave structure was chosen to produce the samples by using six different face structures and two back structures divided into two groups according to the back structures. They were evaluated by their physical and mechanical properties such as tensile strength, puncture resistance, air permeability and humidity properties in horizontal and vertical wicking, drying rate and water vapor transmission. Findings Fencing sport recently is one of the most growing sports in the world, which necessitates special requirements and properties of fencing suit, either mechanical properties, which allow the easily and freely movement for the athlete, or the comfort properties that save the player’s effort and energy for a long time to improve his performance. Originality/value ANOVA test analysis showed highly significant results in some properties comparing back and face structures of the double weave fabric high correlation coefficient were found between packing density factor of produced fabric and the weft material types. The final results showed the produced sample that weaved with plain 1/1 for back structure and warp rib 2/2 for face structure achieved the best results, followed by the produced sample weaved with plain 1/1 for back structure and weft rib 2/2 for face structure compared with the other produced samples.

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