Today we learn at such a young age about the periodic properties of the elements and their atomic structure that it seems as if we grew up with the knowledge, and that everyone must always have known such basic, simple stuff. But till nearly the end of the nineteenth century no one even suspected that such things as the noble gases, with their filled electronic orbits, might exist. Helium was the first one we at Brookhaven looked for in our mass spectrometer, and the first one discovered. This was in 1868, but the discovery was ignored and the discoverer ridiculed. He didn’t care; he had other things on his mind. His name was Pierre Jules César Janssen, and he was a French astronomer who sailed to India that year in order to take advantage of a predicted solar eclipse. With the overwhelming brightness of the sun’s disk blocked by the moon, he hoped to observe the outer layers using the newly discovered technique of absorption spectroscopy. Nobody at the time understood why, but it had been observed that when a bright light shone through a gas, the chemical elements in the gas absorbed the light at specific wavelengths. The resulting dark lines in the emission spectrum of the light were like fingerprints, for it had been found in chemical laboratories that when an element was heated it emitted light at the same wavelengths it would absorb when light from an outside source was shined on it. So the way the technique worked, Janssen reasoned, was that he could measure the wavelengths of the solar absorbed lines and compare them with lines emitted in chemical laboratories where different elements were routinely studied, thus identifying the gases present in the sun. On August 18 of that year the moon moved properly into position, and Janssen’s spectroscope captured the dark absorption lines of the gases surrounding the sun. It was an exciting moment, as for the first time the old riddle could be answered: “Twinkle twinkle, little star, how I wonder what you are.” The answer now was clear: the sun, a typical star, was made overwhelmingly of hydrogen. But to Janssen’s surprise there was one additional and annoying line, with a wavelength of 587.49 nanometers.