scholarly journals Investigation on an air solar-driven open sorption system for comfort cooling

Solar Energy ◽  
2022 ◽  
Vol 231 ◽  
pp. 57-71
Author(s):  
Elsabet Nielsen ◽  
Sonja Becker-Hardt ◽  
Gerald Englmair ◽  
Weiqiang Kong ◽  
Simon Furbo
Keyword(s):  
2021 ◽  
Vol 3 (3) ◽  
Author(s):  
Péter Sipos

AbstractStudies comparing numerous sorption curve models and different error functions are lacking completely for soil-metal adsorption systems. We aimed to fill this gap by studying several isotherm models and error functions on soil-metal systems with different sorption curve types. The combination of fifteen sorption curve models and seven error functions were studied for Cd, Cu, Pb, and Zn in competitive systems in four soils with different geochemical properties. Statistical calculations were carried out to compare the results of the minimizing procedures and the fit of the sorption curve models. Although different sorption models and error functions may provide some variation in fitting the models to the experimental data, these differences are mostly not significant statistically. Several sorption models showed very good performances (Brouers-Sotolongo, Sips, Hill, Langmuir-Freundlich) for varying sorption curve types in the studied soil-metal systems, and further models can be suggested for certain sorption curve types. The ERRSQ error function exhibited the lowest error distribution between the experimental data and predicted sorption curves for almost each studied cases. Consequently, their combined use could be suggested for the study of metal sorption in the studied soils. Besides testing more than one sorption isotherm model and error function combination, evaluating the shape of the sorption curve and excluding non-adsorption processes could be advised for reliable data evaluation in soil-metal sorption system.


Chemosphere ◽  
2019 ◽  
Vol 218 ◽  
pp. 955-965 ◽  
Author(s):  
Seongchul Ryu ◽  
Gayathri Naidu ◽  
Md Abu Hasan Johir ◽  
Youngkwon Choi ◽  
Sanghyun Jeong ◽  
...  

1999 ◽  
Vol 39 (8) ◽  
pp. 139-146
Author(s):  
R. Y. Stefanova

The kinetics of removal of zinc ions from aqueous solutions by a modified acrylnitrile copolymer containing carboxyl and amino groups has been investigated. The dependence of the rate of removal on the intensity of stirring, the size of the sorbent's particles, the initial concentration of metal ions and the temperature of the solution have been established. Attempts have been made to identify the rate limiting step and to determine the batch kinetic parameters. The limiting conditions of the transition from external to intraparticle diffusion step of mass transfer in a sorption system have been determined. The coefficients of intraparticle diffusion and the energy of activation of the sorption process have been established. The data obtained in this work show that the modified polymer with a high sorption capacity and very good kinetic characteristics can be successfully used for removal of heavy metal ions from water solutions and industrial wastewaters.


2014 ◽  
Vol 141 ◽  
pp. 1-7 ◽  
Author(s):  
Mike A. Acheampong ◽  
Piet N.L. Lens

2008 ◽  
Vol 3 (1) ◽  
Author(s):  
Shaik Basha ◽  
Z.V.P. Murthy ◽  
B. Jha

A comparison between linear least-squares method and non-linear regression method of the widely used equilibrium isotherms (Langmuir, Freundlich and Redlich-Peterson) for the sorption of Cr(VI) onto Cystoseira indica, which was chemically-modified by cross-linking with epichlorohydrin (CB1, CB2), or oxidized by potassium permanganate (CB3), or only washed by distilled water (RB) was examined. The biosorption equilibriums were established in about 2 h and the maximum removal was observed at pH 3.0 with solid to liquid ratio of 0.05 g/l. The four different linearized forms of Langmuir isotherms are also discussed. Langmuir isotherm parameters obtained from the four Langmuir linear equations are different but they are the same by using non-linear Langmuir equation. The best-fitting isotherms are Langmuir and Redlich-Peterson. The present investigation showed that the non-linear method is the more appropriate method to determine the isotherm parameters. A design procedure was proposed using the Langmuir isotherm to design a two stage sorption system to minimize the amount of biomass required for the treatment of Cr(VI) solution using Cystoseira indica. A two stage sorption system reduced the amount of biomass required by 51.2, 50.7, 51.1 and 51.3%, for CB1, CB2, CB3 and RB, respectively, to achieve the required amount of Cr(VI) removal for any solution volume.


2021 ◽  
Author(s):  
Amanda L. Ciosek ◽  
Grace K. Luk

This study investigates the design and performance of a novel sorption system containing natural zeolite. The apparatus consists of packed, fixed-bed, dual-columns with custom automated controls and sampling chambers, connected in series and stock fed by a metering pump at a controlled adjustable distribution. The purpose of the system is to remove heavy metallic ions predominately found in acid mine drainage, including lead (Pb2+), copper (Cu2+), iron (Fe3+), nickel (Ni2+) and zinc (Zn2+), combined in equal equivalence to form an acidified total 10 meq/L aqueous solution. Reported trends on the zeolite’s preference to these heavy metallic ions is established in the system breakthrough curve, as Pb2+ >> Fe3+ > Cu2+ > Zn2+ >> Ni2+. Within a 3-h contact period, Pb2+ is completely removed from both columns. Insufficient Ni2+ removal is achieved by either column with the promptest breakthrough attained, as zeolite demonstrates the least affinity towards it; however, a 48.97% removal is observed in the cumulative collection at the completion of the analysis period. The empty bed contact times for the first and second columns are 20 and 30 min, respectively; indicating a higher bed capacity at breakthrough and a lower usage rate of the zeolite mineral in the second column. This sorption system experimentally demonstrates the potential for industrial wastewater treatment technology development. Keywords: zeolite; sorption; packed fixed-bed columns; heavy metallic ions; automated sampling design


2009 ◽  
Vol 3 (1) ◽  
pp. 17-22 ◽  
Author(s):  
Ayoob Sulaiman ◽  
Ashok Gupta ◽  
Abi Basheer

Author(s):  
Kelechi EBISIKE ◽  
Afamefuna Elvis OKORONKWO ◽  
Kenneth Kanayo ALANEME

The utilization and efficiency of agricultural waste-derived chitosan-silica hybrid aerogel “(CS)hA” on nickel removal from aqueous solution was examined and optimum parameters for pH, contact time, and initial ion concentration were determined during batch sorption system studies. Metal recovery was performed on the adsorbent using separately dilute concentrations of hydrochloric acid, acetic acid, ammonia, and sodium hydroxide solutions as eluents. The results generated were analyzed from kinetic and isotherm studies. The maximum Ni2+ adsorption of 99.78 % was established at 60 min and pH 3 in this study. The batch studies revealed that the percentage of nickel ion removal by the adsorbent decreased along with an increase in the initial Ni2+ ions concentration. The pseudo-second-order, the best fit of the kinetic model, has the values of its correlation coefficient “R2” ranging from 0.9 to 1, whereas the Langmuir model which had the maximum monolayer adsorption capacity of 85.84 mg g-1, was the best isotherm in interpreting the sorption process and the calculated separation factor was higher than 0 but less than 1. Dilute hydrochloric acid (0.1 M) was the best eluent in removing bound nickel ions (55.63 %) from (CS)hA.


Aerospace ◽  
2006 ◽  
Author(s):  
John D. Bernardin ◽  
Snezana Konecni ◽  
Roger Wiens

A novel spacecraft, the Sample Collection for Investigation of Mars (SCIM), was proposed for the collection and return of atmospheric gas and dust samples from the martian atmosphere. The SCIM mission, part of NASA's Mars Exploration Strategy, would allow scientists to greatly enhance our understanding of Mars' water, climate, and geological evolution by studying the element and isotopic composition of the gas and dust. The SCIM spacecraft was proposed to collect its samples during a single high-speed pass through the martian atmosphere at an altitude of 37 km and return the samples back to earth. For the atmospheric gas sampling aspect the SCIM employs the Atmospheric Collection Experiment (ACE), a dual-component apparatus consisting of a passive and a cryogenic sorption gas collection system. Each of these systems possesses a collection vessel that is initially under high vacuum. At the time of entry into the martian atmosphere, valves on SCIM open and gas flows into the parallel-plumbed passive and cryogenic sorption gas collection systems. The passive system simply allows the incoming gas to fill an initially evacuated 1 Liter vessel. The cryogenic sorption system employs a Joule-Thompson cryocooler and sorption medium that initially condenses and captures the incoming gas. As the SCIM begins to exit the atmosphere isolation valves close and trap the gas samples in their collection systems for the return journey back to earth. The minimum SCIM mission goal was to collect 100 cm3 @STP(≈ 0.2 g) of martian atmospheric gas and the ACE was being designed to gather 1000 cm3 @STP (≈ 2.0 g) using both the passive and cryogenic systems. The volumes referred to above correspond to standard temperature and pressure on Earth (e.g., STP). The goals of this study were to prove the gas collection concepts mentioned above and develop the numerical and experimental tools to allow for the optimization of a flight worthy ACE. This paper discusses the design, analysis, and testing of a prototype ACE. First, more specific details on the design and testing methodology for the prototype are presented. Next, the development of a computational fluid dynamics (CFD) model is discussed. Finally, empirical pressure data from the prototype tests are used to assess the performances of the passive and cryogenic sorption gas collection systems and are compared to numerical pressure predictions to provide a benchmark for the CFD model. Results indicate that the prototype ACE is capable of meeting the design goal of 1000 cm3 @STP (2.0 g) of total gas collection.


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