Method and Device for Quantitative Measurement of Crude Oil Fouling Deposits of Several Crude Oils and Blends at a Higher Temperature and the Impact of Antifoulant Additives

2018 ◽  
Vol 32 (6) ◽  
pp. 6782-6787 ◽  
Author(s):  
Yassin Al Obaidi ◽  
Mike Kozminski ◽  
Joshua D. Ward
2014 ◽  
Vol 625 ◽  
pp. 196-200 ◽  
Author(s):  
Arya Hosseinipour ◽  
Khalik M. Sabil ◽  
Andhy Arya Ekaputra ◽  
Azuraien B. Japper ◽  
Lukman B. Ismail

One of the major problems in petroleum industry is wax precipitation and deposition. The component’s compositional and structural analysis of the crude oils is key factors to be studied to mitigate wax formation and precipitation tendency for the betterment of the crude oil flowability. In this work, the compositions and structures of two Malaysian and Sudanese crude oil samples were determined to investigate their effects on wax precipitation. The GC/MS was used to analyze hydrocarbon components. For this work, high pressure micro differential scanning calorimetry (HPμDSC) is used to determine the wax crystallization point and solubility curve. Results showed a linear relationship between wax appearance temperature (WAT) and weight percentage of component in the crude oil having > 14 carbon atoms. In addition, the effect of temperature on the amount of wax precipitation has also been investigated. Keywords: N-paraffin, Wax appearance temperature, Wax precipitation, High pressure micro differential scanning calorimetry


2020 ◽  
Vol 8 (1) ◽  
pp. 28-42
Author(s):  
Suresh Aluvihara ◽  
Jagath Premachandra

In the industry of petroleum oil refining industry the term of corrosion is frequently applicable regarding the several incidents because of the corrosiveness of petroleum oils due to the presence of trace corrosive compounds in such petroleum oils since the occurrences. Usually the corrosion is the results of chemical or electrochemical process of metals when it is exposing to the corrosive environment. The investigations of the impact of the organic acids, salts, elemental sulfur and the Mercaptans on the corrosion rates of seven different types of ferrous metals and the analysis of the nature of the corrosion between these materials were the objectives of the existing research. The relevant corrosive properties of two different types of selected crude oils and the chemical compositions of selected seven different types of ferrous metals were tested by the standard methods and instruments. A batch of similar sized metal coupons was immersed in both crude oil samples separately as three homogeneous metal coupons per each crude oil container. In order of after 15, 30 and 45 days from the immersion the corrosion rates of such metal coupons were determined by the weight loss method as three sets of samples while observing the corroded metal surfaces through an optical microscope. In addition, the decay of ferrous and copper from metals into crude oils while the interaction and the deductions of the initial hardness of metals were tested. As the basic investigations there were observed the relatively lower corrosion rates from stainless steels, relatively higher impact from salts on the metallic corrosion at lower temperatures, formations of FeS, Fe2O3, corrosion cracks and pitting, significant decays of ferrous and copper from some metals and the slight reductions of the initial hardness of metals after the interaction with the petroleum oils.


2014 ◽  
Vol 625 ◽  
pp. 482-485 ◽  
Author(s):  
Nitin Shetty ◽  
Marappagounder Ramasamy ◽  
Rajashekhar Pendyala

Temperature plays a very important role in the formation of fouling precursors in crude oils which is considered to be the first step before the precursors are either attached to the wall as a deposit or transferred back to the bulk fluid by diffusion. In order to investigate the formation characteristics of fouling precursors in crude oils at different bulk temperatures, a custom-design thin film microreactor is constructed. It is observed during the experiments that tendency to form fouling precursors is higher at higher surface temperatures. The precursor particles once formed continue to grow in size with time at constant surface temperatures. It is also observed that the particles tend to grow in size while it is cooled when the temperatures are below 55 oC.


2015 ◽  
Vol 22 (04) ◽  
pp. 26-50
Author(s):  
Ngoc Tran Thi Bich ◽  
Huong Pham Hoang Cam

This paper aims to examine the main determinants of inflation in Vietnam during the period from 2002Q1 to 2013Q2. The cointegration theory and the Vector Error Correction Model (VECM) approach are used to examine the impact of domestic credit, interest rate, budget deficit, and crude oil prices on inflation in both long and short terms. The results show that while there are long-term relations among inflation and the others, such factors as oil prices, domestic credit, and interest rate, in the short run, have no impact on fluctuations of inflation. Particularly, the budget deficit itself actually has a short-run impact, but its level is fundamentally weak. The cause of the current inflation is mainly due to public's expectations of the inflation in the last period. Although the error correction, from the long-run relationship, has affected inflation in the short run, the coefficient is small and insignificant. In other words, it means that the speed of the adjustment is very low or near zero. This also implies that once the relationship among inflation, domestic credit, interest rate, budget deficit, and crude oil prices deviate from the long-term trend, it will take the economy a lot of time to return to the equilibrium state.


2018 ◽  
Vol 5 (1) ◽  
pp. 43-54
Author(s):  
Suresh Aluvihara ◽  
Jagath K Premachandra

Corrosion is a severe matter regarding the most of metal using industries such as the crude oil refining. The formation of the oxides, sulfides or hydroxides on the surface of metal due to the chemical reaction between metals and surrounding is the corrosion that  highly depended on the corrosive properties of crude oil as well as the chemical composition of ferrous metals since it was expected to investigate the effect of Murban and Das blend crude oils on the rate of corrosion of seven different ferrous metals which are used in the crude oil refining industry and investigate the change in hardness of metals. The sulfur content, acidity and salt content of each crude oil were determined. A series of similar pieces of seven different types of ferrous metals were immersed in each crude oil separately and their rates of corrosion were determined by using their relative weight loss after 15, 30 and 45 days. The corroded metal surfaces were observed under the microscope. The hardness of each metal piece was tested before the immersion in crude oil and after the corrosion with the aid of Vicker’s hardness tester. The metallic concentrations of each crude oil sample were tested using atomic absorption spectroscopy (AAS). The Das blend crude oil contained higher sulfur content and acidity than Murban crude oil. Carbon steel metal pieces showed the highest corrosion rates whereas the stainless steel metal pieces showed the least corrosion rates in both crude oils since that found significant Fe and Cu concentrations from some of crude oil samples. The mild steel and the Monel showed relatively intermediate corrosion rates compared to the other types of ferrous metal pieces in both crude oils. There was a slight decrease in the initial hardness of all the ferrous metal pieces due to corrosion.


BMJ Open ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. e043863
Author(s):  
Jingyuan Wang ◽  
Ke Tang ◽  
Kai Feng ◽  
Xin Lin ◽  
Weifeng Lv ◽  
...  

ObjectivesWe aim to assess the impact of temperature and relative humidity on the transmission of COVID-19 across communities after accounting for community-level factors such as demographics, socioeconomic status and human mobility status.DesignA retrospective cross-sectional regression analysis via the Fama-MacBeth procedure is adopted.SettingWe use the data for COVID-19 daily symptom-onset cases for 100 Chinese cities and COVID-19 daily confirmed cases for 1005 US counties.ParticipantsA total of 69 498 cases in China and 740 843 cases in the USA are used for calculating the effective reproductive numbers.Primary outcome measuresRegression analysis of the impact of temperature and relative humidity on the effective reproductive number (R value).ResultsStatistically significant negative correlations are found between temperature/relative humidity and the effective reproductive number (R value) in both China and the USA.ConclusionsHigher temperature and higher relative humidity potentially suppress the transmission of COVID-19. Specifically, an increase in temperature by 1°C is associated with a reduction in the R value of COVID-19 by 0.026 (95% CI (−0.0395 to −0.0125)) in China and by 0.020 (95% CI (−0.0311 to −0.0096)) in the USA; an increase in relative humidity by 1% is associated with a reduction in the R value by 0.0076 (95% CI (−0.0108 to −0.0045)) in China and by 0.0080 (95% CI (−0.0150 to −0.0010)) in the USA. Therefore, the potential impact of temperature/relative humidity on the effective reproductive number alone is not strong enough to stop the pandemic.


Resources ◽  
2021 ◽  
Vol 10 (8) ◽  
pp. 75
Author(s):  
Ivelina K. Shishkova ◽  
Dicho S. Stratiev ◽  
Mariana P. Tavlieva ◽  
Rosen K. Dinkov ◽  
Dobromir Yordanov ◽  
...  

Thirty crude oils, belonging to light, medium, heavy, and extra heavy, light sulfur, and high sulfur have been characterized and compatibility indices defined. Nine crude oil compatibility indices have been employed to evaluate the compatibility of crude blends from the thirty individual crude oils. Intercriteria analysis revealed the relations between the different compatibility indices, and the different petroleum properties. Tetra-plot was employed to model crude blend compatibility. The ratio of solubility blending number to insolubility number was found to best describe the desalting efficiency, and therefore could be considered as the compatible index that best models the crude oil blend compatibility. Density of crude oil and the n-heptane dilution test seem to be sufficient to model, and predict the compatibility of crude blends.


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