Effect of large-scale kelp and bivalve farming on seawater carbonate system variations in the semi-enclosed Sanggou Bay

The Faxe limestone quarry in eastern Denmark exposes Danian (Lower Paleocene) cool-water carbonate deposits. They constitute remnants of an apparent build-up that covers about 12 km2 today. The Danian deposits at Faxe are conspicuous due to their pronounced thickness of coral limestone relative to the regional carbonate system. In the Faxe quarry, scleractinian corals are uniquely exposed in up to 30 m high mounds. The rapid accumulation of scleractinians combined with induration of the mounds may locally have protected the limestone from Quaternary glacial erosion and created a Danian thickness anomaly at Faxe. The position of Faxe above a local fault-bounded basement high and the extent of coral limestone has been better defined by new mapping. A mapped lithostratigraphic surface in the quarry reveals the large-scale organisation of nested bryozoan mounds on three elongated ridges striking NW–SE. The main scleractinian coral mounds are located above this horizon. Data for reservoir characterisation, mainly of the bryozoan mounds, were collected as photographs of the outcrop, petrophysical and petrographical data from cored boreholes, and as ground-penetrating radar sections. Old boreholes and measured sections were used to reconstruct the build-up, and new nannofossil data allow a discussion of stratigraphy and accumulation rate. The petrophysical data show that common mound-building bryozoan packstone has higher permeability and lower capillary entry pressure than chalk, whereas less commonly occurring grain-dominated packstone and grainstone deposits from local higher-energy sites of the mound complex were found to have reduced amounts of coccolith mud, significantly higher permeability and a higher degree of lithification. Based on biostratigraphic age constraints, correlation of flint – limestone couplets and recog-nised hierarchical patterns, we develop a cyclostratigraphy for the middle Danian and suggest that cyclicity in lithology and petrophysical characteristics of bryozoan limestone are controlled by precession and eccentricity of the orbit of the Earth.

Download Full-text

Ocean acidification over the next three centuries using a simple global climate carbon-cycle model: projections and sensitivities

Biogeosciences ◽

10.5194/bg-13-4329-2016 ◽

2016 ◽

Vol 13 (15) ◽

pp. 4329-4342 ◽

Cited By ~ 27

Author(s):

Corinne A. Hartin ◽

Benjamin Bond-Lamberty ◽

Pralit Patel ◽

Anupriya Mundra

Keyword(s):

Ocean Acidification ◽

Ocean Circulation ◽

Large Scale ◽

Sensitivity Analyses ◽

Reduced Form ◽

Cmip5 Models ◽

Cmip5 Model ◽

Low Latitude ◽

Carbonate System ◽

Carbon Cycle Model

Abstract. Continued oceanic uptake of anthropogenic CO2 is projected to significantly alter the chemistry of the upper oceans over the next three centuries, with potentially serious consequences for marine ecosystems. Relatively few models have the capability to make projections of ocean acidification, limiting our ability to assess the impacts and probabilities of ocean changes. In this study we examine the ability of Hector v1.1, a reduced-form global model, to project changes in the upper ocean carbonate system over the next three centuries, and quantify the model's sensitivity to parametric inputs. Hector is run under prescribed emission pathways from the Representative Concentration Pathways (RCPs) and compared to both observations and a suite of Coupled Model Intercomparison (CMIP5) model outputs. Current observations confirm that ocean acidification is already taking place, and CMIP5 models project significant changes occurring to 2300. Hector is consistent with the observational record within both the high- (> 55°) and low-latitude oceans (< 55°). The model projects low-latitude surface ocean pH to decrease from preindustrial levels of 8.17 to 7.77 in 2100, and to 7.50 in 2300; aragonite saturation levels (ΩAr) decrease from 4.1 units to 2.2 in 2100 and 1.4 in 2300 under RCP 8.5. These magnitudes and trends of ocean acidification within Hector are largely consistent with the CMIP5 model outputs, although we identify some small biases within Hector's carbonate system. Of the parameters tested, changes in [H+] are most sensitive to parameters that directly affect atmospheric CO2 concentrations – Q10 (terrestrial respiration temperature response) as well as changes in ocean circulation, while changes in ΩAr saturation levels are sensitive to changes in ocean salinity and Q10. We conclude that Hector is a robust tool well suited for rapid ocean acidification projections and sensitivity analyses, and it is capable of emulating both current observations and large-scale climate models under multiple emission pathways.

Download Full-text

GEOSECS Atlantic Radiocarbon

Radiocarbon ◽

10.1017/s0033822200004690 ◽

1980 ◽

Vol 22 (1) ◽

pp. 1-24 ◽

Cited By ~ 136

Author(s):

Minze Stuiver ◽

H G Östlund

Keyword(s):

Large Scale ◽

Chemical Constituents ◽

Carbonate System ◽

Mixing Processes ◽

Chemical Changes ◽

Baseline Study ◽

Section Study ◽

The World ◽

Transport And Mixing ◽

Oceanic Transport

The program called Geochemical Ocean Section Study (GEOSECS) was initiated in 1971 and designed to make an oceanic inventory of chemical constituents in the world oceans, partly as a baseline study for future chemical changes, and partly to investigate large-scale oceanic transport and mixing processes. Measured were hydrographic parameters (salinity, temperature, and oxygen vs depth), the carbonate system, the nutrients, and assorted other constituents with heavy emphasis laid on the radioactive substances, radiocarbon, tritium, and radon.

Download Full-text

Projections of ocean acidification over the next three centuries using a simple global climate carbon-cycle model

Biogeosciences Discussions ◽

10.5194/bgd-12-19269-2015 ◽

2015 ◽

Vol 12 (23) ◽

pp. 19269-19305 ◽

Cited By ~ 1

Author(s):

C. A. Hartin ◽

B. Bond-Lamberty ◽

P. Patel ◽

A. Mundra

Keyword(s):

Ocean Acidification ◽

Large Scale ◽

Reduced Form ◽

Cmip5 Models ◽

Earth System ◽

Carbonate System ◽

Form Model ◽

Reduced Form Model ◽

Ph Decrease ◽

Earth System Models

Abstract. Continued oceanic uptake of anthropogenic CO2 is projected to significantly alter the chemistry of the upper oceans, potentially having serious consequences for the marine ecosystems. Projections of ocean acidification are primarily determined from prescribed emission pathways within large scale earth system models. Rather than running the cumbersome earth system models, we can use a reduced-form model to quickly emulate the CMIP5 models for projection studies under arbitrary emission pathways and for uncertainty analyses of the marine carbonate system. In this study we highlight the capability of Hector v1.1, a reduced-form model, to project changes in the upper ocean carbonate system over the next three centuries. Hector is run under historical emissions and a high emissions scenario (Representative Concentration Pathway 8.5), comparing its output to observations and CMIP5 models that contain ocean biogeochemical cycles. Ocean acidification changes are already taking place, with significant changes projected to occur over the next 300 years. We project a low latitude (> 55°) surface ocean pH decrease from preindustrial conditions by 0.4 units to 7.77 at 2100, and an additional 0.27 units to 7.50 at 2300. Aragonite saturations decrease by 1.85 units to 2.21 at 2100 and an additional 0.80 units to 1.42 at 2300. Under a high emissions scenario, for every 1 °C of future warming we find a 0.107 unit pH decrease and a 0.438 unit decrease in aragonite saturations. Hector reproduces the global historical trends, and future projections with equivalent rates of change over time compared to observations and CMIP5 models. Hector is a robust tool that can be used for quick ocean acidification projections, accurately emulating large scale climate models under multiple emission pathways.

Download Full-text

Some comments about observations and image processing of comet 29P/Schwassmann-Wachmann 1

International Astronomical Union Colloquium ◽

10.1017/s0252921100031493 ◽

1999 ◽

Vol 173 ◽

pp. 243-248

Author(s):

D. Kubáček ◽

A. Galád ◽

A. Pravda

Keyword(s):

Image Processing ◽

Large Scale ◽

Harvard College ◽

Oak Ridge ◽

Large Scale Structures ◽

Short Period Comet ◽

Short Period ◽

Scale Structures ◽

Harvard College Observatory ◽

Period Comet

AbstractUnusual short-period comet 29P/Schwassmann-Wachmann 1 inspired many observers to explain its unpredictable outbursts. In this paper large scale structures and features from the inner part of the coma in time periods around outbursts are studied. CCD images were taken at Whipple Observatory, Mt. Hopkins, in 1989 and at Astronomical Observatory, Modra, from 1995 to 1998. Photographic plates of the comet were taken at Harvard College Observatory, Oak Ridge, from 1974 to 1982. The latter were digitized at first to apply the same techniques of image processing for optimizing the visibility of features in the coma during outbursts. Outbursts and coma structures show various shapes.

Download Full-text

Evolution of Large-Scale Coronal Structures

International Astronomical Union Colloquium ◽

10.1017/s0252921100024945 ◽

1994 ◽

Vol 144 ◽

pp. 29-33

Author(s):

P. Ambrož

Keyword(s):

Magnetic Field ◽

Field Line ◽

Large Scale ◽

Coronal Magnetic Field ◽

Source Surface ◽

Solar Cycles ◽

Characteristic Relationship ◽

The Magnetic Field ◽

Coronal Structures

AbstractThe large-scale coronal structures observed during the sporadically visible solar eclipses were compared with the numerically extrapolated field-line structures of coronal magnetic field. A characteristic relationship between the observed structures of coronal plasma and the magnetic field line configurations was determined. The long-term evolution of large scale coronal structures inferred from photospheric magnetic observations in the course of 11- and 22-year solar cycles is described.Some known parameters, such as the source surface radius, or coronal rotation rate are discussed and actually interpreted. A relation between the large-scale photospheric magnetic field evolution and the coronal structure rearrangement is demonstrated.

Download Full-text

Large-scale Motion of Solar Filaments

International Astronomical Union Colloquium ◽

10.1017/s0252921100064502 ◽

2000 ◽

Vol 179 ◽

pp. 205-208

Author(s):

Pavel Ambrož ◽

Alfred Schroll

Keyword(s):

Magnetic Flux ◽

Proper Motion ◽

Time Scale ◽

Large Scale ◽

Accuracy Of Measurements ◽

Solar Filaments ◽

General Movement ◽

Scale Motion ◽

Velocity Scatter

AbstractPrecise measurements of heliographic position of solar filaments were used for determination of the proper motion of solar filaments on the time-scale of days. The filaments have a tendency to make a shaking or waving of the external structure and to make a general movement of whole filament body, coinciding with the transport of the magnetic flux in the photosphere. The velocity scatter of individual measured points is about one order higher than the accuracy of measurements.

Download Full-text

Some applications of electron beam microanalysis techniques in VLSI process evaluation

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s042482010007463x ◽

1983 ◽

Vol 41 ◽

pp. 160-161

Author(s):

Simon Thomas

Keyword(s):

Integrated Circuits ◽

Process Evaluation ◽

Large Scale ◽

Technology Development ◽

Analytical Techniques ◽

Successful Implementation ◽

Analysis Of Failures ◽

Characterization Of Materials ◽

Circuits Vlsi

Trends in the technology development of very large scale integrated circuits (VLSI) have been in the direction of higher density of components with smaller dimensions. The scaling down of device dimensions has been not only laterally but also in depth. Such efforts in miniaturization bring with them new developments in materials and processing. Successful implementation of these efforts is, to a large extent, dependent on the proper understanding of the material properties, process technologies and reliability issues, through adequate analytical studies. The analytical instrumentation technology has, fortunately, kept pace with the basic requirements of devices with lateral dimensions in the micron/ submicron range and depths of the order of nonometers. Often, newer analytical techniques have emerged or the more conventional techniques have been adapted to meet the more stringent requirements. As such, a variety of analytical techniques are available today to aid an analyst in the efforts of VLSI process evaluation. Generally such analytical efforts are divided into the characterization of materials, evaluation of processing steps and the analysis of failures.

Download Full-text

Electron microscopy study of reactively sputter-deposited Ti/N films on silicon

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100131449 ◽

1992 ◽

Vol 50 (2) ◽

pp. 1362-1363

Author(s):

V. C. Kannan ◽

A. K. Singh ◽

R. B. Irwin ◽

S. Chittipeddi ◽

F. D. Nkansah ◽

...

Keyword(s):

Integrated Circuits ◽

Large Scale ◽

Hexagonal Phase ◽

Microscopy Study ◽

Electron Microscopy Study ◽

Process Conditions ◽

Tin Films ◽

Wide Range ◽

Fcc Phase ◽

Circuits Vlsi

Titanium nitride (TiN) films have historically been used as diffusion barrier between silicon and aluminum, as an adhesion layer for tungsten deposition and as an interconnect material etc. Recently, the role of TiN films as contact barriers in very large scale silicon integrated circuits (VLSI) has been extensively studied. TiN films have resistivities on the order of 20μ Ω-cm which is much lower than that of titanium (nearly 66μ Ω-cm). Deposited TiN films show resistivities which vary from 20 to 100μ Ω-cm depending upon the type of deposition and process conditions. TiNx is known to have a NaCl type crystal structure for a wide range of compositions. Change in color from metallic luster to gold reflects the stabilization of the TiNx (FCC) phase over the close packed Ti(N) hexagonal phase. It was found that TiN (1:1) ideal composition with the FCC (NaCl-type) structure gives the best electrical property.

Download Full-text