P-type Co3O4 nanoarrays decorated on the surface of n-type flower-like WO3 nanosheets for high-performance gas sensing

2019 ◽  
Vol 288 ◽  
pp. 104-112 ◽  
Author(s):  
Yanghai Gui ◽  
Lele Yang ◽  
Kuan Tian ◽  
Hongzhong Zhang ◽  
Shaoming Fang
Sensors ◽  
2019 ◽  
Vol 20 (1) ◽  
pp. 149 ◽  
Author(s):  
Weiyu Zhang ◽  
Shuai Cao ◽  
Zhaofeng Wu ◽  
Min Zhang ◽  
Yali Cao ◽  
...  

Inspired by the enhanced gas-sensing performance by the one-dimensional hierarchical structure, one-dimensional hierarchical polyaniline/multi-walled carbon nanotubes (PANI/CNT) fibers were prepared. Interestingly, the simple heating changed the sensing characteristics of PANI from p-type to n-type and n-type PANI and p-type CNTs form p–n hetero junctions at the core–shell interface of hierarchical PANI/CNT composites. The p-type PANI/CNT (p-PANI/CNT) and n-type PANI/CNT (n-PANI/CNT) performed the higher sensitivity to NO2 and NH3, respectively. The response times of p-PANI/CNT and n-PANI/CNT to 50 ppm of NO2 and NH3 are only 5.2 and 1.8 s, respectively, showing the real-time response. The estimated limit of detection for NO2 and NH3 is as low as to 16.7 and 6.4 ppb, respectively. After three months, the responses of p-PANI/CNT and n-PANI/CNT decreased by 19.1% and 11.3%, respectively. It was found that one-dimensional hierarchical structures and the deeper charge depletion layer enhanced by structural changes of PANI contributed to the sensitive and fast responses to NH3 and NO2. The formation process of the hierarchical PANI/CNT fibers, p–n transition, and the enhanced gas-sensing performance were systematically analyzed. This work also predicts the development prospects of cost-effective, high-performance PANI/CNT-based sensors.


Nanomaterials ◽  
2018 ◽  
Vol 8 (11) ◽  
pp. 902 ◽  
Author(s):  
Jae-Hyoung Lee ◽  
Jin-Young Kim ◽  
Ali Mirzaei ◽  
Hyoun Kim ◽  
Sang Kim

Metal oxide p-n heterojunction nanofibers (NFs) are among the most promising approaches to enhancing the efficiency of gas sensors. In this paper, we report the preparation of a series of p-NiO-loaded n-ZnO NFs, namely (1−x)ZnO-xNiO (x = 0.03, 0.05, 0.7, 0.1, and 0.15 wt%), for hydrogen gas sensing experiments. Samples were prepared through the electrospinning technique followed by a calcination process. The sensing experiments showed that the sample with 0.05 wt% NiO loading resulted in the highest sensing performance at an optimal sensing temperature of 200 °C. The sensing mechanism is discussed in detail and contributions of the p-n heterojunctions, metallization of ZnO and catalytic effect of NiO on the sensing enhancements of an optimized gas sensor are analyzed. This study demonstrates the possibility of fabricating high-performance H2 sensors through the optimization of p-type metal oxide loading on the surfaces of n-type metal oxides.


Author(s):  
Jae-Hyoung Lee ◽  
Jin-Young Kim ◽  
Ali Mirzaei ◽  
Hyoun Woo Kim ◽  
Sang Sub Kim

Metal oxide p-n heterojunction nanofibers (NFs) are among the most promising approaches to enhancing the efficiency of gas sensors. In this paper, we report the preparation of a series of p-NiO-loaded n-ZnO NFs, namely (1 − x) ZnO-xNiO (x = 0.03, 0.05, and 0.1 wt%), for hydrogen gas sensing experiments. Samples were prepared through the electrospinning technique followed by a calcination process. The sensing experiments showed that the sample with 0.05 wt% NiO loading resulted in the highest sensing performance at an optimal sensing temperature of 200 °C. The sensing mechanism is discussed in detail and contributions of the p-n heterojunctions, metallization of ZnO and catalytic effect of NiO on the sensing enhancements of an optimized gas sensor are analyzed. This study demonstrates the possibility of fabricating high-performance H2 sensors through the optimization of p-type metal oxide loading on the surfaces of n-type metal oxides.


2015 ◽  
Vol 135 (8) ◽  
pp. 317-322
Author(s):  
Mitsuaki Yano ◽  
Yousuke Hirahara ◽  
Jiro Terada ◽  
Shigehiko Sasa ◽  
Sigeru Omatu
Keyword(s):  

1998 ◽  
Vol 34 (19) ◽  
pp. 1888 ◽  
Author(s):  
G. Höck ◽  
T. Hackbarth ◽  
U. Erben ◽  
E. Kohn ◽  
U. König
Keyword(s):  

Sensors ◽  
2021 ◽  
Vol 21 (3) ◽  
pp. 783 ◽  
Author(s):  
Andrea Gaiardo ◽  
David Novel ◽  
Elia Scattolo ◽  
Michele Crivellari ◽  
Antonino Picciotto ◽  
...  

The substrate plays a key role in chemoresistive gas sensors. It acts as mechanical support for the sensing material, hosts the heating element and, also, aids the sensing material in signal transduction. In recent years, a significant improvement in the substrate production process has been achieved, thanks to the advances in micro- and nanofabrication for micro-electro-mechanical system (MEMS) technologies. In addition, the use of innovative materials and smaller low-power consumption silicon microheaters led to the development of high-performance gas sensors. Various heater layouts were investigated to optimize the temperature distribution on the membrane, and a suspended membrane configuration was exploited to avoid heat loss by conduction through the silicon bulk. However, there is a lack of comprehensive studies focused on predictive models for the optimization of the thermal and mechanical properties of a microheater. In this work, three microheater layouts in three membrane sizes were developed using the microfabrication process. The performance of these devices was evaluated to predict their thermal and mechanical behaviors by using both experimental and theoretical approaches. Finally, a statistical method was employed to cross-correlate the thermal predictive model and the mechanical failure analysis, aiming at microheater design optimization for gas-sensing applications.


Sensors ◽  
2021 ◽  
Vol 21 (12) ◽  
pp. 3947
Author(s):  
Wei Wang ◽  
Qinyi Zhang ◽  
Ruonan Lv ◽  
Dong Wu ◽  
Shunping Zhang

High performance formaldehyde gas sensors are widely needed for indoor air quality monitoring. A modified layer of zeolite on the surface of metal oxide semiconductors results in selectivity improvement to formaldehyde as gas sensors. However, there is insufficient knowledge on how the thickness of the zeolite layer affects the gas sensing properties. In this paper, ZSM-5 zeolite films were coated on the surface of the SnO2 gas sensors by the screen printing method. The thickness of ZSM-5 zeolite films was controlled by adjusting the numbers of screen printing layers. The influence of ZSM-5 film thickness on the performance of ZSM-5/SnO2 gas sensors was studied. The results showed that the ZSM-5/SnO2 gas sensors with a thickness of 19.5 μm greatly improved the selectivity to formaldehyde, and reduced the response to ethanol, acetone and benzene at 350 °C. The mechanism of the selectivity improvement to formaldehyde of the sensors was discussed.


2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Muhammad Naqi ◽  
Kyung Hwan Choi ◽  
Hocheon Yoo ◽  
Sudong Chae ◽  
Bum Jun Kim ◽  
...  

AbstractLow-temperature-processed semiconductors are an emerging need for next-generation scalable electronics, and these semiconductors need to feature large-area fabrication, solution processability, high electrical performance, and wide spectral optical absorption properties. Although various strategies of low-temperature-processed n-type semiconductors have been achieved, the development of high-performance p-type semiconductors at low temperature is still limited. Here, we report a unique low-temperature-processed method to synthesize tellurium nanowire networks (Te-nanonets) over a scalable area for the fabrication of high-performance large-area p-type field-effect transistors (FETs) with uniform and stable electrical and optical properties. Maximum mobility of 4.7 cm2/Vs, an on/off current ratio of 1 × 104, and a maximum transconductance of 2.18 µS are achieved. To further demonstrate the applicability of the proposed semiconductor, the electrical performance of a Te-nanonet-based transistor array of 42 devices is also measured, revealing stable and uniform results. Finally, to broaden the applicability of p-type Te-nanonet-based FETs, optical measurements are demonstrated over a wide spectral range, revealing an exceptionally uniform optical performance.


Nanomaterials ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 372
Author(s):  
Liyang Lin ◽  
Susu Chen ◽  
Tao Deng ◽  
Wen Zeng

The metal oxides/graphene nanocomposites have great application prospects in the fields of electrochemical energy storage and gas sensing detection. However, rational synthesis of such materials with good conductivity and electrochemical activity is the topical challenge for high-performance devices. Here, SnO2/graphene nanocomposite is taken as a typical example and develops a universal synthesis method that overcome these challenges and prepares the oxygen-deficient SnO2 hollow nanospheres/graphene (r-SnO2/GN) nanocomposite with excellent performance for supercapacitors and gas sensors. The electrode r-SnO2/GN exhibits specific capacitance of 947.4 F g−1 at a current density of 2 mA cm−2 and of 640.0 F g−1 even at 20 mA cm−2, showing remarkable rate capability. For gas-sensing application, the sensor r-SnO2/GN showed good sensitivity (~13.8 under 500 ppm) and short response/recovering time toward methane gas. These performance features make r-SnO2/GN nanocomposite a promising candidate for high-performance energy storage devices and gas sensors.


Sensors ◽  
2021 ◽  
Vol 21 (13) ◽  
pp. 4425
Author(s):  
Ana María Pineda-Reyes ◽  
María R. Herrera-Rivera ◽  
Hugo Rojas-Chávez ◽  
Heriberto Cruz-Martínez ◽  
Dora I. Medina

Monitoring and detecting carbon monoxide (CO) are critical because this gas is toxic and harmful to the ecosystem. In this respect, designing high-performance gas sensors for CO detection is necessary. Zinc oxide-based materials are promising for use as CO sensors, owing to their good sensing response, electrical performance, cost-effectiveness, long-term stability, low power consumption, ease of manufacturing, chemical stability, and non-toxicity. Nevertheless, further progress in gas sensing requires improving the selectivity and sensitivity, and lowering the operating temperature. Recently, different strategies have been implemented to improve the sensitivity and selectivity of ZnO to CO, highlighting the doping of ZnO. Many studies concluded that doped ZnO demonstrates better sensing properties than those of undoped ZnO in detecting CO. Therefore, in this review, we analyze and discuss, in detail, the recent advances in doped ZnO for CO sensing applications. First, experimental studies on ZnO doped with transition metals, boron group elements, and alkaline earth metals as CO sensors are comprehensively reviewed. We then focused on analyzing theoretical and combined experimental–theoretical studies. Finally, we present the conclusions and some perspectives for future investigations in the context of advancements in CO sensing using doped ZnO, which include room-temperature gas sensing.


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