One-step self-assembly fabrication of three-dimensional copper oxide/graphene oxide aerogel composite material for supercapacitors

2019 ◽  
Vol 287 ◽  
pp. 27-30 ◽  
Author(s):  
Zhaoxia Song ◽  
Wei Liu ◽  
Nanxuan Sun ◽  
Wensuo Wei ◽  
Zheng Zhang ◽  
...  
RSC Advances ◽  
2016 ◽  
Vol 6 (61) ◽  
pp. 56278-56286 ◽  
Author(s):  
Lei Chen ◽  
Zhang-Run Xu

A 3D nickel-doped reduced graphene oxide aerogel was prepared by one-step reduction and self-assembly, which exhibited favorable selectivity and high adsorption capacity for isolating hemoglobin.


RSC Advances ◽  
2019 ◽  
Vol 9 (64) ◽  
pp. 37573-37583 ◽  
Author(s):  
Ting Wu ◽  
Bo Zhang ◽  
Zhimin Wu ◽  
Jinglin Zhang ◽  
Huidi Liu ◽  
...  

By using three-dimensional reduced graphene oxide (rGO) aerogel as a carrier for molybdenum trioxide (MoO3), a series of rGO-MoO3 aerogels were synthesized by a self-assembly process.


Micromachines ◽  
2019 ◽  
Vol 11 (1) ◽  
pp. 13 ◽  
Author(s):  
Bin Zhang ◽  
Jaehyun Lee ◽  
Mincheol Kim ◽  
Naeeung Lee ◽  
Hyungdong Lee ◽  
...  

The macroscopic assembly of two-dimensional materials into a laminar structure has received considerable attention because it improves both the mechanical and chemical properties of the original materials. However, conventional manufacturing methods have certain limitations in that they require a high temperature process, use toxic solvents, and are considerably time consuming. Here, we present a new system for the self-assembly of layer-by-layer (LBL) graphene oxide (GO) via an electrohydrodynamic (EHD) jet printing technique. During printing, the orientation of GO flakes can be controlled by the velocity distribution of liquid jet and electric field-induced alignment spontaneously. Closely-packed GO patterns with an ordered laminar structure can be rapidly realized using an interfacial assembly process on the substrates. The surface roughness and electrical conductivity of the LBL structure were significantly improved compared with conventional dispensing methods. We further applied this technique to fabricate a reduced graphene oxide (r-GO)-based supercapacitor and a three-dimensional (3D) metallic grid hybrid ammonia sensor. We present the EHD-assisted assembly of laminar r-GO structures as a new platform for preparing high-performance energy storage devices and sensors.


2015 ◽  
Vol 3 (27) ◽  
pp. 14445-14457 ◽  
Author(s):  
Jianyun Cao ◽  
Yaming Wang ◽  
Junchen Chen ◽  
Xiaohong Li ◽  
Frank C. Walsh ◽  
...  

The 3D interconnected structure of the GO/PPy composite ensures fast ion diffusion through the electrode, leading to excellent supercapacitor performance.


2020 ◽  
Vol 7 (10) ◽  
pp. 200857 ◽  
Author(s):  
Junhong Tao ◽  
Jie Yang ◽  
Chengxiao Ma ◽  
Junfeng Li ◽  
Keqing Du ◽  
...  

Residual antibiotics in water are often persistent organic pollutants. The purpose of this study was to prepare a cellulose nanocrystals/graphene oxide composite (CNCs-GO) with a three-dimensional structure for the removal of the antibiotic levofloxacin hydrochloride (Levo-HCl) in water by adsorption. The scanning electron microscope, Fourier transform infrared (FT-IR), energy-dispersive spectroscopy, X-ray photoelectron spectroscopy and other characterization methods were used to study the physical structure and chemical properties of the CNCs-GO. The three-dimensional structure of the composite material rendered a high surface area and electrostatic attraction, resulting in increased adsorption capacity of the CNCs-GO for Levo-HCl. Based on the Box–Behnken design, the effects of different factors on the removal of Levo-HCl by the CNCs-GO were explored. The composite material exhibited good antibiotic adsorption capacity, with a removal percentage exceeding 80.1% at an optimal pH of 4, the adsorbent dosage of 1.0 g l −1 , initial pollutant concentration of 10.0 mg l −1 and contact time of 4 h. The adsorption isotherm was well fitted by the Sips model, and kinetics studies demonstrated that the adsorption process conformed to a quasi-second-order kinetics model. Consequently, the as-synthesized CNCs-GO demonstrates good potential for the effective removal of antibiotics such as levofloxacin hydrochloride from aqueous media.


2020 ◽  
Vol 993 ◽  
pp. 646-653
Author(s):  
Shao Hui Liu ◽  
Yu Zhao ◽  
Xu Ran

In order to improve the interfacial bonding between graphene and copper and improve the dispersibility of graphene in the copper matrix, a novel method was used to prepare graphene. Firstly, graphene oxide (GO) was prepared by the modified Hummer's method, and then the reduced graphene oxide-supported cobalt nanoparticle composite powder (Co@RGO) was prepared by one-step in-situ reduction method. The fabricated materials were mixed with copper powder to obtain various volume fractions. The powder mixture was subjected to compression and discharge plasma sintering (SPS) to prepare a bulk copper-based composite material. The microstructure and its comprehensive properties were studied by SEM, TEM, XRD, FTIR and Raman. The results show that the agglomeration of graphene can be effectively inhibited after the cobalt nanoparticles supported on the graphene surface. The proper amount of Co@RGO could be uniformly dispersed in the copper matrix. The composite material showed a high electrical conductivity (>86% IACS), and the Vickers hardness also increased by about 30% compared with pure copper.


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