Potent Oxidation of DNA by Haloquinoid Disinfection Byproducts to the More Mutagenic Imidazolone dIz via an Unprecedented Haloquinone-Enoxy Radical-Mediated Mechanism

2020 ◽  
Vol 54 (10) ◽  
pp. 6244-6253 ◽  
Author(s):  
Jie Shao ◽  
Chun-Hua Huang ◽  
Bo Shao ◽  
Li Qin ◽  
Dan Xu ◽  
...  
Keyword(s):  
Disinfection Byproducts ◽  
Oxidation Of Dna

Resorcinarene Cavitand Polymers for the Remediation of Halomethanes and 1,4-Dioxane

2019 ◽  
Author(s):  
Luke Skala ◽  
Anna Yang ◽  
Max Justin Klemes ◽  
Leilei Xiao ◽  
William Dichtel
Keyword(s):  
Drinking Water ◽  
Activated Carbon ◽  
High Capacity ◽  
The United States ◽  
Water Sources ◽  
Disinfection Byproducts ◽  
Porous Polymer ◽  
Organic Micropollutants ◽  
Executive Summary ◽  
Regulatory Limits

<p>Executive summary: Porous resorcinarene-containing polymers are used to remove halomethane disinfection byproducts and 1,4-dioxane from water.<br></p><p><br></p><p>Disinfection byproducts such as trihalomethanes are some of the most common micropollutants found in drinking water. Trihalomethanes are formed upon chlorination of natural organic matter (NOM) found in many drinking water sources. Municipalities that produce drinking water from surface water sources struggle to remain below regulatory limits for CHCl<sub>3</sub> and other trihalomethanes (80 mg L<sup>–1</sup> in the United States). Inspired by molecular CHCl<sub>3</sub>⊂cavitand host-guest complexes, we designed a porous polymer comprised of resorcinarene receptors. These materials show higher affinity for halomethanes than a specialty activated carbon used for trihalomethane removal. The cavitand polymers show similar removal kinetics as activated carbon and have high capacity (49 mg g<sup>–1</sup> of CHCl<sub>3</sub>). Furthermore, these materials maintain their performance in real drinking water and can be thermally regenerated under mild conditions. Cavitand polymers also outperform activated carbon in their adsorption of 1,4-dioxane, which is difficult to remove and contaminates many public water sources. These materials show promise for removing toxic organic micropollutants and further demonstrate the value of using supramolecular chemistry to design novel absorbents for water purification.<br></p>

DISINFEKSI UNTUK PROSES PENGOLAHAN AIR MINUM

2018 ◽  
Vol 3 (1) ◽  
Author(s):  
Nusa Idaman Said
Keyword(s):  
Drinking Water ◽  
Water Purification ◽  
Distribution System ◽  
Residual Effect ◽  
Drinking Water Treatment ◽  
Disinfection Byproducts ◽  
Water Disinfection ◽  
Pathogenic Microorganisms ◽  
Microbiological Contamination ◽  
Disinfection Process

Water disinfection means the removal, deactivation or killing of pathogenic microorganisms. Microorganisms are destroyed or deactivated, resulting in termination of growth and reproduction. When microorganisms are not removed from drinking water, drinking water usage will cause people to fall ill. Chemical inactivation of microbiological contamination in natural or untreated water is usually one of the final steps to reduce pathogenic microorganisms in drinking water. Combinations of water purification steps (oxidation, coagulation, settling, disinfection, and filtration) cause (drinking) water to be safe after production. As an extra measure many countries apply a second disinfection step at the end of the water purification process, in order to protect the water from microbiological contamination in the water distribution system. Usually one uses a different kind of disinfectant from the one earlier in the process, during this disinfection process. The secondary disinfection makes sure that bacteria will not multiply in the water during distribution. This paper describes several technique of disinfection process for drinking water treatment. Disinfection can be attained by means of physical or chemical disinfectants. The agents also remove organic contaminants from water, which serve as nutrients or shelters for microorganisms. Disinfectants should not only kill microorganisms. Disinfectants must also have a residual effect, which means that they remain active in the water after disinfection. For chemical disinfection of water the following disinfectants can be used such as Chlorine (Cl2),  Hypo chlorite (OCl-), Chloramines, Chlorine dioxide (ClO2), Ozone (O3), Hydrogen peroxide etch. For physical disinfection of water the following disinfectants can be used is Ultraviolet light (UV). Every technique has its specific advantages and and disadvantages its own application area sucs as environmentally friendly, disinfection byproducts, effectivity, investment, operational costs etc. Kata Kunci : Disinfeksi, bakteria, virus, air minum, khlor, hip khlorit, khloramine, khlor dioksida, ozon, UV.

Chlorination decreases acute toxicity of iodophenols through the formation of iodate and chlorinated aliphatic disinfection byproducts

2021 ◽  
Vol 194 ◽  
pp. 116951
Author(s):  
Xian-Shi Wang ◽  
Heng Song ◽  
Jing Zhang ◽  
Yu-Lei Liu ◽  
Jun Ma ◽  
...  
Keyword(s):  
Acute Toxicity ◽  
Disinfection Byproducts

scholarly journals The Role of Catalytic Ozonation Processes on the Elimination of DBPs and Their Precursors in Drinking Water Treatment

Catalysts ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 521
Author(s):  
Fernando J. Beltrán ◽  
Ana Rey ◽  
Olga Gimeno
Keyword(s):  
Drinking Water ◽  
Water Treatment ◽  
Humic Substances ◽  
Hypochlorous Acid ◽  
Drinking Water Treatment ◽  
Disinfection Byproducts ◽  
Catalytic Ozonation ◽  
Operating Conditions ◽  
Halogen Compounds ◽  
Radiation Sources

Formation of disinfection byproducts (DBPs) in drinking water treatment (DWT) as a result of pathogen removal has always been an issue of special attention in the preparation of safe water. DBPs are formed by the action of oxidant-disinfectant chemicals, mainly chlorine derivatives (chlorine, hypochlorous acid, chloramines, etc.), that react with natural organic matter (NOM), mainly humic substances. DBPs are usually refractory to oxidation, mainly due to the presence of halogen compounds so that advanced oxidation processes (AOPs) are a recommended option to deal with their removal. In this work, the application of catalytic ozonation processes (with and without the simultaneous presence of radiation), moderately recent AOPs, for the removal of humic substances (NOM), also called DBPs precursors, and DBPs themselves is reviewed. First, a short history about the use of disinfectants in DWT, DBPs formation discovery and alternative oxidants used is presented. Then, sections are dedicated to conventional AOPs applied to remove DBPs and their precursors to finalize with the description of principal research achievements found in the literature about application of catalytic ozonation processes. In this sense, aspects such as operating conditions, reactors used, radiation sources applied in their case, kinetics and mechanisms are reviewed.

scholarly journals Spatial variation of dissolved organic nitrogen in Wuhan surface waters: Correlation with the occurrence of disinfection byproducts during the COVID-19 pandemic

2021 ◽  
pp. 117138
Author(s):  
Leyun Wang ◽  
Xian Zhang ◽  
Shanshan Chen ◽  
Fanbin Meng ◽  
Dayi Zhang ◽  
...  
Keyword(s):  
Spatial Variation ◽  
Surface Waters ◽  
Dissolved Organic Nitrogen ◽  
Organic Nitrogen ◽  
Disinfection Byproducts

Chemical structures of extra- and intra-cellular algogenic organic matters as precursors to the formation of carbonaceous disinfection byproducts

2017 ◽  
Vol 328 ◽  
pp. 1022-1030 ◽  
Author(s):  
Lap-Cuong Hua ◽  
Jr-Lin Lin ◽  
Pei-Chung Chen ◽  
Chihpin Huang
Keyword(s):  
Disinfection Byproducts ◽  
Organic Matters ◽  
Chemical Structures

p-Cyano substituted 5-benzoyldeoxyuridine as a novel electron-accepting nucleobase for one-electron oxidation of DNA

1998 ◽  
Vol 39 (33) ◽  
pp. 5995-5998 ◽  
Author(s):  
Kazuhiko Nakatani ◽  
Kazuhiko Fujisawa ◽  
Chikara Dohno ◽  
Takashi Nakamura ◽  
Isao Saito
Keyword(s):  
Oxidation Of Dna

scholarly journals Evaluation of an environmentally sustainable UV-assisted water treatment system for the removal of Bacillus globigii spores in water

2017 ◽  
Vol 18 (3) ◽  
pp. 968-975
Author(s):  
R. G. Silva ◽  
J. Szabo ◽  
V. Namboodiri ◽  
E. R. Krishnan ◽  
J. Rodriguez ◽  
...  
Keyword(s):  
Water Treatment ◽  
High Efficiency ◽  
Membrane Filter ◽  
Water Security ◽  
Disinfection Byproducts ◽  
Treatment System ◽  
Health Concern ◽  
Environmentally Sustainable ◽  
Inorganic Substances ◽  
The Impact

Abstract Development of greener water treatment technologies is important for the production of safe drinking water and water security applications, such as decontamination. Chlorine assisted disinfection is common and economical, but can generate disinfection byproducts (DBPs) that may be of health concern. DBPs are formed due to the reaction of chlorine with naturally occurring organic and inorganic substances in water. Currently, various innovative technologies are being developed as alternative approaches for preventing DBPs during water treatment. In this study, we evaluated the effectiveness of a novel combination of high efficiency flow filtration and UV disinfection treatment system for the removal of Bacillus globigii (B. globigii) spores in water. The filtration system consists of a charged membrane filter (CMF) that not only helps to remove suspended particles but also reduces the impact of other impurities including bio organisms. In order to get most performance details, the CMF was evaluated at clean, half-life, and end of life (EOL) conditions along with 100% UV transmittance (UVT). In addition, the effectiveness of the UV system was evaluated as a stand alone system at 100% and 70% EOL intensity. The study was conducted at the US EPA's Test and Evaluation (T&E) Facility in Cincinnati, OH, using B. globigii, a surrogate for B. anthracis spores. This non-chemical environmentally-friendly CMF/UV combination system and the stand alone UV unit showed greater than 6.0 log removal of B. globigii during the tests.

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