Physico-chemical structure of the benthic environment of a Galician ría (Ría de Ares-Betanzos, north-west Spain)

1999 ◽  
Vol 79 (1) ◽  
pp. 1-21 ◽  
Author(s):  
A. Sánchez-Mata ◽  
M. Glémarec ◽  
J. Mora
Keyword(s):  
Organic Carbon ◽  
Principal Component ◽  
Clay Content ◽  
Size Composition ◽  
Total Carbon ◽  
Sediment Type ◽  
Overlying Water ◽  
Sediment Distribution ◽  
North West ◽  
Inorganic Content

In a preliminary study of the marine benthos of Ría de Ares-Betanzos, 50 stations covering the quadrant delineated by the coordinates 43°26′42″N–43°20′42″N and 08°18′54″W–08°10′12″W were sampled and sediment samples analysed for particle-size composition, sand, silt and clay content, degree of sorting, median diameter and grain-size diversity of sediments. Organic and inorganic content, total carbon and nitrogen, carbonates, organic carbon/total nitrogen ratio and bathymetric data were also collected. On a smaller scale a few stations were sampled for sediment redox potential and pH measurement. The salinity, temperature and oxygen content of the overlying water was also assessed.Cluster analysis and Principal Component Analysis methods were used to describe seabed heterogeneity and the pattern of sediment distribution within the ría, and to relate the environmental variables to each sediment type. Sediments were predominantly fine to very fine sands, and exhibited a direct depth-related gradient, i.e. with the finer grades, higher organic carbon and silt and clay occurring at the shallower areas of Pontedeume, Ares and Redes inlets and Ría de Betanzos sector where terrigenous input was important. Carbonate, organic carbon and organic matter maxima occurred in the central sector of the ría where most mollusc recruitment takes place: revealing the chiefly bioclastic origin of sediments. Taking into account the geological and hydrographic processes, explanations for the formation of the sedimentary bottoms in Ría de Ares-Betanzos are provided.

scholarly journals Relationship between soil oxidizable carbon and physical, chemical and mineralogical properties of umbric ferralsols

2011 ◽  
Vol 35 (1) ◽  
pp. 25-40 ◽  
Author(s):  
Flávio Adriano Marques ◽  
Márcia Regina Calegari ◽  
Pablo Vidal-Torrado ◽  
Peter Buurman
Keyword(s):  
Organic Matter ◽  
Organic Carbon ◽  
Clay Content ◽  
Selective Extraction ◽  
Total Carbon ◽  
Soil Matrix ◽  
Soil Variables ◽  
Physical Chemical ◽  
Mineralogical Properties ◽  
Extractable Al

The occurrence of Umbric Ferralsols with thick umbric epipedons (> 100 cm thickness) in humid Tropical and Subtropical areas is a paradox since the processes of organic matter decomposition in these environments are very efficient. Nevertheless, this soil type has been reported in areas in the Southeast and South of Brazil, and at some places in the Northeast. Aspects of the genesis and paleoenvironmental significance of these Ferralsols still need a better understanding. The processes that made the umbric horizons so thick and dark and contributed to the preservation of organic carbon (OC) at considerable depths in these soils are of special interest. In this study, eight Ferralsols with a thick umbric horizon (UF) under different vegetation types were sampled (tropical rain forest, tropical seasonal forest and savanna woodland) and their macromorphological, physical, chemical and mineralogical properties studied to detect soil characteristics that could explain the preservation of high carbon amounts at considerable depths. The studied UF are clayey to very clayey, strongly acidic, dystrophic, and Al-saturated and charcoal fragments are often scattered in the soil matrix. Kaolinites are the main clay minerals in the A and B horizons, followed by abundant gibbsite and hydroxyl-interlayered vermiculite. The latter was only found in UFs derived from basalt rock in the South of the country. Total carbon (TC) ranged from 5 to 101 g kg-1 in the umbric epipedon. Dichromate-oxidizable organic carbon represented nearly 75 % of TC in the thick A horizons, while non-oxidizable C, which includes recalcitrant C (e.g., charcoal), contributed to the remaining 25 % of TC. Carbon contents were not related to most of the inorganic soil variables studied, except for oxalate-extractable Al, which individually explained 69 % (P < 0.001) of the variability of TC in the umbric epipedon. Clay content was not suited as predictor of TC or of the other studied C forms. Bulk density, exchangeable Al3+, Al saturation, ECEC and other parameters obtained by selective extraction were not suitable as predictors of TC and other C forms. Interactions between organic matter and poorly crystalline minerals, as indicated by oxalate-extractable Al, appear to be one of the possible organic matter protection mechanisms of these soils.

A survey of total and dissolved organic carbon in alkaline soils of southern Australia

Soil Research ◽  
2017 ◽  
Vol 55 (7) ◽  
pp. 617 ◽  
Author(s):  
G. K. McDonald ◽  
E. Tavakkoli ◽  
D. Cozzolino ◽  
K. Banas ◽  
M. Derrien ◽  
...  
Keyword(s):  
Organic Carbon ◽  
Dissolved Organic Carbon ◽  
Management Practices ◽  
South Australia ◽  
Principal Component ◽  
Clay Content ◽  
Alkaline Soils ◽  
Soil Organic C ◽  
Organic C ◽  
Western Victoria

Dissolved organic carbon (DOC) is important to microbial activity and nutrient cycling, and its concentration is sensitive to pH. Despite the importance of alkaline soils to agricultural production in southern Australia, few studies have documented the concentrations of soil organic carbon (C) and DOC or described the effects of soil properties and management practices on DOC in these soils. A survey of 33 paddocks from the Eyre Peninsula and mid-North regions of South Australia and north-western Victoria demonstrated significant variation in pH, soil organic C and DOC. Carbon stocks in the surface 30cm were 40–55tC/ha and were lowest in paddocks from Victoria. Soils from South Australia had higher DOC concentrations in the top 20cm than soils from Victoria. Principal component analysis suggested variation in DOC was increased by high pH, electric conductivity and the concentration of exchangeable Na, and was reduced by the concentration of exchangeable Ca and clay content. Mid-infrared Fourier transform infrared spectroscopy identified regional differences in the composition of soil organic C, with high amounts of charcoal in Eyre Peninsula soils. Farm management practices had little effect on soil organic C but influenced DOC. Grain yield and DOC concentration were inversely related across and within regions which appeared to be related to the intensity of cropping having opposite influences on yield and DOC. Compared with international data, DOC concentrations were high relative to the amount of soil organic C and, in contrast to many previous studies, DOC in all regions increased with depth.

scholarly journals Impact of aquaculture on distribution of dissolved organic matter in coastal Jeju Island, Korea, based on absorption and fluorescence spectroscopy

2021 ◽  
Author(s):  
Jeonghyun Kim ◽  
Yeseul Kim ◽  
Sung Eun Park ◽  
Tae-Hoon Kim ◽  
Bong-Guk Kim ◽  
...  
Keyword(s):  
Organic Matter ◽  
Organic Carbon ◽  
Fluorescence Spectroscopy ◽  
Dissolved Organic Matter ◽  
Coastal Water ◽  
Coastal Region ◽  
Principal Component ◽  
Distribution Patterns ◽  
Organic Pollution ◽  
Jeju Island

AbstractIn Jeju Island, multiple land-based aquafarms were fully operational along most coastal region. However, the effect of effluent on distribution and behaviours of dissolved organic matter (DOM) in the coastal water are still unknown. To decipher characteristics of organic pollution, we compared physicochemical parameters with spectral optical properties near the coastal aquafarms in Jeju Island. Absorption spectra were measured to calculate the absorption coefficient, spectral slope coefficient, and specific UV absorbance. Fluorescent DOM was analysed using fluorescence spectroscopy coupled with parallel factor analysis. Dissolved organic carbon (DOC) and total dissolved nitrogen (TDN) were measured using high-temperature catalytic oxidation. The DOC concentration near the discharge outlet was twice higher than that in natural groundwater, and the TDN concentration exponentially increased close to the outlet. These distribution patterns indicate that aquafarms are a significant source of DOM. Herein, principal component analysis was applied to categorise the DOM origins. There were two distinct groups, namely, aquaculture activity for TDN with humic-like and high molecular weights DOM (PC1: 48.1%) and natural biological activity in the coastal water for DOC enrichment and protein-like DOM (PC2: 18.8%). We conclude that the aquafarms significantly discharge organic nitrogen pollutants and provoke in situ production of organic carbon. Furthermore, these findings indicate the potential of optical techniques for the efficient monitoring of anthropogenic organic pollutants from aquafarms worldwide.

Effects of grazing intensity on organic carbon stock characteristics in Stipa breviflora desert steppe vegetation soil systems

2017 ◽  
Vol 39 (2) ◽  
pp. 169 ◽  
Author(s):  
Heyun Wang ◽  
Zhi Dong ◽  
Jianying Guo ◽  
Hongli Li ◽  
Jinrong Li ◽  
...  
Keyword(s):  
Organic Carbon ◽  
Soil Organic Carbon ◽  
Aboveground Biomass ◽  
Carbon Stock ◽  
Belowground Biomass ◽  
Total Carbon ◽  
Desert Steppe ◽  
Light Fraction Organic Carbon ◽  
Grazing Intensities ◽  
Organic Carbon Stock

Grassland ecosystems, an important component of the terrestrial environment, play an essential role in the global carbon cycle and balance. We considered four different grazing intensities on a Stipa breviflora desert steppe: heavy grazing (HG), moderate grazing (MG), light grazing (LG), and an area fenced to exclude livestock grazing as the Control (CK). The analyses of the aboveground biomass, litter, belowground biomass, soil organic carbon and soil light fraction organic carbon were utilised to study the organic carbon stock characteristics in the S. breviflora desert steppe under different grazing intensities. This is important to reveal the mechanisms of grazing impact on carbon processes in the desert steppe, and can provide a theoretical basis for conservation and utilisation of grassland resources. Results showed that the carbon stock was 11.98–44.51 g m–2 in aboveground biomass, 10.43–36.12 g m–2 in plant litters, and 502.30–804.31 g m–2 in belowground biomass (0–40 cm). It was significantly higher in CK than in MG and HG. The carbon stock at 0–40-cm soil depth was 7817.43–9694.16 g m–2, and it was significantly higher in LG than in CK and HG. The total carbon stock in the vegetation-soil system was 8342.14–10494.80 g m–2 under different grazing intensities, with the largest value in LG, followed by MG, CK, and HG. About 90.54–93.71% of the total carbon in grassland ecosystem was reserved in soil. The LG and MG intensities were beneficial to the accumulation of soil organic carbon stock. The soil light fraction organic carbon stock was 484.20–654.62 g m–2 and was the highest under LG intensity. The LG and MG intensities were beneficial for soil nutrient accumulation in the desert steppe.

scholarly journals Effect of termite activity on soil under different land management strategies

2017 ◽  
Vol 38 (1) ◽  
pp. 143
Author(s):  
Liane Barreto Alves Pinheiro ◽  
Rodrigo Camara ◽  
Marcos Gervasio Pereira ◽  
Eduardo Lima ◽  
Maria Elizabeth Fernandes Correia ◽  
...  
Keyword(s):  
Organic Carbon ◽  
Management Strategies ◽  
Chemical Properties ◽  
Clay Content ◽  
Exchange Capacity ◽  
Termite Mounds ◽  
Eucalyptus Plantation ◽  
Exchangeable Acidity ◽  
Calcium And Magnesium ◽  
Surrounding Soil

Mound-building termites are important agents of soil bioperturbation, but these species have not been extensively studied thus far. The present study aimed to evaluate the soil particle-size and the chemical attributes of termite mounds and the surrounding soil under different land use strategies. A one-hectare plot was defined for an unmanaged degraded pasture, planted pasture, and for a eucalyptus Corymbia citriodora plantation. In each plot, the top, center, and base sections of five Cornitermes cumulans mounds, and the surrounding soil at the depths of 0-5; 5-10; 10-20 cm, were sampled in the Pinheiral, Rio de Janeiro state. In the three areas, the center of the mounds contained higher clay content, organic carbon, phosphorous, calcium and magnesium, total bases, and cation exchangeable capacity, when compared to the top, base, and the surrounding soils. However, the center had lower values of exchangeable acidity and potassium, of the three areas. In the eucalyptus plantation, the values of pH, total bases, calcium, and magnesium were lower, whereas aluminum, exchangeable acidity, sodium, and cation exchange capacity were higher both in the mounds and in the surrounding soil, in relation to the pastures. There were no differences among the three areas in terms of organic carbon, potassium, phosphorous, and total bases, in the mounds and adjacent soil. Thus, the termite activity altered the clay content and most of the soil chemical properties in all of the studied areas, but only for the center of the mounds. However, the effect of these organisms was different in the eucalyptus plantation in relation to the pasture areas.

scholarly journals Fossil and non-fossil source contributions to atmospheric carbonaceous aerosols during extreme spring grassland fires in Eastern Europe

2016 ◽  
Vol 16 (9) ◽  
pp. 5513-5529 ◽  
Author(s):  
Vidmantas Ulevicius ◽  
Steigvilė Byčenkienė ◽  
Carlo Bozzetti ◽  
Athanasia Vlachou ◽  
Kristina Plauškaitė ◽  
...  
Keyword(s):  
Organic Carbon ◽  
Biomass Burning ◽  
Nitrogen Isotopes ◽  
Early Spring ◽  
Total Carbon ◽  
Carbonaceous Aerosols ◽  
Pmf Model ◽  
Source Contributions ◽  
The Baltic ◽  
The Impact

Abstract. In early spring the Baltic region is frequently affected by high-pollution events due to biomass burning in that area. Here we present a comprehensive study to investigate the impact of biomass/grass burning (BB) on the evolution and composition of aerosol in Preila, Lithuania, during springtime open fires. Non-refractory submicron particulate matter (NR-PM1) was measured by an Aerodyne aerosol chemical speciation monitor (ACSM) and a source apportionment with the multilinear engine (ME-2) running the positive matrix factorization (PMF) model was applied to the organic aerosol fraction to investigate the impact of biomass/grass burning. Satellite observations over regions of biomass burning activity supported the results and identification of air mass transport to the area of investigation. Sharp increases in biomass burning tracers, such as levoglucosan up to 683 ng m−3 and black carbon (BC) up to 17 µg m−3 were observed during this period. A further separation between fossil and non-fossil primary and secondary contributions was obtained by coupling ACSM PMF results and radiocarbon (14C) measurements of the elemental (EC) and organic (OC) carbon fractions. Non-fossil organic carbon (OCnf) was the dominant fraction of PM1, with the primary (POCnf) and secondary (SOCnf) fractions contributing 26–44 % and 13–23 % to the total carbon (TC), respectively. 5–8 % of the TC had a primary fossil origin (POCf), whereas the contribution of fossil secondary organic carbon (SOCf) was 4–13 %. Non-fossil EC (ECnf) and fossil EC (ECf) ranged from 13–24 and 7–13 %, respectively. Isotope ratios of stable carbon and nitrogen isotopes were used to distinguish aerosol particles associated with solid and liquid fossil fuel burning.

scholarly journals Australian net (1950s–1990) soil organic carbon erosion: implications for CO<sub>2</sub> emission and land–atmosphere modelling

2014 ◽  
Vol 11 (18) ◽  
pp. 5235-5244 ◽  
Author(s):  
A. Chappell ◽  
N. P. Webb ◽  
R. A. Viscarra Rossel ◽  
E. Bui
Keyword(s):  
Soil Erosion ◽  
Organic Carbon ◽  
Soil Organic Carbon ◽  
Land Surface ◽  
Total Carbon ◽  
Catchment Scale ◽  
European Settlement ◽  
Surface Models ◽  
Management Context ◽  
Land Use And Management

Abstract. The debate remains unresolved about soil erosion substantially offsetting fossil fuel emissions and acting as an important source or sink of CO2. There is little historical land use and management context to this debate, which is central to Australia's recent past of European settlement, agricultural expansion and agriculturally-induced soil erosion. We use "catchment" scale (∼25 km2) estimates of 137Cs-derived net (1950s–1990) soil redistribution of all processes (wind, water and tillage) to calculate the net soil organic carbon (SOC) redistribution across Australia. We approximate the selective removal of SOC at net eroding locations and SOC enrichment of transported sediment and net depositional locations. We map net (1950s–1990) SOC redistribution across Australia and estimate erosion by all processes to be ∼4 Tg SOC yr−1, which represents a loss of ∼2% of the total carbon stock (0–10 cm) of Australia. Assuming this net SOC loss is mineralised, the flux (∼15 Tg CO2-equivalents yr−1) represents an omitted 12% of CO2-equivalent emissions from all carbon pools in Australia. Although a small source of uncertainty in the Australian carbon budget, the mass flux interacts with energy and water fluxes, and its omission from land surface models likely creates more uncertainty than has been previously recognised.

scholarly journals CARBON CONTENTS AND MODELLING OF TOTAL ORGANIC CARBON FOR Pinus taeda L. FROM NATURAL REGENERATION

2016 ◽  
Vol 40 (4) ◽  
pp. 661-668 ◽  
Author(s):  
Rafael Cubas ◽  
Emanuel Arnoni Costa ◽  
Viviane Zaniz
Keyword(s):  
Organic Carbon ◽  
Total Organic Carbon ◽  
Pinus Taeda ◽  
Natural Regeneration ◽  
Ground Level ◽  
Total Carbon ◽  
Forest Understory ◽  
Planted Forest ◽  
Pinus Taeda L ◽  
Selection Of

ABSTRACT This study aimed to quantify total carbon and its compartments: roots, stems, branches, and aciculas, in order to select an estimated equation of the total organic carbon for Pinus taeda L. settled from natural regeneration in the forest understory of a planted forest in the municipality of Três Barras, SC. Data have been collected from a random selection of 96 individuals with diameter at 0.3 meters above ground level, varying from 2.5 to 19cm. The selected individuals had their dimensional variables (dendrometric and morphometric variables) measured being subsequently felled and their compartments separated, weighed and samples were collected and taken to analysis of carbon contents. Eight traditional models were tested, six arithmetic and two logarithmic, as well as a model developed by the Stepwise process, being total organic carbon the dependent variable, and dimensional variables the independent variables. The total organic carbon found was 46.7% on average, and Tukey-Kramer test indicated significant differences of carbon contents amongst compartments. In comparison with traditional equations tested, the equation adjusted by Stepwise seemed more accurate, with good fit (R2aj. = 0.931) and precision (Syx% = 18.5).

scholarly journals The use of radiocarbon <sup>14</sup>C to constrain carbon dynamics in the soil module of the land surface model ORCHIDEE (SVN r5165)

2018 ◽  
Author(s):  
Marwa Tifafi ◽  
Marta Camino-Serrano ◽  
Christine Hatté ◽  
Hector Morras ◽  
Lucas Moretti ◽  
...  
Keyword(s):  
Organic Carbon ◽  
Soil Organic Carbon ◽  
Soil Carbon ◽  
Land Surface ◽  
Carbon Stock ◽  
Land Surface Model ◽  
Carbon Dynamics ◽  
Total Carbon ◽  
Soil Parameters ◽  
Surface Model

Abstract. Despite the importance of soil as a large component of the terrestrial ecosystems, the soil compartments are not well represented in the Land Surface Models (LSMs). Indeed, soils in current LSMs are generally represented based on a very simplified schema that can induce a misrepresentation of the deep dynamics of soil carbon. Here, we present a new version of the IPSL-Land Surface Model called ORCHIDEE-SOM, incorporating the 14C dynamic in the soil. ORCHIDEE-SOM, first, simulates soil carbon dynamics for different layers, down to 2 m depth. Second, concentration of dissolved organic carbon (DOC) and its transport are modeled. Finally, soil organic carbon (SOC) decomposition is considered taking into account the priming effect. After implementing the 14C in the soil module of the model, we evaluated model outputs against observations of soil organic carbon and 14C activity (F14C) for different sites with different characteristics. The model managed to reproduce the soil organic carbon stocks and the F14C along the vertical profiles. However, an overestimation of the total carbon stock was noted, but was mostly marked on the surface. Then, thanks to the introduction of 14C, it has been possible to highlight an underestimation of the age of carbon in the soil. Thereafter, two different tests on this new version have been established. The first was to increase carbon residence time of the passive pool and decrease the flux from the slow pool to the passive pool. The second was to establish an equation of diffusion, initially constant throughout the profile, making it vary exponentially as a function of depth. The first modifications did not improve the capacity of the model to reproduce observations whereas the second test showed a decrease of the soil carbon stock overestimation, especially at the surface and an improvement of the estimates of the carbon age. This assumes that we should focus more on vertical variation of soil parameters as a function of depth, mainly for diffusion, in order to upgrade the representation of global carbon cycle in LSMs, thereby helping to improve predictions of the future response of soil organic carbon to global warming.

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